CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability

Plant lipoxygenases (LOXs) catalyze the oxidation of polyunsaturated fatty acids, which can adversely affect grain storability. Although the genetic engineering of LOXs holds great potential for improving grain storage quality, this approach remains largely unexplored in barley. In this study, we id...

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Main Authors: Zhanghui Zeng, Huiling Wang, Yingjie Luo, Wenjun Chen, Mingrui Xu, Haonan Wei, Zhehao Chen, Taihe Xiang, Lilin Wang, Ning Han, Xiaoping Huang, Hongwu Bian
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:GM Crops & Food
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Online Access:https://www.tandfonline.com/doi/10.1080/21645698.2025.2523069
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author Zhanghui Zeng
Huiling Wang
Yingjie Luo
Wenjun Chen
Mingrui Xu
Haonan Wei
Zhehao Chen
Taihe Xiang
Lilin Wang
Ning Han
Xiaoping Huang
Hongwu Bian
author_facet Zhanghui Zeng
Huiling Wang
Yingjie Luo
Wenjun Chen
Mingrui Xu
Haonan Wei
Zhehao Chen
Taihe Xiang
Lilin Wang
Ning Han
Xiaoping Huang
Hongwu Bian
author_sort Zhanghui Zeng
collection DOAJ
description Plant lipoxygenases (LOXs) catalyze the oxidation of polyunsaturated fatty acids, which can adversely affect grain storability. Although the genetic engineering of LOXs holds great potential for improving grain storage quality, this approach remains largely unexplored in barley. In this study, we identified five LOX genes in the barley genome: HvLOXA, HvLOXB, and HvLOXC1–3. HvLOXC1 exhibited the highest expression in early developing grains, roots, and shoots; HvLOXA was predominantly expressed in embryos, whereas HvLOXB and HvLOXC3 were weakly expressed across tissues. Transgene-free homozygous barley mutants of loxB, loxC1, and loxAloxC1 were generated using CRISPR/Cas9-mediated genome editing. Compared to the wild-type, all mutants displayed normal plant height, tiller number, and grain size, although the loxC1 and loxAloxC1 mutants exhibited significantly lower thousand grain weights. Notably, the total LOX activity in mature grains decreased by 36–42% in loxC1 mutants and by 94% in loxAloxC1 mutants, with no significant change observed in loxB mutants. Additionally, the loxAloxC1 double mutants had a significantly lower malondialdehyde content and accumulated 10–21% more fatty acids than the wild-type. Artificial aging treatment experiments revealed that loxAloxC1 mutants had enhanced grain storability, demonstrated by significantly higher germination rates, reduced lipid peroxidation, and improved seedling growth. Our findings highlight that the targeted knockout of LOX genes, particularly the double mutation of HvLOXA and HvLOXC1, represents a promising genetic strategy for improving grain storability and nutritional value in barley.
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spelling doaj-art-ff8090eed73b4057b39e466eddfc7e9a2025-08-20T03:24:00ZengTaylor & Francis GroupGM Crops & Food2164-56982164-57012025-12-0116148249710.1080/21645698.2025.2523069CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storabilityZhanghui Zeng0Huiling Wang1Yingjie Luo2Wenjun Chen3Mingrui Xu4Haonan Wei5Zhehao Chen6Taihe Xiang7Lilin Wang8Ning Han9Xiaoping Huang10Hongwu Bian11College of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaKey Laboratory for Cell and Gene Engineering of Zhejiang Province, College of Life Sciences, Zhejiang University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaKey Laboratory for Cell and Gene Engineering of Zhejiang Province, College of Life Sciences, Zhejiang University, Hangzhou, Zhejiang, ChinaCollege of Life and Environmental Sciences, Hangzhou Normal University, Hangzhou, Zhejiang, ChinaKey Laboratory for Cell and Gene Engineering of Zhejiang Province, College of Life Sciences, Zhejiang University, Hangzhou, Zhejiang, ChinaPlant lipoxygenases (LOXs) catalyze the oxidation of polyunsaturated fatty acids, which can adversely affect grain storability. Although the genetic engineering of LOXs holds great potential for improving grain storage quality, this approach remains largely unexplored in barley. In this study, we identified five LOX genes in the barley genome: HvLOXA, HvLOXB, and HvLOXC1–3. HvLOXC1 exhibited the highest expression in early developing grains, roots, and shoots; HvLOXA was predominantly expressed in embryos, whereas HvLOXB and HvLOXC3 were weakly expressed across tissues. Transgene-free homozygous barley mutants of loxB, loxC1, and loxAloxC1 were generated using CRISPR/Cas9-mediated genome editing. Compared to the wild-type, all mutants displayed normal plant height, tiller number, and grain size, although the loxC1 and loxAloxC1 mutants exhibited significantly lower thousand grain weights. Notably, the total LOX activity in mature grains decreased by 36–42% in loxC1 mutants and by 94% in loxAloxC1 mutants, with no significant change observed in loxB mutants. Additionally, the loxAloxC1 double mutants had a significantly lower malondialdehyde content and accumulated 10–21% more fatty acids than the wild-type. Artificial aging treatment experiments revealed that loxAloxC1 mutants had enhanced grain storability, demonstrated by significantly higher germination rates, reduced lipid peroxidation, and improved seedling growth. Our findings highlight that the targeted knockout of LOX genes, particularly the double mutation of HvLOXA and HvLOXC1, represents a promising genetic strategy for improving grain storability and nutritional value in barley.https://www.tandfonline.com/doi/10.1080/21645698.2025.2523069Artificial agingbarleyCRISPR/Cas9lipoxygenase (LOX)storability
spellingShingle Zhanghui Zeng
Huiling Wang
Yingjie Luo
Wenjun Chen
Mingrui Xu
Haonan Wei
Zhehao Chen
Taihe Xiang
Lilin Wang
Ning Han
Xiaoping Huang
Hongwu Bian
CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability
GM Crops & Food
Artificial aging
barley
CRISPR/Cas9
lipoxygenase (LOX)
storability
title CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability
title_full CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability
title_fullStr CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability
title_full_unstemmed CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability
title_short CRISPR/Cas9-mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability
title_sort crispr cas9 mediated editing of barley lipoxygenase genes promotes grain fatty acid accumulation and storability
topic Artificial aging
barley
CRISPR/Cas9
lipoxygenase (LOX)
storability
url https://www.tandfonline.com/doi/10.1080/21645698.2025.2523069
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