Preparation and Application of Core–Shell Nanocarbon-Based Slow-Release Foliar Fertilizer

The application of nanotechnology offers a promising solution to improve fertilizer utilization efficiency by mitigating the losses and volatilization of conventional fertilizers, contributing to sustainable agriculture. In this study, a core–shell nanocarbon-based slow-release foliar fertilizer (CN...

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Main Authors: Ting Zhang, Xinheng Chen, Hongtao Gu, Huayi Chen, Kaichun Huang, Jinjin Wang, Huijuan Xu, Yulong Zhang, Wenyan Li
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/15/7/565
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Summary:The application of nanotechnology offers a promising solution to improve fertilizer utilization efficiency by mitigating the losses and volatilization of conventional fertilizers, contributing to sustainable agriculture. In this study, a core–shell nanocarbon-based slow-release foliar fertilizer (CN@mSiO<sub>2</sub>-NH<sub>2</sub>@Urea@PDA) was synthesized using nanocarbon (CN) as the core, amino-functionalized mesoporous silica (mSiO<sub>2</sub>-NH<sub>2</sub>) as the shell, and polydopamine (PDA) as the coating layer. BET analysis revealed a 3.5-fold and 1.9-fold reduction in material porosity after PDA encapsulation, confirming successful synthesis. The controlled-release performance was enhanced, with a 24% decrease in the release rate and a prolonged nutrient delivery duration. Hydrophobicity tests demonstrated a 20° increase in the contact angle, indicating improved adhesion. Seed germination assays validated biosafety, while field trials showed a 69.94% increase in the choy sum (<i>Brassica rapa</i>) yield, 21.64% higher nitrogen utilization efficiency, and 22.21% reduced nitrogen loss. The foliar application increased the plant nitrogen use efficiency by 18.37%. These findings highlight the potential of CN@mSiO<sub>2</sub>-NH<sub>2</sub>@Urea@PDA as an advanced foliar fertilizer, providing a strategic approach to promote nanomaterial applications in agriculture and enhance the acceptance of functional fertilizers among farmers.
ISSN:2079-4991