Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVC
The effects of titanate as a coupling agent and some particulate nanoscale particles such as TiO2, CaCO3, and ZnO on thermal and mechanical properties of emulsion polyvinylchloride (E-PVC) were investigated by thermogravimetric analysis (TGA), and mechanical tests. In this research, it was found tha...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2011/238619 |
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| author | Morteza Hajian Gholam Ali Koohmareh Afsaneh Mostaghasi |
| author_facet | Morteza Hajian Gholam Ali Koohmareh Afsaneh Mostaghasi |
| author_sort | Morteza Hajian |
| collection | DOAJ |
| description | The effects of titanate as a coupling agent and some particulate nanoscale particles such as TiO2, CaCO3, and ZnO on thermal and mechanical properties of emulsion polyvinylchloride (E-PVC) were investigated by thermogravimetric analysis (TGA), and mechanical tests. In this research, it was found that, in the presence of nanoparticles of CaCO3, TiO2, and ZnO, the peak temperature of dehydrochlorination of E-PVC was shifted to higher temperatures, and the rate of mass loss was decreased. Also results of differential scanning calorimetry showed that the addition of nanoparticle of CaCO3, TiO2, and ZnO led to an increase in glass transition temperature. The impact strength, elastic modulus and toughness of the samples were enhanced after addition of 0–10 part of filer in hundred parts of resin (phr) nano-CaCO3, nano-TiO2, and nano-ZnO due to improvement of compatibility of the polymer and the nano-particles. Also UV and thermal stability of the samples were enhanced by means of the nanoparticles. It was found that, in the presence of titanate as coupling agent, content of additives that could be used in the composite of PVC shifts to higher amounts. |
| format | Article |
| id | doaj-art-fed5bad87dd04306bc5624739fe3072e |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-fed5bad87dd04306bc5624739fe3072e2025-02-03T05:44:53ZengWileyInternational Journal of Polymer Science1687-94221687-94302011-01-01201110.1155/2011/238619238619Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVCMorteza Hajian0Gholam Ali Koohmareh1Afsaneh Mostaghasi2Department of Chemistry, College of Science, University of Isfahan, Isfahan 81746-73441, IranDepartment of Chemistry, College of Science, University of Isfahan, Isfahan 81746-73441, IranDepartment of Chemistry, College of Science, University of Isfahan, Isfahan 81746-73441, IranThe effects of titanate as a coupling agent and some particulate nanoscale particles such as TiO2, CaCO3, and ZnO on thermal and mechanical properties of emulsion polyvinylchloride (E-PVC) were investigated by thermogravimetric analysis (TGA), and mechanical tests. In this research, it was found that, in the presence of nanoparticles of CaCO3, TiO2, and ZnO, the peak temperature of dehydrochlorination of E-PVC was shifted to higher temperatures, and the rate of mass loss was decreased. Also results of differential scanning calorimetry showed that the addition of nanoparticle of CaCO3, TiO2, and ZnO led to an increase in glass transition temperature. The impact strength, elastic modulus and toughness of the samples were enhanced after addition of 0–10 part of filer in hundred parts of resin (phr) nano-CaCO3, nano-TiO2, and nano-ZnO due to improvement of compatibility of the polymer and the nano-particles. Also UV and thermal stability of the samples were enhanced by means of the nanoparticles. It was found that, in the presence of titanate as coupling agent, content of additives that could be used in the composite of PVC shifts to higher amounts.http://dx.doi.org/10.1155/2011/238619 |
| spellingShingle | Morteza Hajian Gholam Ali Koohmareh Afsaneh Mostaghasi Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVC International Journal of Polymer Science |
| title | Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVC |
| title_full | Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVC |
| title_fullStr | Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVC |
| title_full_unstemmed | Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVC |
| title_short | Investigation of the Effects of Titanate as Coupling Agent and Some Inorganic Nanoparticles as Fillers on Mechanical Properties and Morphology of Soft PVC |
| title_sort | investigation of the effects of titanate as coupling agent and some inorganic nanoparticles as fillers on mechanical properties and morphology of soft pvc |
| url | http://dx.doi.org/10.1155/2011/238619 |
| work_keys_str_mv | AT mortezahajian investigationoftheeffectsoftitanateascouplingagentandsomeinorganicnanoparticlesasfillersonmechanicalpropertiesandmorphologyofsoftpvc AT gholamalikoohmareh investigationoftheeffectsoftitanateascouplingagentandsomeinorganicnanoparticlesasfillersonmechanicalpropertiesandmorphologyofsoftpvc AT afsanehmostaghasi investigationoftheeffectsoftitanateascouplingagentandsomeinorganicnanoparticlesasfillersonmechanicalpropertiesandmorphologyofsoftpvc |