Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 Nanoparticles

In this paper, ZnFe2O4 nanoparticles were synthesized using the co-precipitation method, aiming to investigate the effect of pH on their structural and optical properties. The synthesis was carried out at various pH levels of 7, 9, and 11, to explore how acidic and basic conditions can influence the...

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Main Authors: Mahdiyeh Taherkhani, Mohammad Ehsani, Reza Zarei moghadam, Abbas Javadian
Format: Article
Language:English
Published: Semnan University 2025-05-01
Series:Progress in Physics of Applied Materials
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Online Access:https://ppam.semnan.ac.ir/article_9504_5d988d00692ee3c73a7c87fe81e85507.pdf
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author Mahdiyeh Taherkhani
Mohammad Ehsani
Reza Zarei moghadam
Abbas Javadian
author_facet Mahdiyeh Taherkhani
Mohammad Ehsani
Reza Zarei moghadam
Abbas Javadian
author_sort Mahdiyeh Taherkhani
collection DOAJ
description In this paper, ZnFe2O4 nanoparticles were synthesized using the co-precipitation method, aiming to investigate the effect of pH on their structural and optical properties. The synthesis was carried out at various pH levels of 7, 9, and 11, to explore how acidic and basic conditions can influence the characteristics of these nanoparticles. Structural analysis was conducted using X-ray diffraction (XRD), which allowed for a comprehensive understanding of the phase composition and crystallinity of the nanoparticles. The XRD results revealed that as the pH increased from 7 to 11, the diffraction peaks became broader, indicating a reduction in crystalline size, which is a common phenomenon attributed to increased defects within the crystalline structure. This size reduction corresponds with an increase in dislocation density and strain within the samples, suggesting that higher pH environments lead to more significant structural alterations. Optical properties were investigated using a UV-Vis spectrometer. The optical analysis showed a noteworthy trend: as the pH increased from 7 to 11, the absorption capacity of the ZnFe2O4 nanoparticles decreased. This reduction in absorption may imply a modification in band gap energy, which is crucial for potential applications in photonic devices and sensors.
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publishDate 2025-05-01
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series Progress in Physics of Applied Materials
spelling doaj-art-fe4bd6b3f89a4af9a712850b2df8d94f2025-08-20T02:58:19ZengSemnan UniversityProgress in Physics of Applied Materials2783-47942025-05-0151535910.22075/ppam.2025.36655.11299504Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 NanoparticlesMahdiyeh Taherkhani0Mohammad Ehsani1Reza Zarei moghadam2Abbas Javadian3Thin Film Lab, Faculty of Physics, University of Semnan, Semnan, Islamic Republic of IranFaculty of PhysicsPhysics Department, Faculty of Science, Arak University, Arak, 38156, IranPhysicsIn this paper, ZnFe2O4 nanoparticles were synthesized using the co-precipitation method, aiming to investigate the effect of pH on their structural and optical properties. The synthesis was carried out at various pH levels of 7, 9, and 11, to explore how acidic and basic conditions can influence the characteristics of these nanoparticles. Structural analysis was conducted using X-ray diffraction (XRD), which allowed for a comprehensive understanding of the phase composition and crystallinity of the nanoparticles. The XRD results revealed that as the pH increased from 7 to 11, the diffraction peaks became broader, indicating a reduction in crystalline size, which is a common phenomenon attributed to increased defects within the crystalline structure. This size reduction corresponds with an increase in dislocation density and strain within the samples, suggesting that higher pH environments lead to more significant structural alterations. Optical properties were investigated using a UV-Vis spectrometer. The optical analysis showed a noteworthy trend: as the pH increased from 7 to 11, the absorption capacity of the ZnFe2O4 nanoparticles decreased. This reduction in absorption may imply a modification in band gap energy, which is crucial for potential applications in photonic devices and sensors.https://ppam.semnan.ac.ir/article_9504_5d988d00692ee3c73a7c87fe81e85507.pdfznf2o4 nanoparticlesco-precipitation methodx-ray diffraction pattern
spellingShingle Mahdiyeh Taherkhani
Mohammad Ehsani
Reza Zarei moghadam
Abbas Javadian
Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 Nanoparticles
Progress in Physics of Applied Materials
znf2o4 nanoparticles
co-precipitation method
x-ray diffraction pattern
title Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 Nanoparticles
title_full Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 Nanoparticles
title_fullStr Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 Nanoparticles
title_full_unstemmed Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 Nanoparticles
title_short Exploring the Effects of pH on the Morphology and Optical Characteristics of ZnFe2O4 Nanoparticles
title_sort exploring the effects of ph on the morphology and optical characteristics of znfe2o4 nanoparticles
topic znf2o4 nanoparticles
co-precipitation method
x-ray diffraction pattern
url https://ppam.semnan.ac.ir/article_9504_5d988d00692ee3c73a7c87fe81e85507.pdf
work_keys_str_mv AT mahdiyehtaherkhani exploringtheeffectsofphonthemorphologyandopticalcharacteristicsofznfe2o4nanoparticles
AT mohammadehsani exploringtheeffectsofphonthemorphologyandopticalcharacteristicsofznfe2o4nanoparticles
AT rezazareimoghadam exploringtheeffectsofphonthemorphologyandopticalcharacteristicsofznfe2o4nanoparticles
AT abbasjavadian exploringtheeffectsofphonthemorphologyandopticalcharacteristicsofznfe2o4nanoparticles