Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.

Field portable X-ray fluorescence (FP-XRF) has tremendous potential in geoenvironmental engineering as a qualitative assessment tool. Identification of the elevated concentrations of the selected elements (Cr, Cu, Mn, Ni, Pb, and Zn) in various geomaterials like soil-like-material (SLM), incinerated...

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Main Authors: Pranjal Singh, Manoj Datta, G V Ramana, Sanjay Kumar Gupta, Tabarak Malik
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2022-01-01
Series:PLoS ONE
Online Access:https://journals.plos.org/plosone/article/file?id=10.1371/journal.pone.0268268&type=printable
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author Pranjal Singh
Manoj Datta
G V Ramana
Sanjay Kumar Gupta
Tabarak Malik
author_facet Pranjal Singh
Manoj Datta
G V Ramana
Sanjay Kumar Gupta
Tabarak Malik
author_sort Pranjal Singh
collection DOAJ
description Field portable X-ray fluorescence (FP-XRF) has tremendous potential in geoenvironmental engineering as a qualitative assessment tool. Identification of the elevated concentrations of the selected elements (Cr, Cu, Mn, Ni, Pb, and Zn) in various geomaterials like soil-like-material (SLM), incinerated bottom ash (IBA), construction and demolition waste (CDW), zinc tailings (ZT) and fly ash (FA) was performed by FP-XRF and compared with the local soil-Delhi silt. Comparably higher concentrations (mg/kg) of Cr (401.0), Cu (499.0), Pb (532.0), Zn (608.0) in SLM, Cr (195.0), Cu (419.0), Ni (93.0), Pb (931.0), Zn (771.0) in IBA and Cr (195.0), Cu (4000.0), Pb (671.0), Zn (7122.0) in ZT were observed. CDW and FA showed similar concentrations range as in local soils. FP-XRF was also used in-situ on local soil at 11 sites to examine its ability to identify the elements with significant variations in concentrations. The results showed high variability in Cl and S concentration values across the 11 sites attributed to the changing moisture content and dissolved salts. The concentration range for the remaining elements were similar at all sites. The verification of the detected elements through visual inspection of the spectrum was also carried out.
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spelling doaj-art-fe48fa3391194d09b9f2bd58db71ad112025-08-20T02:46:27ZengPublic Library of Science (PLoS)PLoS ONE1932-62032022-01-01175e026826810.1371/journal.pone.0268268Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.Pranjal SinghManoj DattaG V RamanaSanjay Kumar GuptaTabarak MalikField portable X-ray fluorescence (FP-XRF) has tremendous potential in geoenvironmental engineering as a qualitative assessment tool. Identification of the elevated concentrations of the selected elements (Cr, Cu, Mn, Ni, Pb, and Zn) in various geomaterials like soil-like-material (SLM), incinerated bottom ash (IBA), construction and demolition waste (CDW), zinc tailings (ZT) and fly ash (FA) was performed by FP-XRF and compared with the local soil-Delhi silt. Comparably higher concentrations (mg/kg) of Cr (401.0), Cu (499.0), Pb (532.0), Zn (608.0) in SLM, Cr (195.0), Cu (419.0), Ni (93.0), Pb (931.0), Zn (771.0) in IBA and Cr (195.0), Cu (4000.0), Pb (671.0), Zn (7122.0) in ZT were observed. CDW and FA showed similar concentrations range as in local soils. FP-XRF was also used in-situ on local soil at 11 sites to examine its ability to identify the elements with significant variations in concentrations. The results showed high variability in Cl and S concentration values across the 11 sites attributed to the changing moisture content and dissolved salts. The concentration range for the remaining elements were similar at all sites. The verification of the detected elements through visual inspection of the spectrum was also carried out.https://journals.plos.org/plosone/article/file?id=10.1371/journal.pone.0268268&type=printable
spellingShingle Pranjal Singh
Manoj Datta
G V Ramana
Sanjay Kumar Gupta
Tabarak Malik
Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.
PLoS ONE
title Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.
title_full Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.
title_fullStr Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.
title_full_unstemmed Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.
title_short Qualitative comparison of elemental concentration in soils and other geomaterials using FP-XRF.
title_sort qualitative comparison of elemental concentration in soils and other geomaterials using fp xrf
url https://journals.plos.org/plosone/article/file?id=10.1371/journal.pone.0268268&type=printable
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AT gvramana qualitativecomparisonofelementalconcentrationinsoilsandothergeomaterialsusingfpxrf
AT sanjaykumargupta qualitativecomparisonofelementalconcentrationinsoilsandothergeomaterialsusingfpxrf
AT tabarakmalik qualitativecomparisonofelementalconcentrationinsoilsandothergeomaterialsusingfpxrf