Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation Time

Color, phenolic content, and chemical age values of red wines made from Cretan grape varieties (Kotsifali, Mandilari) were evaluated over nine months of maturation in different containers for two vintages. The wines differed greatly on their anthocyanin profiles. Mid-IR spectra were also recorded wi...

Full description

Saved in:
Bibliographic Details
Main Authors: M. Basalekou, C. Pappas, Y. Kotseridis, P. A. Tarantilis, E. Kontaxakis, S. Kallithraka
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Journal of Analytical Methods in Chemistry
Online Access:http://dx.doi.org/10.1155/2017/5767613
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849469536484458496
author M. Basalekou
C. Pappas
Y. Kotseridis
P. A. Tarantilis
E. Kontaxakis
S. Kallithraka
author_facet M. Basalekou
C. Pappas
Y. Kotseridis
P. A. Tarantilis
E. Kontaxakis
S. Kallithraka
author_sort M. Basalekou
collection DOAJ
description Color, phenolic content, and chemical age values of red wines made from Cretan grape varieties (Kotsifali, Mandilari) were evaluated over nine months of maturation in different containers for two vintages. The wines differed greatly on their anthocyanin profiles. Mid-IR spectra were also recorded with the use of a Fourier Transform Infrared Spectrophotometer in ZnSe disk mode. Analysis of Variance was used to explore the parameter’s dependency on time. Determination models were developed for the chemical age indexes using Partial Least Squares (PLS) (TQ Analyst software) considering the spectral region 1830–1500 cm−1. The correlation coefficients (r) for chemical age index i were 0.86 for Kotsifali (Root Mean Square Error of Calibration (RMSEC) = 0.067, Root Mean Square Error of Prediction (RMSEP) = 0,115, and Root Mean Square Error of Validation (RMSECV) = 0.164) and 0.90 for Mandilari (RMSEC = 0.050, RMSEP = 0.040, and RMSECV = 0.089). For chemical age index ii the correlation coefficients (r) were 0.86 and 0.97 for Kotsifali (RMSEC 0.044, RMSEP = 0.087, and RMSECV = 0.214) and Mandilari (RMSEC = 0.024, RMSEP = 0.033, and RMSECV = 0.078), respectively. The proposed method is simpler, less time consuming, and more economical and does not require chemical reagents.
format Article
id doaj-art-fd7a0340d1944eb7bb893637b84c4618
institution Kabale University
issn 2090-8865
2090-8873
language English
publishDate 2017-01-01
publisher Wiley
record_format Article
series Journal of Analytical Methods in Chemistry
spelling doaj-art-fd7a0340d1944eb7bb893637b84c46182025-08-20T03:25:26ZengWileyJournal of Analytical Methods in Chemistry2090-88652090-88732017-01-01201710.1155/2017/57676135767613Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation TimeM. Basalekou0C. Pappas1Y. Kotseridis2P. A. Tarantilis3E. Kontaxakis4S. Kallithraka5Laboratory of Oenology, Department of Food Science & Human Nutrition, Agricultural University of Athens, 75 Iera Odos, 11855 Athens, GreeceLaboratory of Chemistry, Department of Food Science & Human Nutrition, Agricultural University of Athens, 75 Iera Odos, 11855 Athens, GreeceLaboratory of Oenology, Department of Food Science & Human Nutrition, Agricultural University of Athens, 75 Iera Odos, 11855 Athens, GreeceLaboratory of Chemistry, Department of Food Science & Human Nutrition, Agricultural University of Athens, 75 Iera Odos, 11855 Athens, GreeceDepartment of Agriculture, School of Agriculture, Food and Nutrition, Technological Educational Institute of Crete, Estavromenos, 71004 Heraklion, GreeceLaboratory of Oenology, Department of Food Science & Human Nutrition, Agricultural University of Athens, 75 Iera Odos, 11855 Athens, GreeceColor, phenolic content, and chemical age values of red wines made from Cretan grape varieties (Kotsifali, Mandilari) were evaluated over nine months of maturation in different containers for two vintages. The wines differed greatly on their anthocyanin profiles. Mid-IR spectra were also recorded with the use of a Fourier Transform Infrared Spectrophotometer in ZnSe disk mode. Analysis of Variance was used to explore the parameter’s dependency on time. Determination models were developed for the chemical age indexes using Partial Least Squares (PLS) (TQ Analyst software) considering the spectral region 1830–1500 cm−1. The correlation coefficients (r) for chemical age index i were 0.86 for Kotsifali (Root Mean Square Error of Calibration (RMSEC) = 0.067, Root Mean Square Error of Prediction (RMSEP) = 0,115, and Root Mean Square Error of Validation (RMSECV) = 0.164) and 0.90 for Mandilari (RMSEC = 0.050, RMSEP = 0.040, and RMSECV = 0.089). For chemical age index ii the correlation coefficients (r) were 0.86 and 0.97 for Kotsifali (RMSEC 0.044, RMSEP = 0.087, and RMSECV = 0.214) and Mandilari (RMSEC = 0.024, RMSEP = 0.033, and RMSECV = 0.078), respectively. The proposed method is simpler, less time consuming, and more economical and does not require chemical reagents.http://dx.doi.org/10.1155/2017/5767613
spellingShingle M. Basalekou
C. Pappas
Y. Kotseridis
P. A. Tarantilis
E. Kontaxakis
S. Kallithraka
Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation Time
Journal of Analytical Methods in Chemistry
title Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation Time
title_full Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation Time
title_fullStr Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation Time
title_full_unstemmed Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation Time
title_short Red Wine Age Estimation by the Alteration of Its Color Parameters: Fourier Transform Infrared Spectroscopy as a Tool to Monitor Wine Maturation Time
title_sort red wine age estimation by the alteration of its color parameters fourier transform infrared spectroscopy as a tool to monitor wine maturation time
url http://dx.doi.org/10.1155/2017/5767613
work_keys_str_mv AT mbasalekou redwineageestimationbythealterationofitscolorparametersfouriertransforminfraredspectroscopyasatooltomonitorwinematurationtime
AT cpappas redwineageestimationbythealterationofitscolorparametersfouriertransforminfraredspectroscopyasatooltomonitorwinematurationtime
AT ykotseridis redwineageestimationbythealterationofitscolorparametersfouriertransforminfraredspectroscopyasatooltomonitorwinematurationtime
AT patarantilis redwineageestimationbythealterationofitscolorparametersfouriertransforminfraredspectroscopyasatooltomonitorwinematurationtime
AT ekontaxakis redwineageestimationbythealterationofitscolorparametersfouriertransforminfraredspectroscopyasatooltomonitorwinematurationtime
AT skallithraka redwineageestimationbythealterationofitscolorparametersfouriertransforminfraredspectroscopyasatooltomonitorwinematurationtime