Development and Research of Ion Optics Digital Simulation System for EI Source

The ion optical system is an important component of electron impact (EI) ion source, which uses electrostatic lens to extract ions in the ion chamber, further focus, accelerate and shape, and regulate the speed and energy of the ion beam. The performance of the ion optical system will directly affec...

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Main Authors: Li-na YANG, Xing-chuang XIONG, Zi-long LIU, Xiang FANG
Format: Article
Language:English
Published: Editorial Board of Journal of Chinese Mass Spectrometry Society 2025-01-01
Series:Zhipu Xuebao
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Online Access:https://zpxb.xml-journal.net/article/doi/10.7538/zpxb.2024.0067
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author Li-na YANG
Xing-chuang XIONG
Zi-long LIU
Xiang FANG
author_facet Li-na YANG
Xing-chuang XIONG
Zi-long LIU
Xiang FANG
author_sort Li-na YANG
collection DOAJ
description The ion optical system is an important component of electron impact (EI) ion source, which uses electrostatic lens to extract ions in the ion chamber, further focus, accelerate and shape, and regulate the speed and energy of the ion beam. The performance of the ion optical system will directly affect the sensitivity and stability of the mass spectrometer. Based on the digital simulation, the ion optical system of EI source can be used to track the movement trajectory of ions from generation to the moment before entering the mass analyzer, which is helpful to deeply understand and recognize the dynamic behavior of ions in the system, and study the key influencing factors of ion movement. In this paper, the ion optical digital simulation system of EI source named Sim-EI-Lens-COM-V1.0 was developed. The geometric structure of each component in the simulation system can be uniformly configured and modified, which is suitable for the simulation of different types of ion optical systems. Based on the developed simulation system, two kinds of typical ion optics with cylindrical and sheet lenses were constructed. The key factors affecting the ion transport efficiency, such as geometric size and voltage parameter of each component in the simulation system, the species and total number of ions produced, and the time of the ion to pass through the system, were studied. Firstly, the influences of the electrostatic lens thickness on the ion dynamic behavior and transport efficiency were investigated. Then appropriate number and initial distribution of ions were selected, and the parametric scanning calculations of the voltage parameters were carried out. Through coarse, fine and precise adjustment of different voltage step values, the optimal voltage combinations of two typical ion optics systems were achieved. The performances of the two ion optical systems were compared under the optimal voltage combination. The result showed that the ion transmission in cylindrical lens ion optical system can reach to 97%, and it can reach more than 99% in sheet lens. The time for ions to pass through the system increases with the increasing of ion mass-charge ratio. The time to pass through the cylindrical lens is shorter than that of the sheet lens under the same ion mass-charge ratio. The radial energy distributions of ions at the outlet of the two ions optical systems are similar, and the axial energy distribution at the outlet of the sheet lens is more concentrated with higher consistency.
format Article
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institution Kabale University
issn 1004-2997
language English
publishDate 2025-01-01
publisher Editorial Board of Journal of Chinese Mass Spectrometry Society
record_format Article
series Zhipu Xuebao
spelling doaj-art-fca051cdc20a48a09136cb36d558c0722025-01-22T02:33:54ZengEditorial Board of Journal of Chinese Mass Spectrometry SocietyZhipu Xuebao1004-29972025-01-01461889610.7538/zpxb.2024.00672024-067-c3Development and Research of Ion Optics Digital Simulation System for EI SourceLi-na YANG0Xing-chuang XIONG1Zi-long LIU2Xiang FANG3National Institute of Metrology, Beijing 100029, ChinaNational Institute of Metrology, Beijing 100029, ChinaNational Institute of Metrology, Beijing 100029, ChinaNational Institute of Metrology, Beijing 100029, ChinaThe ion optical system is an important component of electron impact (EI) ion source, which uses electrostatic lens to extract ions in the ion chamber, further focus, accelerate and shape, and regulate the speed and energy of the ion beam. The performance of the ion optical system will directly affect the sensitivity and stability of the mass spectrometer. Based on the digital simulation, the ion optical system of EI source can be used to track the movement trajectory of ions from generation to the moment before entering the mass analyzer, which is helpful to deeply understand and recognize the dynamic behavior of ions in the system, and study the key influencing factors of ion movement. In this paper, the ion optical digital simulation system of EI source named Sim-EI-Lens-COM-V1.0 was developed. The geometric structure of each component in the simulation system can be uniformly configured and modified, which is suitable for the simulation of different types of ion optical systems. Based on the developed simulation system, two kinds of typical ion optics with cylindrical and sheet lenses were constructed. The key factors affecting the ion transport efficiency, such as geometric size and voltage parameter of each component in the simulation system, the species and total number of ions produced, and the time of the ion to pass through the system, were studied. Firstly, the influences of the electrostatic lens thickness on the ion dynamic behavior and transport efficiency were investigated. Then appropriate number and initial distribution of ions were selected, and the parametric scanning calculations of the voltage parameters were carried out. Through coarse, fine and precise adjustment of different voltage step values, the optimal voltage combinations of two typical ion optics systems were achieved. The performances of the two ion optical systems were compared under the optimal voltage combination. The result showed that the ion transmission in cylindrical lens ion optical system can reach to 97%, and it can reach more than 99% in sheet lens. The time for ions to pass through the system increases with the increasing of ion mass-charge ratio. The time to pass through the cylindrical lens is shorter than that of the sheet lens under the same ion mass-charge ratio. The radial energy distributions of ions at the outlet of the two ions optical systems are similar, and the axial energy distribution at the outlet of the sheet lens is more concentrated with higher consistency.https://zpxb.xml-journal.net/article/doi/10.7538/zpxb.2024.0067electron impact (ei) ion sourceion opticselectrostatic lenstransmission efficiency
spellingShingle Li-na YANG
Xing-chuang XIONG
Zi-long LIU
Xiang FANG
Development and Research of Ion Optics Digital Simulation System for EI Source
Zhipu Xuebao
electron impact (ei) ion source
ion optics
electrostatic lens
transmission efficiency
title Development and Research of Ion Optics Digital Simulation System for EI Source
title_full Development and Research of Ion Optics Digital Simulation System for EI Source
title_fullStr Development and Research of Ion Optics Digital Simulation System for EI Source
title_full_unstemmed Development and Research of Ion Optics Digital Simulation System for EI Source
title_short Development and Research of Ion Optics Digital Simulation System for EI Source
title_sort development and research of ion optics digital simulation system for ei source
topic electron impact (ei) ion source
ion optics
electrostatic lens
transmission efficiency
url https://zpxb.xml-journal.net/article/doi/10.7538/zpxb.2024.0067
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AT xingchuangxiong developmentandresearchofionopticsdigitalsimulationsystemforeisource
AT zilongliu developmentandresearchofionopticsdigitalsimulationsystemforeisource
AT xiangfang developmentandresearchofionopticsdigitalsimulationsystemforeisource