Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex
Polyethylene glycol (PEG) mediated kinetic study of nitro decarboxylation of α,β-unsaturated acids (USA) has been taken up by Blau’s [Fe(III) nitrate-Phen] yellow complex in acetonitrile medium. Kinetics of the reactions indicated Michaelis-Menton type of mechanism and rate law. Reaction rates are s...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/703271 |
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| author | K. Ramesh S. Shylaja K. C. Rajanna P. Giridhar Reddy P. K. Saiprakash |
| author_facet | K. Ramesh S. Shylaja K. C. Rajanna P. Giridhar Reddy P. K. Saiprakash |
| author_sort | K. Ramesh |
| collection | DOAJ |
| description | Polyethylene glycol (PEG) mediated kinetic study of nitro decarboxylation of α,β-unsaturated acids (USA) has been taken up by Blau’s [Fe(III) nitrate-Phen] yellow complex in acetonitrile medium. Kinetics of the reactions indicated Michaelis-Menton type of mechanism and rate law. Reaction rates are significantly influenced by the structural variation and concentration of PEG. Catalysis of PEG was explained on the lines of nonionic micelles such as TX-100 because of their structural resemblance and also due to a slight negative charge developed on polyoxyethylene and cationic form(s) of Fe(III) chelates in the intermediate stages. |
| format | Article |
| id | doaj-art-fc8f601ea50d4a9490d079928943d315 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-fc8f601ea50d4a9490d079928943d3152025-02-03T01:07:20ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/703271703271Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen ComplexK. Ramesh0S. Shylaja1K. C. Rajanna2P. Giridhar Reddy3P. K. Saiprakash4Department of Chemistry, CBIT, Gandipet, Hyderabad 500 075, IndiaDepartment of Chemistry, CBIT, Gandipet, Hyderabad 500 075, IndiaDepartment of Chemistry, Osmania University, Hyderabad 500 007, IndiaDepartment of Chemistry, CBIT, Gandipet, Hyderabad 500 075, IndiaDepartment of Chemistry, Osmania University, Hyderabad 500 007, IndiaPolyethylene glycol (PEG) mediated kinetic study of nitro decarboxylation of α,β-unsaturated acids (USA) has been taken up by Blau’s [Fe(III) nitrate-Phen] yellow complex in acetonitrile medium. Kinetics of the reactions indicated Michaelis-Menton type of mechanism and rate law. Reaction rates are significantly influenced by the structural variation and concentration of PEG. Catalysis of PEG was explained on the lines of nonionic micelles such as TX-100 because of their structural resemblance and also due to a slight negative charge developed on polyoxyethylene and cationic form(s) of Fe(III) chelates in the intermediate stages.http://dx.doi.org/10.1155/2013/703271 |
| spellingShingle | K. Ramesh S. Shylaja K. C. Rajanna P. Giridhar Reddy P. K. Saiprakash Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex Journal of Chemistry |
| title | Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex |
| title_full | Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex |
| title_fullStr | Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex |
| title_full_unstemmed | Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex |
| title_short | Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex |
| title_sort | polyethylene glycol mediated kinetic study of nitro decarboxylation of α β unsaturated acids by blau s fe iii phen complex |
| url | http://dx.doi.org/10.1155/2013/703271 |
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