Graphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interaction

Abstract Preventing and controlling agricultural non-point-source pollution, advancing the agricultural industry, and facilitating cation–π interaction to address cation instability and fertilizer loss are crucial for advancing agricultural sustainability. Due to the unique π-bond characteristics of...

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Main Authors: Wei Zhang, Yijia He, Hongwei Zhu, Xiao Li, Zucai Zou, Chaogui Luo, Jianlie Wei, Baoying Lu, Duo Zhang, Ming Zhou
Format: Article
Language:English
Published: Nature Portfolio 2025-02-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-87696-z
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author Wei Zhang
Yijia He
Hongwei Zhu
Xiao Li
Zucai Zou
Chaogui Luo
Jianlie Wei
Baoying Lu
Duo Zhang
Ming Zhou
author_facet Wei Zhang
Yijia He
Hongwei Zhu
Xiao Li
Zucai Zou
Chaogui Luo
Jianlie Wei
Baoying Lu
Duo Zhang
Ming Zhou
author_sort Wei Zhang
collection DOAJ
description Abstract Preventing and controlling agricultural non-point-source pollution, advancing the agricultural industry, and facilitating cation–π interaction to address cation instability and fertilizer loss are crucial for advancing agricultural sustainability. Due to the unique π-bond characteristics of GO (graphene oxide), it was selected as a cation carrier to improve fertilizer anti-loss capabilities and facilitate the effective release of nutrient ions. By adjusting the interface properties of GO, RGO (rippled graphene oxide) and CGO (crumpled graphene oxide) were successfully prepared, and their interactions with cations and the impact on sustained-release performance were studied. The selected optimal kinetic model provides a theoretical basis for material design. The results indicate that RGO-Zn1 (Zn2+/RGO = 16.7%) can not only effectively control agricultural non-point source pollution but also promote the cultivation of high-zinc rice. This study not only proposes an innovative solution for soil improvement and agricultural transformation and upgrading but also offers fundamental scientific insights into the cation-π interaction mechanism during transmembrane permeation.
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institution Kabale University
issn 2045-2322
language English
publishDate 2025-02-01
publisher Nature Portfolio
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series Scientific Reports
spelling doaj-art-fc2c48e561b84dcfa33c437f58d83d962025-02-09T12:36:20ZengNature PortfolioScientific Reports2045-23222025-02-0115111110.1038/s41598-025-87696-zGraphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interactionWei Zhang0Yijia He1Hongwei Zhu2Xiao Li3Zucai Zou4Chaogui Luo5Jianlie Wei6Baoying Lu7Duo Zhang8Ming Zhou9Guangxi University of Science and TechnologySchool of Materials Science and Engineering, Tsinghua UniversitySchool of Materials Science and Engineering, Tsinghua UniversityEconomic and Technological Development Zone, Chengdu Carbon Co., LtdGuangxi University of Science and TechnologyGuangxi TsingLube New Material TechnologyGuangxi Huanong Chuangke Modern Agricultural Technology Group Co., LtdGuangxi University of Science and TechnologyGuangxi University of Science and TechnologyGuangxi University of Science and TechnologyAbstract Preventing and controlling agricultural non-point-source pollution, advancing the agricultural industry, and facilitating cation–π interaction to address cation instability and fertilizer loss are crucial for advancing agricultural sustainability. Due to the unique π-bond characteristics of GO (graphene oxide), it was selected as a cation carrier to improve fertilizer anti-loss capabilities and facilitate the effective release of nutrient ions. By adjusting the interface properties of GO, RGO (rippled graphene oxide) and CGO (crumpled graphene oxide) were successfully prepared, and their interactions with cations and the impact on sustained-release performance were studied. The selected optimal kinetic model provides a theoretical basis for material design. The results indicate that RGO-Zn1 (Zn2+/RGO = 16.7%) can not only effectively control agricultural non-point source pollution but also promote the cultivation of high-zinc rice. This study not only proposes an innovative solution for soil improvement and agricultural transformation and upgrading but also offers fundamental scientific insights into the cation-π interaction mechanism during transmembrane permeation.https://doi.org/10.1038/s41598-025-87696-zNon-point-source pollutionGOSustained-release performanceTransmembrane permeationCation-π interactions
spellingShingle Wei Zhang
Yijia He
Hongwei Zhu
Xiao Li
Zucai Zou
Chaogui Luo
Jianlie Wei
Baoying Lu
Duo Zhang
Ming Zhou
Graphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interaction
Scientific Reports
Non-point-source pollution
GO
Sustained-release performance
Transmembrane permeation
Cation-π interactions
title Graphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interaction
title_full Graphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interaction
title_fullStr Graphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interaction
title_full_unstemmed Graphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interaction
title_short Graphene oxide and its derivatives films for sustained-release trace element zinc based on cation-π interaction
title_sort graphene oxide and its derivatives films for sustained release trace element zinc based on cation π interaction
topic Non-point-source pollution
GO
Sustained-release performance
Transmembrane permeation
Cation-π interactions
url https://doi.org/10.1038/s41598-025-87696-z
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