Synthesis, crystal structure and Hirshfeld surface analysis of 5,5-diphenyl-2-[2-(propan-2-ylidene)hydrazin-1-yl]-4,5-dihydro-1H-imidazol-4-one N,N-dimethylformamide hemisolvate

Synthesis, crystal structure and Hirshfeld surface analysis of 5,5-diphenyl-2-[2-(propan-2-ylidene)hydrazin-1-yl]-4,5-dihydro-1H-imidazol-4-one N,N-dimethylformamide hemisolvate

The asymmetric unit of the title structure, 2C18H18N4O2·C3H7NO, consists of two independent molecules of the substituted imidazolone having different conformations, and one molecule of solvent DMF. The two imidazolone molecules are linked by N—H...N and C—H...O hydrogen bonds and the DMF is joined t...

Full description

Saved in:

Bibliographic Details
Main Authors:	Abderrazzak El Moutaouakil Ala Allah, Benson M. Kariuki, Walid Guerrab, Abdulsalam Alsubari, Musa A. Said, Joel T. Mague, Youssef Ramli
Format:	Article
Language:	English
Published:	International Union of Crystallography 2025-02-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure hydrogen bond dihydroimidazolone c—h...π (ring) interaction
Online Access:	https://journals.iucr.org/paper?S2056989025000076
Tags:	Add Tag No Tags, Be the first to tag this record!

Similar Items

The crystal structure of (9H-thioxanthen-9- ylidene)hydrazine monohydrate, C13H11N2SO0.5
by: Zhou Qi, et al.
Published: (2025-02-01)

Crystal structure and Hirshfeld surface analysis of N-(4-nitrophenyl)-2-(piperidin-1-yl)acetamide (lidocaine analogue)
by: Imane Maimoune, et al.
Published: (2025-01-01)

The crystal structure of dichlorido-[(E)-N′,N″-bis((2E,3E)-3-(hydroxyimino)butan-2-ylidene)-2-((E)-3-(hydroxyimino)butan-2-ylidene)hydrazine-1-carbohydrazonhydrazide-κ 4 N 4]cobalt(II), C13H22N9O3Cl2Co
by: Zhai Zhi-Wei, et al.
Published: (2025-02-01)

Crystal structure of 2-(3,5,5-trimethylcyclohex-2-en-1-ylidene)malononitrile, C12H14N2
by: Liu Yingfan, et al.
Published: (2023-10-01)

Total Electrosynthesis of N, N‐Dimethylformamide From CO2 and NO3−
by: Shuai Yan, et al.
Published: (2025-01-01)

Synthesis and Pharmacological Evaluation of 2-(4-Halosubstituted phenyl)-4,5-diphenyl-1H-imidazoles
by: G. Nagalakshmi
Published: (2008-01-01)

(E)-2-((E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-ylidene)hydrazine-1-carbothioamide C14H23N3S1
by: Rong Zeng, et al.
Published: (2023-10-01)

Crystal structure of (E)-2-amino-N′-((3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene)benzohydrazide – dimethylformamide – water (1/1/2), C15H16N4O3·C3H7NO·2H2O
by: Wang Xue, et al.
Published: (2023-10-01)

Theoretical Calculations and Molecular Docking Analysis of 4-(2-(4-Bromophenyl)Hydrazineylidene)-3,5-Diphenyl-4H-Pyrazole Molecule
by: Ümit Yıldıko, et al.
Published: (2024-12-01)

Crystal structure of (Z)-4-(((4-bromophenyl)amino)(furan-2-yl)methylene)-2,5-diphenyl-2,4-dihydro-3H-pyrazol-3-one, C26H18BrN3O2
by: Li Zhang, et al.
Published: (2022-08-01)

The crystal structure of 2,5,5-triphenyl-3,5-dihydro-4H-imidazol-4-one, C21H16N2O
by: Wang De-Xing, et al.
Published: (2022-08-01)

Crystal structure of (Z)-N-(4-(4-(4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenoxy)butoxy)phenyl)acetamide, C30H31NO8
by: Xu Lian-Hua, et al.
Published: (2023-10-01)

The crystal structure of 2,5-bis(3,5-dimethylphenyl)thiazolo[5,4-d]thiazole, C20H18N2S2
by: Zhai Zhi-Wei, et al.
Published: (2021-09-01)

Crystal structure of 2-[(4-bromobenzyl)thio]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C13H8Br2N2OS2
by: Al-Omary Fatmah A. M., et al.
Published: (2023-10-01)

Crystal structure of 1H-1,2,3-Triazolo[4,5-b]-pyridin-4-ium nitrate, C5H5N5O3
by: Zhou Meng-Shu, et al.
Published: (2022-08-01)

Crystal structure of catena-poly[(5,5,7,12,12,14-hexamethyl -1,4,8,11-tetraazacyclotetradecane- κ4N,N′,Nʺ,N‴)nickel(II)-(μ2-perchlorato-κ2O:O′)] 3,5-dicarboxybenzoate – methanol (1/2), C27H49ClN4NiO12
by: Wang Qiong, et al.
Published: (2022-08-01)

Cardioprotective Activity of N′′,N′′′-Bis[5-methyl-2-oxo-1,2-dihydro-3H-indol-3-ylidene]carbonohydrazide Derivative against Doxorubicin Induced Cardiotoxicity in Rats
by: Salma Tabassum, et al.
Published: (2014-01-01)

Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene-N,N′-bis(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-1,3,2-diazaborol-2-yl)-l2-germenediamine, C63H94B2GeN8
by: Wang Bing, et al.
Published: (2023-10-01)

Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-bis(propan-2-yl)-1H-pyrazol-4-amine, C26H36N6
by: Fujisawa Kiyoshi, et al.
Published: (2023-10-01)

Crystal structure and Hirshfeld surface analysis of 1,3,3,4,4,5,5-heptafluoro-2-(3-[(2,3,3,4,4,5,5-heptafluorocyclopenten-1-yl)oxy]-2-{[(2,3,3,4,4,5,5-heptafluorocyclopenten-1-yl)oxy]methyl}-2-methylpropoxy)cyclopentene
by: Andrew J. Peloquin, et al.
Published: (2025-01-01)

Line and surface defects in 5D $$N=2$$ N = 2 SCFT from matter-coupled F(4) gauged supergravity
by: Parinya Karndumri
Published: (2024-12-01)

The crystal structure of [μ-hydroxido-bis[(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)-tricarbonylrhenium(I)] bromide hemihydrate, C30H26N4O9Re2Br
by: Moherane Lehlohonolo, et al.
Published: (2021-09-01)

Crystal structure of 2-(1H-pyrazol-3-yl-κN)pyridine-κN-bis(2-(2,4-difluorophenyl)pyridinato-κ2C,N)iridium(III) sesquihydrate, C30H18F4IrN5·1.5[H2O]
by: Abdul Latiff Aqilah, et al.
Published: (2022-08-01)

Synthesis, Characterization and Antitumor Activity of cis-bis(acylthioureato) platinum(II) Complexes, cis-[PtL2] [HL1=N,N-Diphenyl-N'-Benzoylthiourea or HL2=N,N-diphenyl-N'-(p-nitrobenzoyl)thiourea]
by: Wilfredo Hernández, et al.
Published: (2003-01-01)

The crystal structure of (1E,2E)-1,2-bis(quinolin-2-ylmethylene)hydrazine, C20H14N4
by: Liao Fuguang, et al.
Published: (2023-08-01)

The crystal structure of 5-amino-1-methyl-4-nitroimidazole, C4H6O2N4
by: Cai Cao, et al.
Published: (2023-10-01)

Crystal structure of (glycinto-κ 2 O,N ′)-[5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ 4 N,N ′,N ″,N ‴]nickel(II) perchlorate monohydrate C18H42ClN5NiO7
by: Zhang Zu-Jiao, et al.
Published: (2023-08-01)

Synthesis and crystal structure of 2,2,2-trichloroethyl N-{4-[6-(1-hydroxyethyl)-1,2,4,5-tetrazin-3-yl]benzyl}carbamate
by: J. Voss, et al.
Published: (2025-02-01)

Crystal structure of the dihydrate of tetraethylammonium 1,3,5-thiadiazole-5-amido-2-carbamate, C11H27N5O4S
by: Tan Xiaoke, et al.
Published: (2022-08-01)

Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex
by: Hakan Arslan, et al.
Published: (2011-01-01)

Synthesis, crystal structure and Hirshfeld surface analysis of 5-oxo-N-phenyl-3-(thiophen-2-yl)-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxamide
by: Khatira N. Aliyeva, et al.
Published: (2025-02-01)

The crystal structure of diaqua-(naphthalene-4,5-dicarboxylate-1,8-dicarboxylic anhydride-κ1O)-(4′-(4-(1H-benzimidazolyl-1-yl)phenyl)-2,2′:6′,2″-terpyridine-κ3N,N′,N″)–manganese(II) dihydrate, C42H27MnN5O9·2H2O
by: Liu Xinyao, et al.
Published: (2023-10-01)

The crystal structure of (2,2′-bipyridine-κ2N,N′)- bis(6-phenylpyridine-2-carboxylate-κ2N,O)manganese(II)] monohydrate, C34H26N4O5Mn
by: Tai Xi-Shi, et al.
Published: (2022-08-01)

Crystal structure of bis(5-amino-1,2,4-triazol-4-ium-3-yl)methane sulfate, C5H10N8O4S
by: Zhang Guo-Tao, et al.
Published: (2022-08-01)

Synthesis and Biological Activity of (Z) –n-(5-Benzylidene-4-oxo-2-substituted- phenylthiazolidin-3-yl)-5-((1, 3-dioxoisoindolin-2-yl)methyl)-2-hydroxybenzamide
by: M. C. Patel, et al.
Published: (2010-01-01)

Crystal structure of N′,N′′′-((1E,1′E)-(propane-2,2-diylbis(1H-pyrrole-5,2diyl))bis(methaneylylidene))di(nicotinohydrazide) pentahydrate, C25H24N8O2·5H2O
by: Zhou Yi, et al.
Published: (2021-09-01)

Crystal structure of catena-poly[diaqua-bis(μ2-4,4′-bipyridyl-κ2N:N′) disilver(I)] 4-oxidopyridine-3-sulfonate trihydrate, C25H29Ag2N5O9S
by: Zhao Han-Lin, et al.
Published: (2021-09-01)

Crystal structure of poly[aqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)-(μ3-2,3,5,6-tetrafluoroterephthalato-κ3O:O′:O′′)cadmium(II)], C17H14N4O5F4Cd
by: Guo Yu-Mei, et al.
Published: (2021-09-01)

Synthesis of N-[{5-Aryl-1,3,4-oxadiazole-2-yl}methyl]-4-methoxyaniline Derivatives and Their Anticonvulsant Activity
by: B. N. Prasanna Kumar, et al.
Published: (2013-01-01)

The structure of t-butyl 7-[2-(4-fluorophenyl)-3-phenyl-4-(phenylcarbamoyl)-5-(propan-2-yl)-1H-pyrrol-1-yl]-3,5-dihydroxyheptanoate, C37H43FN2O5
by: Sun Wei-Jie, et al.
Published: (2025-02-01)