SERS nose arrays based on a signal differentiation approach for TNT gas detection

Abstract TNT, a well-known explosive, is highly toxic and difficult to decompose, making the detection of trace amounts of residual TNT in the environment a topic of significant research importance. Label-free surface-enhanced Raman spectroscopy (SERS) has been demonstrated to be capable of capturin...

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Main Authors: Peitao Dong, Haiyang Yang, Tianran Wang, Siyue Xiong, Li Kuang, Weihong Qi, Xiaohua Chen, Lixia Yang, Qiuyun Fan, Dingbang Xiao, Xuezhong Wu
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-025-01656-2
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author Peitao Dong
Haiyang Yang
Tianran Wang
Siyue Xiong
Li Kuang
Weihong Qi
Xiaohua Chen
Lixia Yang
Qiuyun Fan
Dingbang Xiao
Xuezhong Wu
author_facet Peitao Dong
Haiyang Yang
Tianran Wang
Siyue Xiong
Li Kuang
Weihong Qi
Xiaohua Chen
Lixia Yang
Qiuyun Fan
Dingbang Xiao
Xuezhong Wu
author_sort Peitao Dong
collection DOAJ
description Abstract TNT, a well-known explosive, is highly toxic and difficult to decompose, making the detection of trace amounts of residual TNT in the environment a topic of significant research importance. Label-free surface-enhanced Raman spectroscopy (SERS) has been demonstrated to be capable of capturing rich compositional information from the sample being tested. Here we show a SERS nose array that contains six individual SERS substrates composed of different components based on a signal differentiation approach (SD-SERS arrays). In this strategy, the SD-SERS arrays integrate differentiated signal structures, physically enhanced structures, and structures with varied adsorption capabilities. Through the differentiated information obtained from SD-SERS arrays, further integration with machine learning algorithms demonstrates the high accuracy of SD-SERS arrays in classifying TNT and structurally similar 2,4-DNPA, as well as in distinguishing between gases at different concentrations. The SERS nose based on SD-SERS arrays presents a convenient and broadly applicable technology with great potential for substance classification and concentration categorization.
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institution Kabale University
issn 2399-3669
language English
publishDate 2025-08-01
publisher Nature Portfolio
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series Communications Chemistry
spelling doaj-art-fb4fb5408f504c13b2f1262f9af552552025-08-24T11:12:22ZengNature PortfolioCommunications Chemistry2399-36692025-08-018111410.1038/s42004-025-01656-2SERS nose arrays based on a signal differentiation approach for TNT gas detectionPeitao Dong0Haiyang Yang1Tianran Wang2Siyue Xiong3Li Kuang4Weihong Qi5Xiaohua Chen6Lixia Yang7Qiuyun Fan8Dingbang Xiao9Xuezhong Wu10College of Intelligence Science and Technology, National University of Defense TechnologySchool of Computer Science and Engineering, Central South UniversityCollege of Intelligence Science and Technology, National University of Defense TechnologyCollege of Intelligence Science and Technology, National University of Defense TechnologySchool of Computer Science and Engineering, Central South UniversityState Key Laboratory of Solidification Processing and Center of Advanced Lubrication and Seal Materials, Northwestern Polytechnical UniversityDepartment of Laboratory Medicine, General Hospital of Central Theater CommandChangsha Institute for Food and Drug ControlHunan Changsha Ecological and Environmental Monitoring CenterCollege of Intelligence Science and Technology, National University of Defense TechnologyCollege of Intelligence Science and Technology, National University of Defense TechnologyAbstract TNT, a well-known explosive, is highly toxic and difficult to decompose, making the detection of trace amounts of residual TNT in the environment a topic of significant research importance. Label-free surface-enhanced Raman spectroscopy (SERS) has been demonstrated to be capable of capturing rich compositional information from the sample being tested. Here we show a SERS nose array that contains six individual SERS substrates composed of different components based on a signal differentiation approach (SD-SERS arrays). In this strategy, the SD-SERS arrays integrate differentiated signal structures, physically enhanced structures, and structures with varied adsorption capabilities. Through the differentiated information obtained from SD-SERS arrays, further integration with machine learning algorithms demonstrates the high accuracy of SD-SERS arrays in classifying TNT and structurally similar 2,4-DNPA, as well as in distinguishing between gases at different concentrations. The SERS nose based on SD-SERS arrays presents a convenient and broadly applicable technology with great potential for substance classification and concentration categorization.https://doi.org/10.1038/s42004-025-01656-2
spellingShingle Peitao Dong
Haiyang Yang
Tianran Wang
Siyue Xiong
Li Kuang
Weihong Qi
Xiaohua Chen
Lixia Yang
Qiuyun Fan
Dingbang Xiao
Xuezhong Wu
SERS nose arrays based on a signal differentiation approach for TNT gas detection
Communications Chemistry
title SERS nose arrays based on a signal differentiation approach for TNT gas detection
title_full SERS nose arrays based on a signal differentiation approach for TNT gas detection
title_fullStr SERS nose arrays based on a signal differentiation approach for TNT gas detection
title_full_unstemmed SERS nose arrays based on a signal differentiation approach for TNT gas detection
title_short SERS nose arrays based on a signal differentiation approach for TNT gas detection
title_sort sers nose arrays based on a signal differentiation approach for tnt gas detection
url https://doi.org/10.1038/s42004-025-01656-2
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