Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer

The presence of the metal compounds in the acryle-nitrile nanopolimer (PPAN) leads to the formation of the metal nanoparticles. The metal-carbon nanocomposites based on PPAN including pair connections with iron and cobalt has been theoretically investigated. The spatial configuration of the nanocomp...

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Main Authors: I.V. Zaporotskova, N.A. Anikeev, L.V. Kojitov, O.A. Davletova, A.V. Popkova
Format: Article
Language:English
Published: Sumy State University 2014-07-01
Series:Журнал нано- та електронної фізики
Subjects:
Online Access:http://jnep.sumdu.edu.ua/download/numbers/2014/3/articles/jnep_2014_V6_03035.pdf
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author I.V. Zaporotskova
N.A. Anikeev
L.V. Kojitov
O.A. Davletova
A.V. Popkova
author_facet I.V. Zaporotskova
N.A. Anikeev
L.V. Kojitov
O.A. Davletova
A.V. Popkova
author_sort I.V. Zaporotskova
collection DOAJ
description The presence of the metal compounds in the acryle-nitrile nanopolimer (PPAN) leads to the formation of the metal nanoparticles. The metal-carbon nanocomposites based on PPAN including pair connections with iron and cobalt has been theoretically investigated. The spatial configuration of the nanocomposite for each option of the arrangement of metal atoms has been received. The analysis of the received results for all options of the arrangement of the metal atoms allowed defining the binding energy of the systems and the width of the forbidden gap ΔЕg of the nanocomposite. The analysis of the electronic and energy structures of the system found out that the introduction of the metal atoms leaded to the essential reduction of the width of the forbidden zone of the composite in comparison with the pure PPAN.
format Article
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issn 2077-6772
language English
publishDate 2014-07-01
publisher Sumy State University
record_format Article
series Журнал нано- та електронної фізики
spelling doaj-art-faedb8dbdb2842feb89afcf69c24b4d72025-08-20T03:06:01ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722014-07-016303035-103035-3Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile NanopolimerI.V. Zaporotskova0N.A. Anikeev1L.V. Kojitov2O.A. Davletova3A.V. Popkova4Volgograd state University, 100, University Av., 400062 Volgograd, RussiaMoscow Institute of Steel and Alloys, 4, Leninskiy Pr., 119049 Moscow, RussiaVolgograd state University, 100, University Av., 400062 Volgograd, RussiaVolgograd state University, 100, University Av., 400062 Volgograd, RussiaVolgograd state University, 100, University Av., 400062 Volgograd, RussiaThe presence of the metal compounds in the acryle-nitrile nanopolimer (PPAN) leads to the formation of the metal nanoparticles. The metal-carbon nanocomposites based on PPAN including pair connections with iron and cobalt has been theoretically investigated. The spatial configuration of the nanocomposite for each option of the arrangement of metal atoms has been received. The analysis of the received results for all options of the arrangement of the metal atoms allowed defining the binding energy of the systems and the width of the forbidden gap ΔЕg of the nanocomposite. The analysis of the electronic and energy structures of the system found out that the introduction of the metal atoms leaded to the essential reduction of the width of the forbidden zone of the composite in comparison with the pure PPAN.http://jnep.sumdu.edu.ua/download/numbers/2014/3/articles/jnep_2014_V6_03035.pdfMetal-carbon nanocompositeCarbon matrixPair connectionAcryle-nitrile nanopolime
spellingShingle I.V. Zaporotskova
N.A. Anikeev
L.V. Kojitov
O.A. Davletova
A.V. Popkova
Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer
Журнал нано- та електронної фізики
Metal-carbon nanocomposite
Carbon matrix
Pair connection
Acryle-nitrile nanopolime
title Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer
title_full Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer
title_fullStr Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer
title_full_unstemmed Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer
title_short Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer
title_sort theoretical studies of the structure of the metal carbon composites on the base of acryle nitrile nanopolimer
topic Metal-carbon nanocomposite
Carbon matrix
Pair connection
Acryle-nitrile nanopolime
url http://jnep.sumdu.edu.ua/download/numbers/2014/3/articles/jnep_2014_V6_03035.pdf
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AT lvkojitov theoreticalstudiesofthestructureofthemetalcarboncompositesonthebaseofacrylenitrilenanopolimer
AT oadavletova theoreticalstudiesofthestructureofthemetalcarboncompositesonthebaseofacrylenitrilenanopolimer
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