Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal Complexes
A novel Schiff base 2-{(E)-[(2,4-dichlorophenyl)imino]methyl}phenol (LB) was synthesized from the condensation reaction of 2,4-dichloroaniline with salicyladehyde in [1:1] ratio in the presence of glacial acetic acid as catalyst. Complexation reaction of this Schiff base with copper (II), cobalt (II...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/928162 |
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| author | Eman Turky Shamkhy Isam Hussain T. Al-Karkhi |
| author_facet | Eman Turky Shamkhy Isam Hussain T. Al-Karkhi |
| author_sort | Eman Turky Shamkhy |
| collection | DOAJ |
| description | A novel Schiff base 2-{(E)-[(2,4-dichlorophenyl)imino]methyl}phenol (LB) was synthesized from the condensation reaction of 2,4-dichloroaniline with salicyladehyde in [1:1] ratio in the presence of glacial acetic acid as catalyst. Complexation reaction of this Schiff base with copper (II), cobalt (II) as nitrate salts and with Rhodium (III) as chloride salt to produce three coordinate metal complexes, with a Schiff base: Metal ion ratio of 2:1. These compounds have been characterized by a variety of physico-chemical and spectroscopic techniques. The ligand and its metal complexes were expected to show an interesting bioactivity and cytotoxicity. |
| format | Article |
| id | doaj-art-fadfd768d7e84c74a3040d785e16739b |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-fadfd768d7e84c74a3040d785e16739b2025-02-03T01:13:12ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01931543154910.1155/2012/928162Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal ComplexesEman Turky Shamkhy0Isam Hussain T. Al-Karkhi1Department of Basic Science, College of Dentistry, University of Baghdad, Bab Al-Moazam, Baghdad, IraqDepartment of Basic Science, College of Dentistry, University of Baghdad, Bab Al-Moazam, Baghdad, IraqA novel Schiff base 2-{(E)-[(2,4-dichlorophenyl)imino]methyl}phenol (LB) was synthesized from the condensation reaction of 2,4-dichloroaniline with salicyladehyde in [1:1] ratio in the presence of glacial acetic acid as catalyst. Complexation reaction of this Schiff base with copper (II), cobalt (II) as nitrate salts and with Rhodium (III) as chloride salt to produce three coordinate metal complexes, with a Schiff base: Metal ion ratio of 2:1. These compounds have been characterized by a variety of physico-chemical and spectroscopic techniques. The ligand and its metal complexes were expected to show an interesting bioactivity and cytotoxicity.http://dx.doi.org/10.1155/2012/928162 |
| spellingShingle | Eman Turky Shamkhy Isam Hussain T. Al-Karkhi Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal Complexes E-Journal of Chemistry |
| title | Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal Complexes |
| title_full | Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal Complexes |
| title_fullStr | Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal Complexes |
| title_full_unstemmed | Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal Complexes |
| title_short | Synthesis, Characterization and Spectroscopic Studies of A Novel 2-[(E)-[(2,4-dichlorophenyl)imino]methyl]phenol Schiff Base and Its Metal Complexes |
| title_sort | synthesis characterization and spectroscopic studies of a novel 2 e 2 4 dichlorophenyl imino methyl phenol schiff base and its metal complexes |
| url | http://dx.doi.org/10.1155/2012/928162 |
| work_keys_str_mv | AT emanturkyshamkhy synthesischaracterizationandspectroscopicstudiesofanovel2e24dichlorophenyliminomethylphenolschiffbaseanditsmetalcomplexes AT isamhussaintalkarkhi synthesischaracterizationandspectroscopicstudiesofanovel2e24dichlorophenyliminomethylphenolschiffbaseanditsmetalcomplexes |