Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes
The synthesis and characterization of two new tetronic acid zinc (II) complexes of the empirical formulae [Zn(L–H)2(H2O)2] (1) and [Zn(L–H)2(H2O)(MeOH)]H2O (2) found within the same crystal are reported. The zinc ions bind through alkoxide and carbonyl groups of the ligand 3-methoxycarbonyl-5-pheny...
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| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2010/651652 |
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| author | K. C. Prousis G. Athanasellis V. Stefanou D. Matiadis E. Kokalari O. Igglessi-Markopoulou V. McKee J. Markopoulos |
| author_facet | K. C. Prousis G. Athanasellis V. Stefanou D. Matiadis E. Kokalari O. Igglessi-Markopoulou V. McKee J. Markopoulos |
| author_sort | K. C. Prousis |
| collection | DOAJ |
| description | The synthesis and characterization of two new tetronic acid zinc (II) complexes of the empirical formulae [Zn(L–H)2(H2O)2] (1) and [Zn(L–H)2(H2O)(MeOH)]H2O (2) found within the same crystal are reported. The zinc ions bind through alkoxide and carbonyl groups of the ligand 3-methoxycarbonyl-5-phenyl tetronic acid (LH) as indicated by H NMR and X-ray crystallographic studies. These complexes promote intra- and intermolecular interactions, such as hydrogen bonding and π stacking, giving place to the formation of molecular aggregates. |
| format | Article |
| id | doaj-art-fa94ce2b26774eb4a5c5a855cd0ca1b1 |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-fa94ce2b26774eb4a5c5a855cd0ca1b12025-02-03T01:20:58ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2010-01-01201010.1155/2010/651652651652Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid ComplexesK. C. Prousis0G. Athanasellis1V. Stefanou2D. Matiadis3E. Kokalari4O. Igglessi-Markopoulou5V. McKee6J. Markopoulos7Laboratory of Organic Chemistry, School of Chemical Engineering, National Technical University of Athens, 15773, Athens, GreeceLaboratory of Organic Chemistry, School of Chemical Engineering, National Technical University of Athens, 15773, Athens, GreeceLaboratory of Organic Chemistry, School of Chemical Engineering, National Technical University of Athens, 15773, Athens, GreeceLaboratory of Organic Chemistry, School of Chemical Engineering, National Technical University of Athens, 15773, Athens, GreeceLaboratory of Organic Chemistry, School of Chemical Engineering, National Technical University of Athens, 15773, Athens, GreeceLaboratory of Organic Chemistry, School of Chemical Engineering, National Technical University of Athens, 15773, Athens, GreeceChemistry Department, University of Loughborough, Leicestershire LE11 3TU, UKLaboratory of Inorganic Chemistry, Department of Chemistry, University of Athens, Panepistimiopolis, 15771 Athens, GreeceThe synthesis and characterization of two new tetronic acid zinc (II) complexes of the empirical formulae [Zn(L–H)2(H2O)2] (1) and [Zn(L–H)2(H2O)(MeOH)]H2O (2) found within the same crystal are reported. The zinc ions bind through alkoxide and carbonyl groups of the ligand 3-methoxycarbonyl-5-phenyl tetronic acid (LH) as indicated by H NMR and X-ray crystallographic studies. These complexes promote intra- and intermolecular interactions, such as hydrogen bonding and π stacking, giving place to the formation of molecular aggregates.http://dx.doi.org/10.1155/2010/651652 |
| spellingShingle | K. C. Prousis G. Athanasellis V. Stefanou D. Matiadis E. Kokalari O. Igglessi-Markopoulou V. McKee J. Markopoulos Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes Bioinorganic Chemistry and Applications |
| title | Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes |
| title_full | Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes |
| title_fullStr | Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes |
| title_full_unstemmed | Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes |
| title_short | Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes |
| title_sort | synthesis and crystal structure characterization of zinc ii tetronic acid complexes |
| url | http://dx.doi.org/10.1155/2010/651652 |
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