Development of eco friendly hybrid nanocomposites with improved antibacterial and mechanical properties through NaOH treated natural fibers

Nanoparticles have emerged as effective enhancers of polymer composite properties, particularly in improving mechanical strength and antibacterial resistance. However, challenges remain in optimizing natural fiber–matrix interfacial bonding and filler dispersion, which affect the overall performance...

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Bibliographic Details
Main Authors: Natrayan Lakshmaiya, M. Karthick, Kiran Bhaskar, Naga Dheeraj Kumar Reddy Chukka, Nimel Sworna Ross, Ramya Maranan
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Results in Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590123025010722
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Summary:Nanoparticles have emerged as effective enhancers of polymer composite properties, particularly in improving mechanical strength and antibacterial resistance. However, challenges remain in optimizing natural fiber–matrix interfacial bonding and filler dispersion, which affect the overall performance of hybrid composites. This study addresses the research gap by combining NaOH-treated coir and hemp fibers with SiO₂ and Al₂O₃ nanofillers to develop eco-friendly hybrid nanocomposites with superior mechanical and antibacterial properties. Natural fibers were alkali-treated with 5 wt. % NaOH for 4 h to enhance fiber–matrix adhesion, while nanoparticles were incorporated at varying loadings (0 to 10 wt. %) into the epoxy matrix. The composites were fabricated using compression molding. Mechanical characterization included flexural testing (ASTM D790) and hardness testing (ASTM E10), while antibacterial activity was evaluated using the well diffusion method against Staphylococcus aureus, Streptococcus mutans, Escherichia coli, and Klebsiella pneumoniae. The results demonstrated that 7.5 wt. % nanofiller addition yielded maximum performance, with a 240 % increase in flexural modulus and up to 41 % improvement in hardness for NaOH-treated fiber composites. Compared to untreated fibers, alkali-treated fibers showed a 16 % improvement in mechanical properties. Antibacterial testing revealed inhibition zones as high as 18 mm, confirming strong effectiveness against gram-positive and gram-negative bacteria. This study establishes a novel approach to hybrid nanocomposite design by integrating fiber surface treatment and dual nanofiller reinforcement, supporting the development of sustainable materials for protective, structural, and biomedical surface applications.
ISSN:2590-1230