Selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculations

Titanium and its alloys interstitially dissolve a large amount of impurities such as oxygen and nitrogen, which degrade the mechanical and physical properties of alloys. On the other hand crucible oxides based on CaO, ZrO2 Y2O3, etc., and their spinels (combination of two or more oxides) can be used...

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Main Authors: Kostov A., Friedrich B.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2005-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2005/1450-53390501113K.pdf
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author Kostov A.
Friedrich B.
author_facet Kostov A.
Friedrich B.
author_sort Kostov A.
collection DOAJ
description Titanium and its alloys interstitially dissolve a large amount of impurities such as oxygen and nitrogen, which degrade the mechanical and physical properties of alloys. On the other hand crucible oxides based on CaO, ZrO2 Y2O3, etc., and their spinels (combination of two or more oxides) can be used for melting titanium and its alloys. However, the thermodynamic behavior of calcium, zirconium, yttrium on the one side, and oxygen on the other side, in molten Ti and Ti-Al alloys have not been made clear and because of that, it is very interesting for research. Owing of literature data, as well as these crucibles are cheaper than standard crucibles for melting titanium and titanium alloys, in this paper will be presented the results of selection of thermo-chemistry analysis with the aim to determine the crucible oxide stability in contact with molten titanium and titanium-aluminum alloys.
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publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-f9a9c40d074546cfa7ac7a4bedbff01f2025-02-02T08:48:36ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392005-01-0141111312510.2298/JMMB0501113KSelection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculationsKostov A.Friedrich B.Titanium and its alloys interstitially dissolve a large amount of impurities such as oxygen and nitrogen, which degrade the mechanical and physical properties of alloys. On the other hand crucible oxides based on CaO, ZrO2 Y2O3, etc., and their spinels (combination of two or more oxides) can be used for melting titanium and its alloys. However, the thermodynamic behavior of calcium, zirconium, yttrium on the one side, and oxygen on the other side, in molten Ti and Ti-Al alloys have not been made clear and because of that, it is very interesting for research. Owing of literature data, as well as these crucibles are cheaper than standard crucibles for melting titanium and titanium alloys, in this paper will be presented the results of selection of thermo-chemistry analysis with the aim to determine the crucible oxide stability in contact with molten titanium and titanium-aluminum alloys.http://www.doiserbia.nb.rs/img/doi/1450-5339/2005/1450-53390501113K.pdfthermo-chemistry calculationscrucible oxidestitaniumtitanium-aluminum alloysthermodynamic stability
spellingShingle Kostov A.
Friedrich B.
Selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculations
Journal of Mining and Metallurgy. Section B: Metallurgy
thermo-chemistry calculations
crucible oxides
titanium
titanium-aluminum alloys
thermodynamic stability
title Selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculations
title_full Selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculations
title_fullStr Selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculations
title_full_unstemmed Selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculations
title_short Selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo-chemistry calculations
title_sort selection of crucible oxides in molten titanium and titanium aluminum alloys by thermo chemistry calculations
topic thermo-chemistry calculations
crucible oxides
titanium
titanium-aluminum alloys
thermodynamic stability
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2005/1450-53390501113K.pdf
work_keys_str_mv AT kostova selectionofcrucibleoxidesinmoltentitaniumandtitaniumaluminumalloysbythermochemistrycalculations
AT friedrichb selectionofcrucibleoxidesinmoltentitaniumandtitaniumaluminumalloysbythermochemistrycalculations