EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENAN

κ-Carrageenan is a sulfated galactan extracted from red algae (Rhodophyceae) which has many functions. However, nonfood applications of κ-carrageenan have been limited by its superior gelling and viscosity properties. The effect of ozonation on physicochemical and rheological properties of κ-carrage...

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Main Authors: AJI PRASETYANINGRUM, BAKTI JOS, RATNAWATI RATNAWATI
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017-03-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4485
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author AJI PRASETYANINGRUM
BAKTI JOS
RATNAWATI RATNAWATI
author_facet AJI PRASETYANINGRUM
BAKTI JOS
RATNAWATI RATNAWATI
author_sort AJI PRASETYANINGRUM
collection DOAJ
description κ-Carrageenan is a sulfated galactan extracted from red algae (Rhodophyceae) which has many functions. However, nonfood applications of κ-carrageenan have been limited by its superior gelling and viscosity properties. The effect of ozonation on physicochemical and rheological properties of κ-carrageenan solution at different pH was investigated. κ-Carrageenan solution was prepared in the ratio of 1:100 (w/v) and was treated with dissolved ozone with concentration of 80±2 ppm. This ozonation was conducted at different times and pH. The viscosity of ozone-treated κ-carrageenan solution was analyzed using Brookfield viscometer and the sulfate content was determined using FT-IR spectra and barium chloride-gelatin method. The results show that the viscosity of ozone-treated κ-carrageenan decreases appreciably with time. The highest percentage reduction in viscosity occurs at pH 3, followed by pH 7 and 10. The FT-IR spectra reveals that the chemical structure of degraded κ-carrageenan, in term of sulfate content, is only slightly affected by the ozone treatment.
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issn 1582-540X
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language English
publishDate 2017-03-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
record_format Article
series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj-art-f9835eac3fae46bb9d027ee63b3f7fca2025-08-20T03:06:31ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2017-03-01181918EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENANAJI PRASETYANINGRUM0 BAKTI JOS1RATNAWATI RATNAWATI21Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Jl. Prof. H. Soedarto, SH., Semarang 50275, Indonesia1Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Jl. Prof. H. Soedarto, SH., Semarang 50275, Indonesia1Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Jl. Prof. H. Soedarto, SH., Semarang 50275, Indonesiaκ-Carrageenan is a sulfated galactan extracted from red algae (Rhodophyceae) which has many functions. However, nonfood applications of κ-carrageenan have been limited by its superior gelling and viscosity properties. The effect of ozonation on physicochemical and rheological properties of κ-carrageenan solution at different pH was investigated. κ-Carrageenan solution was prepared in the ratio of 1:100 (w/v) and was treated with dissolved ozone with concentration of 80±2 ppm. This ozonation was conducted at different times and pH. The viscosity of ozone-treated κ-carrageenan solution was analyzed using Brookfield viscometer and the sulfate content was determined using FT-IR spectra and barium chloride-gelatin method. The results show that the viscosity of ozone-treated κ-carrageenan decreases appreciably with time. The highest percentage reduction in viscosity occurs at pH 3, followed by pH 7 and 10. The FT-IR spectra reveals that the chemical structure of degraded κ-carrageenan, in term of sulfate content, is only slightly affected by the ozone treatment.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4485depolymerizationκ-carrageenanozone treatmentviscositysulfate content
spellingShingle AJI PRASETYANINGRUM
BAKTI JOS
RATNAWATI RATNAWATI
EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENAN
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
depolymerization
κ-carrageenan
ozone treatment
viscosity
sulfate content
title EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENAN
title_full EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENAN
title_fullStr EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENAN
title_full_unstemmed EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENAN
title_short EFFECT OF OZONATION PROCESS ON PHYSICOCHEMICAL AND RHEOLOGICAL PROPERTIES OF κ-CARRAGEENAN
title_sort effect of ozonation process on physicochemical and rheological properties of κ carrageenan
topic depolymerization
κ-carrageenan
ozone treatment
viscosity
sulfate content
url http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4485
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