Crystal structure of AlPCl8

The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric u...

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Main Authors: Hyeonjin Seo, Seungyong Shin, Seung-Tae Hong
Format: Article
Language:English
Published: International Union of Crystallography 2024-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
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Online Access:https://journals.iucr.org/paper?S2056989024010661
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author Hyeonjin Seo
Seungyong Shin
Seung-Tae Hong
author_facet Hyeonjin Seo
Seungyong Shin
Seung-Tae Hong
author_sort Hyeonjin Seo
collection DOAJ
description The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms. The structure is characterized by isolated AlCl4 and PCl4 tetrahedra, isostructural with FePCl8 and GaPCl8.
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institution Kabale University
issn 2056-9890
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publisher International Union of Crystallography
record_format Article
series Acta Crystallographica Section E: Crystallographic Communications
spelling doaj-art-f8c992a1426642ef866c786def737f312024-12-05T11:43:00ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902024-12-0180121280128210.1107/S2056989024010661oi2012Crystal structure of AlPCl8Hyeonjin Seo0Seungyong Shin1Seung-Tae Hong2Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 42988, Republic of KoreaDaegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 42988, Republic of KoreaDaegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 42988, Republic of KoreaThe crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms. The structure is characterized by isolated AlCl4 and PCl4 tetrahedra, isostructural with FePCl8 and GaPCl8.https://journals.iucr.org/paper?S2056989024010661crystal structurealuminium phosphorus chloridealuminium(iii) chloridephosphorus(v) chloridesingle-crystal
spellingShingle Hyeonjin Seo
Seungyong Shin
Seung-Tae Hong
Crystal structure of AlPCl8
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
aluminium phosphorus chloride
aluminium(iii) chloride
phosphorus(v) chloride
single-crystal
title Crystal structure of AlPCl8
title_full Crystal structure of AlPCl8
title_fullStr Crystal structure of AlPCl8
title_full_unstemmed Crystal structure of AlPCl8
title_short Crystal structure of AlPCl8
title_sort crystal structure of alpcl8
topic crystal structure
aluminium phosphorus chloride
aluminium(iii) chloride
phosphorus(v) chloride
single-crystal
url https://journals.iucr.org/paper?S2056989024010661
work_keys_str_mv AT hyeonjinseo crystalstructureofalpcl8
AT seungyongshin crystalstructureofalpcl8
AT seungtaehong crystalstructureofalpcl8