Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric Constant

This paper reports the dielectric characterizations of (Ca<sub>0.95</sub>Sr<sub>0.05</sub>)(Ti<sub>1−x</sub>Sn<sub>x</sub>)O<sub>3</sub> ceramics prepared using a solid-state reaction method with various x values. X-ray diffraction spectros...

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Main Authors: Yuan-Bin Chen, Yu Fan, Shiuan-Ho Chang, Shaobing Shen
Format: Article
Language:English
Published: MDPI AG 2024-09-01
Series:Ceramics
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Online Access:https://www.mdpi.com/2571-6131/7/3/81
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author Yuan-Bin Chen
Yu Fan
Shiuan-Ho Chang
Shaobing Shen
author_facet Yuan-Bin Chen
Yu Fan
Shiuan-Ho Chang
Shaobing Shen
author_sort Yuan-Bin Chen
collection DOAJ
description This paper reports the dielectric characterizations of (Ca<sub>0.95</sub>Sr<sub>0.05</sub>)(Ti<sub>1−x</sub>Sn<sub>x</sub>)O<sub>3</sub> ceramics prepared using a solid-state reaction method with various x values. X-ray diffraction spectroscopy analyses showed that the crystal structure of these pure samples was orthorhombic perovskite. With increasing Sn<sup>4+</sup> content, the lattice constant and unit cell volume increased, while the dielectric constant decreased because of the ionic polarizability decreasing. Moreover, a maximum Q × f value of 5242 (GHz), a dielectric constant (ε<sub>r</sub>) of 91.23, and a temperature coefficient (τ<sub>f</sub>) of +810 ppm/°C were achieved for samples sintered at 1350 °C for 4 h. The microwave dielectric characterization was found to be strongly correlated with the sintering temperature, and the best performance was achieved for the sample sintered at 1350 °C. (Ca<sub>0.95</sub>Sr<sub>0.05</sub>)(Ti<sub>1−x</sub>Sn<sub>x</sub>)O<sub>3</sub> possesses a promising potential to be a τ<sub>f</sub> compensator for a near-zero τ<sub>f</sub> dielectric ceramic applied in wireless communication systems.
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spelling doaj-art-f8b2dd7fca274b3b8b76c54801a88dbb2025-08-20T01:55:22ZengMDPI AGCeramics2571-61312024-09-01731227123610.3390/ceramics7030081Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric ConstantYuan-Bin Chen0Yu Fan1Shiuan-Ho Chang2Shaobing Shen3School of Electronics and Electrical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Electronics and Electrical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Electronics and Electrical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Electronics and Electrical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaThis paper reports the dielectric characterizations of (Ca<sub>0.95</sub>Sr<sub>0.05</sub>)(Ti<sub>1−x</sub>Sn<sub>x</sub>)O<sub>3</sub> ceramics prepared using a solid-state reaction method with various x values. X-ray diffraction spectroscopy analyses showed that the crystal structure of these pure samples was orthorhombic perovskite. With increasing Sn<sup>4+</sup> content, the lattice constant and unit cell volume increased, while the dielectric constant decreased because of the ionic polarizability decreasing. Moreover, a maximum Q × f value of 5242 (GHz), a dielectric constant (ε<sub>r</sub>) of 91.23, and a temperature coefficient (τ<sub>f</sub>) of +810 ppm/°C were achieved for samples sintered at 1350 °C for 4 h. The microwave dielectric characterization was found to be strongly correlated with the sintering temperature, and the best performance was achieved for the sample sintered at 1350 °C. (Ca<sub>0.95</sub>Sr<sub>0.05</sub>)(Ti<sub>1−x</sub>Sn<sub>x</sub>)O<sub>3</sub> possesses a promising potential to be a τ<sub>f</sub> compensator for a near-zero τ<sub>f</sub> dielectric ceramic applied in wireless communication systems.https://www.mdpi.com/2571-6131/7/3/81Q × fmicrowave dielectricceramic
spellingShingle Yuan-Bin Chen
Yu Fan
Shiuan-Ho Chang
Shaobing Shen
Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric Constant
Ceramics
Q × f
microwave dielectric
ceramic
title Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric Constant
title_full Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric Constant
title_fullStr Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric Constant
title_full_unstemmed Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric Constant
title_short Study on Microwave Dielectric Materials an Adjustable Temperature Drift Coefficient and a High Dielectric Constant
title_sort study on microwave dielectric materials an adjustable temperature drift coefficient and a high dielectric constant
topic Q × f
microwave dielectric
ceramic
url https://www.mdpi.com/2571-6131/7/3/81
work_keys_str_mv AT yuanbinchen studyonmicrowavedielectricmaterialsanadjustabletemperaturedriftcoefficientandahighdielectricconstant
AT yufan studyonmicrowavedielectricmaterialsanadjustabletemperaturedriftcoefficientandahighdielectricconstant
AT shiuanhochang studyonmicrowavedielectricmaterialsanadjustabletemperaturedriftcoefficientandahighdielectricconstant
AT shaobingshen studyonmicrowavedielectricmaterialsanadjustabletemperaturedriftcoefficientandahighdielectricconstant