Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic Dyes

A dye-sensitized solar cell (DSSC) is a photovoltaic device capable of generating electrical power from the absorption of solar radiation. These cells use a SnO2 : F/TiO2/dye heterojunction as the active electrode (working electrode). Active electrodes containing TiO2 in the anatase crystalline phas...

Full description

Saved in:
Bibliographic Details
Main Authors: Mario Alberto Sánchez-García, Xim Bokhimi, Sergio Velázquez Martínez, Antonio Esteban Jiménez-González
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2018/1236878
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832559043954081792
author Mario Alberto Sánchez-García
Xim Bokhimi
Sergio Velázquez Martínez
Antonio Esteban Jiménez-González
author_facet Mario Alberto Sánchez-García
Xim Bokhimi
Sergio Velázquez Martínez
Antonio Esteban Jiménez-González
author_sort Mario Alberto Sánchez-García
collection DOAJ
description A dye-sensitized solar cell (DSSC) is a photovoltaic device capable of generating electrical power from the absorption of solar radiation. These cells use a SnO2 : F/TiO2/dye heterojunction as the active electrode (working electrode). Active electrodes containing TiO2 in the anatase crystalline phase and synthetic dyes are used to achieve high conversion efficiencies. Synthetic dyes, whether organic or organometallic compounds, have the disadvantage of being expensive. For this reason, many efforts are made worldwide to find natural dyes with lower production costs that can be used in the fabrication of DSSCs. Nocheztli is a natural red dye obtained from the cochineal insect Dactylopius coccus; the dye dates from pre-Hispanic times and contains high levels of carminic acid (CA). Nocheztli has been used in Mexico in textile dyeing from pre-Hispanic times to the present. Carmine is an organometallic dye with two molecules of carminic acid and one atom of aluminum in its structure; it is obtained by the interaction of the carminic acid from Nocheztli with aluminum salts. Carminic acid and carmine molecules contain a carboxyl group in their structure, allowing them to anchor to TiO2, creating a suitable heterojunction to prepare DSSCs. In this study, both dyes are used to sensitize the mesoporous TiO2m semiconductor to prepare DSSCs.
format Article
id doaj-art-f7f3782985384b84960dd210b7088cd6
institution Kabale University
issn 1687-9503
1687-9511
language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-f7f3782985384b84960dd210b7088cd62025-02-03T01:31:00ZengWileyJournal of Nanotechnology1687-95031687-95112018-01-01201810.1155/2018/12368781236878Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic DyesMario Alberto Sánchez-García0Xim Bokhimi1Sergio Velázquez Martínez2Antonio Esteban Jiménez-González3Institute of Physics, National Autonomous University of Mexico (IF-UNAM), Apartado Postal 20-364, 04510 Mexico City, MexicoInstitute of Physics, National Autonomous University of Mexico (IF-UNAM), Apartado Postal 20-364, 04510 Mexico City, MexicoCentro de Investigación en Ingeniería y Ciencias Aplicadas de la Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Col. Chamilpa, 62209 Cuernavaca, Mor, MexicoInstitute of Renewable Energy, National Autonomous University of Mexico (IER-UNAM), 62580 Temixco, Mor, MexicoA dye-sensitized solar cell (DSSC) is a photovoltaic device capable of generating electrical power from the absorption of solar radiation. These cells use a SnO2 : F/TiO2/dye heterojunction as the active electrode (working electrode). Active electrodes containing TiO2 in the anatase crystalline phase and synthetic dyes are used to achieve high conversion efficiencies. Synthetic dyes, whether organic or organometallic compounds, have the disadvantage of being expensive. For this reason, many efforts are made worldwide to find natural dyes with lower production costs that can be used in the fabrication of DSSCs. Nocheztli is a natural red dye obtained from the cochineal insect Dactylopius coccus; the dye dates from pre-Hispanic times and contains high levels of carminic acid (CA). Nocheztli has been used in Mexico in textile dyeing from pre-Hispanic times to the present. Carmine is an organometallic dye with two molecules of carminic acid and one atom of aluminum in its structure; it is obtained by the interaction of the carminic acid from Nocheztli with aluminum salts. Carminic acid and carmine molecules contain a carboxyl group in their structure, allowing them to anchor to TiO2, creating a suitable heterojunction to prepare DSSCs. In this study, both dyes are used to sensitize the mesoporous TiO2m semiconductor to prepare DSSCs.http://dx.doi.org/10.1155/2018/1236878
spellingShingle Mario Alberto Sánchez-García
Xim Bokhimi
Sergio Velázquez Martínez
Antonio Esteban Jiménez-González
Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic Dyes
Journal of Nanotechnology
title Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic Dyes
title_full Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic Dyes
title_fullStr Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic Dyes
title_full_unstemmed Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic Dyes
title_short Dye-Sensitized Solar Cells Prepared with Mexican Pre-Hispanic Dyes
title_sort dye sensitized solar cells prepared with mexican pre hispanic dyes
url http://dx.doi.org/10.1155/2018/1236878
work_keys_str_mv AT marioalbertosanchezgarcia dyesensitizedsolarcellspreparedwithmexicanprehispanicdyes
AT ximbokhimi dyesensitizedsolarcellspreparedwithmexicanprehispanicdyes
AT sergiovelazquezmartinez dyesensitizedsolarcellspreparedwithmexicanprehispanicdyes
AT antonioestebanjimenezgonzalez dyesensitizedsolarcellspreparedwithmexicanprehispanicdyes