Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
Paper Spray Ionization is an atmospheric pressure ionization technique that utilizes an offline electro-osmotic flow to generate ions off a paper medium. This technique can be performed on a Bruker SolariX Fourier transform ion cyclotron resonance mass spectrometer by modifying the existing nanospra...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2012-01-01
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| Series: | International Journal of Analytical Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/382021 |
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| _version_ | 1832558216294170624 |
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| author | Kevin D. Quinn Charmion I. Cruickshank Troy D. Wood |
| author_facet | Kevin D. Quinn Charmion I. Cruickshank Troy D. Wood |
| author_sort | Kevin D. Quinn |
| collection | DOAJ |
| description | Paper Spray Ionization is an atmospheric pressure ionization technique that utilizes an offline electro-osmotic flow to generate ions off a paper medium. This technique can be performed on a Bruker SolariX Fourier transform ion cyclotron resonance mass spectrometer by modifying the existing nanospray source. High-resolution paper spray spectra were obtained for both organic and biological samples to demonstrate the benefit of linking the technique with a high-resolution mass analyzer. Error values in the range 0.23 to 2.14 ppm were obtained for calf lung surfactant extract with broadband mass resolving power (m/Δm50%) above 60,000 utilizing an external calibration standard. |
| format | Article |
| id | doaj-art-f7a6b59ac2c34ed195a27b7572d52b66 |
| institution | Kabale University |
| issn | 1687-8760 1687-8779 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Analytical Chemistry |
| spelling | doaj-art-f7a6b59ac2c34ed195a27b7572d52b662025-02-03T01:33:04ZengWileyInternational Journal of Analytical Chemistry1687-87601687-87792012-01-01201210.1155/2012/382021382021Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass SpectrometryKevin D. Quinn0Charmion I. Cruickshank1Troy D. Wood2Department of Chemistry, State University of New York at Buffalo, Buffalo, NY 14260, USADepartment of Chemistry, State University of New York at Buffalo, Buffalo, NY 14260, USADepartment of Chemistry, State University of New York at Buffalo, Buffalo, NY 14260, USAPaper Spray Ionization is an atmospheric pressure ionization technique that utilizes an offline electro-osmotic flow to generate ions off a paper medium. This technique can be performed on a Bruker SolariX Fourier transform ion cyclotron resonance mass spectrometer by modifying the existing nanospray source. High-resolution paper spray spectra were obtained for both organic and biological samples to demonstrate the benefit of linking the technique with a high-resolution mass analyzer. Error values in the range 0.23 to 2.14 ppm were obtained for calf lung surfactant extract with broadband mass resolving power (m/Δm50%) above 60,000 utilizing an external calibration standard.http://dx.doi.org/10.1155/2012/382021 |
| spellingShingle | Kevin D. Quinn Charmion I. Cruickshank Troy D. Wood Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry International Journal of Analytical Chemistry |
| title | Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry |
| title_full | Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry |
| title_fullStr | Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry |
| title_full_unstemmed | Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry |
| title_short | Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry |
| title_sort | ultra high mass resolution paper spray by fourier transform ion cyclotron resonance mass spectrometry |
| url | http://dx.doi.org/10.1155/2012/382021 |
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