Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene Adsorption

Pre-extraction of hemicellulose from eucalyptus heartwood and sapwood was conducted using the method of KOH extraction. Activated carbons (ACs) with high toluene adsorption capacity were prepared by using KOH as activator and hemicellulose-pre-extracted residue (HPR) as AC precursor. The findings in...

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Main Authors: Xixiang Huang, Yuanyuan Zhao, Zhiwei Wang, Yanhong Wang, Yun Zhou, Hao Cheng, Penghui Li, Shubin Wu
Format: Article
Language:English
Published: North Carolina State University 2025-01-01
Series:BioResources
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Online Access:https://ojs.bioresources.com/index.php/BRJ/article/view/24121
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author Xixiang Huang
Yuanyuan Zhao
Zhiwei Wang
Yanhong Wang
Yun Zhou
Hao Cheng
Penghui Li
Shubin Wu
author_facet Xixiang Huang
Yuanyuan Zhao
Zhiwei Wang
Yanhong Wang
Yun Zhou
Hao Cheng
Penghui Li
Shubin Wu
author_sort Xixiang Huang
collection DOAJ
description Pre-extraction of hemicellulose from eucalyptus heartwood and sapwood was conducted using the method of KOH extraction. Activated carbons (ACs) with high toluene adsorption capacity were prepared by using KOH as activator and hemicellulose-pre-extracted residue (HPR) as AC precursor. The findings indicated that the pore structure of the ACs could be regulated by adjusting the carbonization temperature. Using the HPR of eucalyptus heartwood as raw material, the activated carbon carbonized at 400 °C exhibited the highest BET surface area (3699 m2·g-1) and pore volume (1.90 cm3·g-1). The adsorption capacity of AC for toluene reached 816 mg·g-1. The results showed that the adsorption capacity of toluene was associated with the micropores (< 2 nm) in the AC. Optimizing the carbonization temperature could enhance the proportion of micropores, thereby significantly enhancing the activated carbon’s adsorption capacity for toluene.
format Article
id doaj-art-f68278b86ead41d6a7fce501e884fde6
institution Kabale University
issn 1930-2126
language English
publishDate 2025-01-01
publisher North Carolina State University
record_format Article
series BioResources
spelling doaj-art-f68278b86ead41d6a7fce501e884fde62025-02-11T00:00:29ZengNorth Carolina State UniversityBioResources1930-21262025-01-01201225922752362Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene AdsorptionXixiang Huang0Yuanyuan Zhao1Zhiwei Wang2Yanhong Wang3Yun Zhou4Hao Cheng5Penghui Li6Shubin Wu7State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510540, P.R. China; Key Laboratory of Clean Pulp and Papermaking and Pollution Control of Guangxi, College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, P.R. ChinaKey Laboratory of Clean Pulp and Papermaking and Pollution Control of Guangxi, College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, P.R. China; Guanghou Paper Group Ltd, Guangzhou 511462, P.R. China Key Laboratory of Clean Pulp and Papermaking and Pollution Control of Guangxi, College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, P.R. ChinaGuanghou Paper Group Ltd, Guangzhou 511462, P.R. ChinaGuanghou Paper Group Ltd, Guangzhou 511462, P.R. ChinaState Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510540, P.R. ChinaState Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510540, P.R. ChinaState Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510540, P.R. ChinaPre-extraction of hemicellulose from eucalyptus heartwood and sapwood was conducted using the method of KOH extraction. Activated carbons (ACs) with high toluene adsorption capacity were prepared by using KOH as activator and hemicellulose-pre-extracted residue (HPR) as AC precursor. The findings indicated that the pore structure of the ACs could be regulated by adjusting the carbonization temperature. Using the HPR of eucalyptus heartwood as raw material, the activated carbon carbonized at 400 °C exhibited the highest BET surface area (3699 m2·g-1) and pore volume (1.90 cm3·g-1). The adsorption capacity of AC for toluene reached 816 mg·g-1. The results showed that the adsorption capacity of toluene was associated with the micropores (< 2 nm) in the AC. Optimizing the carbonization temperature could enhance the proportion of micropores, thereby significantly enhancing the activated carbon’s adsorption capacity for toluene.https://ojs.bioresources.com/index.php/BRJ/article/view/24121eucalyptus heartwoodeucalyptus sapwoodcarbonization temperatureactivated carbontoluene adsorption
spellingShingle Xixiang Huang
Yuanyuan Zhao
Zhiwei Wang
Yanhong Wang
Yun Zhou
Hao Cheng
Penghui Li
Shubin Wu
Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene Adsorption
BioResources
eucalyptus heartwood
eucalyptus sapwood
carbonization temperature
activated carbon
toluene adsorption
title Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene Adsorption
title_full Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene Adsorption
title_fullStr Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene Adsorption
title_full_unstemmed Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene Adsorption
title_short Preparation of Activated Carbons from Hemicellulose Pre-Extraction Residue of Eucalyptus Heartwood and Sapwood and their Application in Toluene Adsorption
title_sort preparation of activated carbons from hemicellulose pre extraction residue of eucalyptus heartwood and sapwood and their application in toluene adsorption
topic eucalyptus heartwood
eucalyptus sapwood
carbonization temperature
activated carbon
toluene adsorption
url https://ojs.bioresources.com/index.php/BRJ/article/view/24121
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