The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatus

ABSTRACT Fungal pathogens pose a serious threat to human health, with Candida and Aspergillus spp. representing some of the most significant opportunistic invaders. Aspergillus fumigatus causes aspergillosis, one of the most prevalent fungal diseases of humans. There is a limited number of drugs ava...

Full description

Saved in:
Bibliographic Details
Main Authors: Thaila Fernanda dos Reis, Endrews Delbaje, Camila Figueiredo Pinzan, Rafael Bastos, Suzanne Ackloo, Sara Fallah, Bradley Laflamme, Nicole Robbins, Leah E. Cowen, Gustavo H. Goldman
Format: Article
Language:English
Published: American Society for Microbiology 2025-05-01
Series:Microbiology Spectrum
Subjects:
Online Access:https://journals.asm.org/doi/10.1128/spectrum.03318-24
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849721850836287488
author Thaila Fernanda dos Reis
Endrews Delbaje
Camila Figueiredo Pinzan
Rafael Bastos
Suzanne Ackloo
Sara Fallah
Bradley Laflamme
Nicole Robbins
Leah E. Cowen
Gustavo H. Goldman
author_facet Thaila Fernanda dos Reis
Endrews Delbaje
Camila Figueiredo Pinzan
Rafael Bastos
Suzanne Ackloo
Sara Fallah
Bradley Laflamme
Nicole Robbins
Leah E. Cowen
Gustavo H. Goldman
author_sort Thaila Fernanda dos Reis
collection DOAJ
description ABSTRACT Fungal pathogens pose a serious threat to human health, with Candida and Aspergillus spp. representing some of the most significant opportunistic invaders. Aspergillus fumigatus causes aspergillosis, one of the most prevalent fungal diseases of humans. There is a limited number of drugs available to combat these infections, and antifungal drug resistance is on the rise. In this manuscript, we show 4-[4-(4-Piperidinyl) phenyl]-7-[4-(-(trifluoromethyl) phenyl]-2-naphthalenecarboxylic acid (PPTN), a highly specific antagonist of the human P2Y14 receptor, is a promising antifungal adjuvant against diverse fungal pathogens. PPTN interacts with caspofungin (CAS), ibrexafungerp, voriconazole (VOR), and amphotericin against A. fumigatus CAS- and VOR-resistant clinical isolates, and also CAS against Candida spp and Cryptococcus neoformans. The combination of PPTN and CAS increases cell death in A. fumigatus. In the model yeast Saccharomyces cerevisiae, heterozygous deletion of genes involved in chromatin remodeling results in PPTN hypersensitivity, and in A. fumigatus, PPTN can have increased fungicidal activity when combined with the histone deacetylase inhibitor trichostatin A and the DNA methyltransferase inhibitor 5-azacytidine. Finally, PPTN has reduced toxicity to human immortalized cell lineages and partially clears A. fumigatus conidia infection in A549 pulmonary epithelial cells. Our results indicate that PPTN is a novel adjuvant antifungal drug against fungal diseases caused by A. fumigatus and Candida spp.IMPORTANCEInvasive fungal infections have a high mortality rate, causing more deaths annually than tuberculosis or malaria. Aspergillus fumigatus is the main etiological agent of aspergillosis, one of the most prevalent and deadly fungal diseases. There are few therapeutic options for treating this disease, and treatment commonly fails due to host complications or the emergence of antifungal resistance. Drug repurposing, where existing drugs are deployed for other clinical indications, has increasingly been used in the process of drug discovery. Here, we show that 4-[4-(4-Piperidinyl) phenyl]-7-[4-(-(trifluoromethyl) phenyl]-2-naphthalenecarboxylic acid (PPTN), a highly specific antagonist of the human P2Y14 receptor, when combined with caspofungin (CAS), ibrexafungerp, voriconazole (VOR), and amphotericin can increase the fungicidal activity against not only A. fumigatus CAS- and VOR-resistant clinical isolates but also CAS against Candida spp.
format Article
id doaj-art-f5de5020edea4634a407a8febab2a5f0
institution DOAJ
issn 2165-0497
language English
publishDate 2025-05-01
publisher American Society for Microbiology
record_format Article
series Microbiology Spectrum
spelling doaj-art-f5de5020edea4634a407a8febab2a5f02025-08-20T03:11:32ZengAmerican Society for MicrobiologyMicrobiology Spectrum2165-04972025-05-0113510.1128/spectrum.03318-24The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatusThaila Fernanda dos Reis0Endrews Delbaje1Camila Figueiredo Pinzan2Rafael Bastos3Suzanne Ackloo4Sara Fallah5Bradley Laflamme6Nicole Robbins7Leah E. Cowen8Gustavo H. Goldman9Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, São Paulo, BrazilFaculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, São Paulo, BrazilFaculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, São Paulo, BrazilNational Institute of Science and Technology in Human Pathogenic Fungi, São Paulo, BrazilStructural Genomics Consortium, University of Toronto, Toronto, Ontario, CanadaDepartment of Molecular Genetics, University of Toronto, Toronto, Ontario, CanadaDepartment of Molecular Genetics, University of Toronto, Toronto, Ontario, CanadaDepartment of Molecular Genetics, University of Toronto, Toronto, Ontario, CanadaDepartment of Molecular Genetics, University of Toronto, Toronto, Ontario, CanadaFaculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, São Paulo, BrazilABSTRACT Fungal pathogens pose a serious threat to human health, with Candida and Aspergillus spp. representing some of the most significant opportunistic invaders. Aspergillus fumigatus causes aspergillosis, one of the most prevalent fungal diseases of humans. There is a limited number of drugs available to combat these infections, and antifungal drug resistance is on the rise. In this manuscript, we show 4-[4-(4-Piperidinyl) phenyl]-7-[4-(-(trifluoromethyl) phenyl]-2-naphthalenecarboxylic acid (PPTN), a highly specific antagonist of the human P2Y14 receptor, is a promising antifungal adjuvant against diverse fungal pathogens. PPTN interacts with caspofungin (CAS), ibrexafungerp, voriconazole (VOR), and amphotericin against A. fumigatus CAS- and VOR-resistant clinical isolates, and also CAS against Candida spp and Cryptococcus neoformans. The combination of PPTN and CAS increases cell death in A. fumigatus. In the model yeast Saccharomyces cerevisiae, heterozygous deletion of genes involved in chromatin remodeling results in PPTN hypersensitivity, and in A. fumigatus, PPTN can have increased fungicidal activity when combined with the histone deacetylase inhibitor trichostatin A and the DNA methyltransferase inhibitor 5-azacytidine. Finally, PPTN has reduced toxicity to human immortalized cell lineages and partially clears A. fumigatus conidia infection in A549 pulmonary epithelial cells. Our results indicate that PPTN is a novel adjuvant antifungal drug against fungal diseases caused by A. fumigatus and Candida spp.IMPORTANCEInvasive fungal infections have a high mortality rate, causing more deaths annually than tuberculosis or malaria. Aspergillus fumigatus is the main etiological agent of aspergillosis, one of the most prevalent and deadly fungal diseases. There are few therapeutic options for treating this disease, and treatment commonly fails due to host complications or the emergence of antifungal resistance. Drug repurposing, where existing drugs are deployed for other clinical indications, has increasingly been used in the process of drug discovery. Here, we show that 4-[4-(4-Piperidinyl) phenyl]-7-[4-(-(trifluoromethyl) phenyl]-2-naphthalenecarboxylic acid (PPTN), a highly specific antagonist of the human P2Y14 receptor, when combined with caspofungin (CAS), ibrexafungerp, voriconazole (VOR), and amphotericin can increase the fungicidal activity against not only A. fumigatus CAS- and VOR-resistant clinical isolates but also CAS against Candida spp.https://journals.asm.org/doi/10.1128/spectrum.03318-24Aspergillus fumigatuscaspofunginPPTNCandida sppCryptococcus neoformans
spellingShingle Thaila Fernanda dos Reis
Endrews Delbaje
Camila Figueiredo Pinzan
Rafael Bastos
Suzanne Ackloo
Sara Fallah
Bradley Laflamme
Nicole Robbins
Leah E. Cowen
Gustavo H. Goldman
The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatus
Microbiology Spectrum
Aspergillus fumigatus
caspofungin
PPTN
Candida spp
Cryptococcus neoformans
title The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatus
title_full The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatus
title_fullStr The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatus
title_full_unstemmed The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatus
title_short The GPCR antagonist PPTN synergizes with caspofungin providing increased fungicidal activity against Aspergillus fumigatus
title_sort gpcr antagonist pptn synergizes with caspofungin providing increased fungicidal activity against aspergillus fumigatus
topic Aspergillus fumigatus
caspofungin
PPTN
Candida spp
Cryptococcus neoformans
url https://journals.asm.org/doi/10.1128/spectrum.03318-24
work_keys_str_mv AT thailafernandadosreis thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT endrewsdelbaje thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT camilafigueiredopinzan thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT rafaelbastos thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT suzanneackloo thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT sarafallah thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT bradleylaflamme thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT nicolerobbins thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT leahecowen thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT gustavohgoldman thegpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT thailafernandadosreis gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT endrewsdelbaje gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT camilafigueiredopinzan gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT rafaelbastos gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT suzanneackloo gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT sarafallah gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT bradleylaflamme gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT nicolerobbins gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT leahecowen gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus
AT gustavohgoldman gpcrantagonistpptnsynergizeswithcaspofunginprovidingincreasedfungicidalactivityagainstaspergillusfumigatus