SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION
Synthesis of C-hexyl calix[4]resorcinarene through condensation reaction between resorcinol and heptanal with HCl catalyst has been investigated. Synthesis conducted by the ratio of resorcinol: heptanal (1:1) using reflux for 6 hours in ethanol. Structural analysis of the product w...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Universitas Sebelas Maret
2016-08-01
|
| Series: | Alchemy |
| Subjects: | |
| Online Access: | https://jurnal.uns.ac.id/index.php?journal=alchemy&page=article&op=view&path[]=730 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850058531659579392 |
|---|---|
| author | Desi Suci Handayani Zainal Arifin Almaqqomul Amin Triana Kusumaningsih Abu Masykur |
| author_facet | Desi Suci Handayani Zainal Arifin Almaqqomul Amin Triana Kusumaningsih Abu Masykur |
| author_sort | Desi Suci Handayani |
| collection | DOAJ |
| description | Synthesis of C-hexyl calix[4]resorcinarene through condensation reaction between resorcinol and heptanal with HCl catalyst has been investigated. Synthesis conducted by the ratio of resorcinol: heptanal (1:1) using reflux for 6 hours in ethanol. Structural analysis of the product was done by FTIR and 1 H-NMR spectroscopy, while the characterization was done by determining melting point. The product was golden brown powder with a yield 99.43% and melting point more than 300 °C. Structural analysis with FTIR and 1 HNMR known vibration and signals characteristic of calix[4]resorcinarena group, the vibrations of the CH bridge. Vibration of CH bridge appearance at wave number 1445 cm-1 and 1456 cm-1, while signal of CH bridge appearance at chemical shifts from 4.17 to 4.21 ppm. |
| format | Article |
| id | doaj-art-f59dff29ebb5449ebb36fc184fee39db |
| institution | DOAJ |
| issn | 1412-4092 2443-4183 |
| language | English |
| publishDate | 2016-08-01 |
| publisher | Universitas Sebelas Maret |
| record_format | Article |
| series | Alchemy |
| spelling | doaj-art-f59dff29ebb5449ebb36fc184fee39db2025-08-20T02:51:07ZengUniversitas Sebelas MaretAlchemy1412-40922443-41832016-08-01101495310.20961/alchemy.v10i1.730SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATIONDesi Suci Handayani0Zainal Arifin Almaqqomul Amin1Triana Kusumaningsih2Abu Masykur3Jurusan Kimia, Universitas Sebelas Maret, Jl. Ir. Sutami No36A kentingan Surakarta 57126Jurusan Kimia, Universitas Sebelas Maret, Jl. Ir. Sutami No36A kentingan Surakarta 57126Jurusan Kimia, Universitas Sebelas Maret, Jl. Ir. Sutami No36A kentingan Surakarta 57126Jurusan Kimia, Universitas Sebelas Maret, Jl. Ir. Sutami No36A kentingan Surakarta 57126Synthesis of C-hexyl calix[4]resorcinarene through condensation reaction between resorcinol and heptanal with HCl catalyst has been investigated. Synthesis conducted by the ratio of resorcinol: heptanal (1:1) using reflux for 6 hours in ethanol. Structural analysis of the product was done by FTIR and 1 H-NMR spectroscopy, while the characterization was done by determining melting point. The product was golden brown powder with a yield 99.43% and melting point more than 300 °C. Structural analysis with FTIR and 1 HNMR known vibration and signals characteristic of calix[4]resorcinarena group, the vibrations of the CH bridge. Vibration of CH bridge appearance at wave number 1445 cm-1 and 1456 cm-1, while signal of CH bridge appearance at chemical shifts from 4.17 to 4.21 ppm.https://jurnal.uns.ac.id/index.php?journal=alchemy&page=article&op=view&path[]=730characterizationC-hexyl calix[4]resorcinareneheptanalresorcinolsynthesis |
| spellingShingle | Desi Suci Handayani Zainal Arifin Almaqqomul Amin Triana Kusumaningsih Abu Masykur SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION Alchemy characterization C-hexyl calix[4]resorcinarene heptanal resorcinol synthesis |
| title | SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION |
| title_full | SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION |
| title_fullStr | SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION |
| title_full_unstemmed | SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION |
| title_short | SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION |
| title_sort | synthesis and characterization of c hexyl calix 4 resorcinarena from resorcinol heptanal condensation |
| topic | characterization C-hexyl calix[4]resorcinarene heptanal resorcinol synthesis |
| url | https://jurnal.uns.ac.id/index.php?journal=alchemy&page=article&op=view&path[]=730 |
| work_keys_str_mv | AT desisucihandayani synthesisandcharacterizationofchexylcalix4resorcinarenafromresorcinolheptanalcondensation AT zainalarifinalmaqqomulamin synthesisandcharacterizationofchexylcalix4resorcinarenafromresorcinolheptanalcondensation AT trianakusumaningsih synthesisandcharacterizationofchexylcalix4resorcinarenafromresorcinolheptanalcondensation AT abumasykur synthesisandcharacterizationofchexylcalix4resorcinarenafromresorcinolheptanalcondensation |