Coordination Chemistry of Nd(Ⅲ) and Tb(Ⅲ)with 4-hydroxysemicarbazide

Coordination Chemistry of Nd(Ⅲ) and Tb(Ⅲ)with 4-hydroxysemicarbazide

4-hydroxysemicarbazide (HSC, HL) could be used as the reducing agent for Pu(Ⅳ) in the Purex process. In this work, three complexes (Nd(HL)3+, and ) with the ratio of metal ion to HL at 1∶1, 1∶2 and 1∶3 were proved to exist through the coordination of HSC and Nd(Ⅲ) in aqueous solution by spectro...

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Bibliographic Details
Main Author: CHEN Shaokang1, YANG Qi1, ZHANG Shibo1, YANG Yating1, ZHOU jin1, HAO Xuan1, YANG Suliang1, , TIAN Guoxin1, 2
Format: Article
Language:English
Published: Editorial Board of Atomic Energy Science and Technology 2025-02-01
Series:Yuanzineng kexue jishu
Subjects:
4-hydroxysemicarbazide
nd(ⅲ)
tb(ⅲ)
coordination chemistry
structural analysis of single crystals
fluorescence lifetime measurement
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