DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION

DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION

Two MX2 (M = Ni, Zn; X = Cl, Br) dimethyl N-cyanodithioiminocarbonate compounds and one CrCl2 triphenylphosphine oxide complex were isolated and elucidated by single crystal X-ray crystallography. NiCl2[(CH3S)2C═NC≡N]2 (1) features inversion-related hydrogen bonded dimers linked into chains interac...

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Bibliographic Details
Main Authors: MOUHAMADOU BIRAME DIOP, MODOU SARR, LIBASSE DIOP, ALLEN G. OLIVER, DAVID HUGHES
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2022-01-01
Series:Journal of Engineering Studies and Research
Subjects:
crystal, dimethyl N-cyanodithioiminocarbonate, Ni(II), Zn(II), Cr(II), redox process, 2D-structure, 3D-structure
Online Access:https://jesr.ub.ro/index.php/1/article/view/284
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