DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION
Two MX2 (M = Ni, Zn; X = Cl, Br) dimethyl N-cyanodithioiminocarbonate compounds and one CrCl2 triphenylphosphine oxide complex were isolated and elucidated by single crystal X-ray crystallography. NiCl2[(CH3S)2C═NC≡N]2 (1) features inversion-related hydrogen bonded dimers linked into chains interac...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2022-01-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/284 |
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| author | MOUHAMADOU BIRAME DIOP MODOU SARR LIBASSE DIOP ALLEN G. OLIVER DAVID HUGHES |
| author_facet | MOUHAMADOU BIRAME DIOP MODOU SARR LIBASSE DIOP ALLEN G. OLIVER DAVID HUGHES |
| author_sort | MOUHAMADOU BIRAME DIOP |
| collection | DOAJ |
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Two MX2 (M = Ni, Zn; X = Cl, Br) dimethyl N-cyanodithioiminocarbonate compounds and one CrCl2 triphenylphosphine oxide complex were isolated and elucidated by single crystal X-ray crystallography. NiCl2[(CH3S)2C═NC≡N]2 (1) features inversion-related hydrogen bonded dimers linked into chains interacting through C-H···Cl growing layers along [110] whose junction into a 3D structure is enabled by H-bonds. ZnBr2[(CH3S)2C═NC≡N]2 (2) also exhibits inversion-related H-bonded dimers. In contrast with 1, the structure of 2 comprises chains along [110], connected via C-H···Br and C-H···S into a 2D layer along [-110]. CrCl2(OPPh3)2 (3) obtaining undergone redox processes, oxidizing [CH3C(O)CH2PPh3]+ to form PPh3PO, and reducing Cr from CrVI to CrII. In the structure, each molecule is linked to height neighbors through H-bonds affording a 3D network.
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| format | Article |
| id | doaj-art-f31742506bcf4bfca08b820249119907 |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2022-01-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-f31742506bcf4bfca08b8202491199072025-02-11T11:39:59ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322022-01-0127310.29081/jesr.v27i3.284DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATIONMOUHAMADOU BIRAME DIOPMODOU SARRLIBASSE DIOPALLEN G. OLIVERDAVID HUGHES Two MX2 (M = Ni, Zn; X = Cl, Br) dimethyl N-cyanodithioiminocarbonate compounds and one CrCl2 triphenylphosphine oxide complex were isolated and elucidated by single crystal X-ray crystallography. NiCl2[(CH3S)2C═NC≡N]2 (1) features inversion-related hydrogen bonded dimers linked into chains interacting through C-H···Cl growing layers along [110] whose junction into a 3D structure is enabled by H-bonds. ZnBr2[(CH3S)2C═NC≡N]2 (2) also exhibits inversion-related H-bonded dimers. In contrast with 1, the structure of 2 comprises chains along [110], connected via C-H···Br and C-H···S into a 2D layer along [-110]. CrCl2(OPPh3)2 (3) obtaining undergone redox processes, oxidizing [CH3C(O)CH2PPh3]+ to form PPh3PO, and reducing Cr from CrVI to CrII. In the structure, each molecule is linked to height neighbors through H-bonds affording a 3D network. https://jesr.ub.ro/index.php/1/article/view/284crystal, dimethyl N-cyanodithioiminocarbonate, Ni(II), Zn(II), Cr(II), redox process, 2D-structure, 3D-structure |
| spellingShingle | MOUHAMADOU BIRAME DIOP MODOU SARR LIBASSE DIOP ALLEN G. OLIVER DAVID HUGHES DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION Journal of Engineering Studies and Research crystal, dimethyl N-cyanodithioiminocarbonate, Ni(II), Zn(II), Cr(II), redox process, 2D-structure, 3D-structure |
| title | DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION |
| title_full | DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION |
| title_fullStr | DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION |
| title_full_unstemmed | DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION |
| title_short | DIMETHYL N-CYANODITHIOIMINOCARBONATE AND TRIPHENYLPHOSPHINE OXIDE METAL HALIDE COMPLEXES: MOLECULAR CRYSTAL ELUCIDATION |
| title_sort | dimethyl n cyanodithioiminocarbonate and triphenylphosphine oxide metal halide complexes molecular crystal elucidation |
| topic | crystal, dimethyl N-cyanodithioiminocarbonate, Ni(II), Zn(II), Cr(II), redox process, 2D-structure, 3D-structure |
| url | https://jesr.ub.ro/index.php/1/article/view/284 |
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