Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based Geopolymer

In this work, geopolymer synthesized with perlite and an alkaline activator medium was evaluated as a new adsorbent and photocatalyst for degradation of methylene blue (MB) dye from an aqueous medium. The functional group, the structure, and the morphology of the raw and the synthesized materials we...

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Main Authors: Hamid Saufi, Marouane El Alouani, Saliha Alehyen, Mohammed El Achouri, Jilali Aride, M’hamed Taibi
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2020/9498349
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author Hamid Saufi
Marouane El Alouani
Saliha Alehyen
Mohammed El Achouri
Jilali Aride
M’hamed Taibi
author_facet Hamid Saufi
Marouane El Alouani
Saliha Alehyen
Mohammed El Achouri
Jilali Aride
M’hamed Taibi
author_sort Hamid Saufi
collection DOAJ
description In this work, geopolymer synthesized with perlite and an alkaline activator medium was evaluated as a new adsorbent and photocatalyst for degradation of methylene blue (MB) dye from an aqueous medium. The functional group, the structure, and the morphology of the raw and the synthesized materials were characterized using FT-IR, XRD, and SEM analysis. The degradation of MB in the contaminated solution was examined using the spectrophotometric technique. Several analysis methods revealed the formation of the aluminosilicate gel after the geopolymerization reaction. The kinetics data with UV and without UV irradiations were well fitted with the pseudo-second-order equation. The results indicated that the degradation efficiency of cationic dye by perlite-based geopolymer without and with UV was up to 88.94% and 97.87% in 4 hours, respectively. The degradation efficiencies of methylene blue are in the following order: perlite-based geopolymer under UV irradiations is greater than perlite-based geopolymer without UV irradiations that is larger than UV irradiations. The overall experimental results suggested that the new elaborated material with synergetic adsorption and photocatalytic activities has a great potential for the treatment of water contaminated by hazardous substances.
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institution Kabale University
issn 1687-806X
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language English
publishDate 2020-01-01
publisher Wiley
record_format Article
series International Journal of Chemical Engineering
spelling doaj-art-f100567de438416182206b928a0379442025-02-03T06:04:38ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782020-01-01202010.1155/2020/94983499498349Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based GeopolymerHamid Saufi0Marouane El Alouani1Saliha Alehyen2Mohammed El Achouri3Jilali Aride4M’hamed Taibi5Mohammed V University in Rabat, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (ENS), Centre des Sciences des Matériaux (CSM), Rabat, MoroccoMohammed V University in Rabat, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (ENS), Centre des Sciences des Matériaux (CSM), Rabat, MoroccoMohammed V University in Rabat, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (ENS), Centre des Sciences des Matériaux (CSM), Rabat, MoroccoMohammed V University in Rabat, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (ENS), Centre des Sciences des Matériaux (CSM), Rabat, MoroccoMohammed V University in Rabat, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (ENS), Centre des Sciences des Matériaux (CSM), Rabat, MoroccoMohammed V University in Rabat, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (ENS), Centre des Sciences des Matériaux (CSM), Rabat, MoroccoIn this work, geopolymer synthesized with perlite and an alkaline activator medium was evaluated as a new adsorbent and photocatalyst for degradation of methylene blue (MB) dye from an aqueous medium. The functional group, the structure, and the morphology of the raw and the synthesized materials were characterized using FT-IR, XRD, and SEM analysis. The degradation of MB in the contaminated solution was examined using the spectrophotometric technique. Several analysis methods revealed the formation of the aluminosilicate gel after the geopolymerization reaction. The kinetics data with UV and without UV irradiations were well fitted with the pseudo-second-order equation. The results indicated that the degradation efficiency of cationic dye by perlite-based geopolymer without and with UV was up to 88.94% and 97.87% in 4 hours, respectively. The degradation efficiencies of methylene blue are in the following order: perlite-based geopolymer under UV irradiations is greater than perlite-based geopolymer without UV irradiations that is larger than UV irradiations. The overall experimental results suggested that the new elaborated material with synergetic adsorption and photocatalytic activities has a great potential for the treatment of water contaminated by hazardous substances.http://dx.doi.org/10.1155/2020/9498349
spellingShingle Hamid Saufi
Marouane El Alouani
Saliha Alehyen
Mohammed El Achouri
Jilali Aride
M’hamed Taibi
Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based Geopolymer
International Journal of Chemical Engineering
title Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based Geopolymer
title_full Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based Geopolymer
title_fullStr Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based Geopolymer
title_full_unstemmed Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based Geopolymer
title_short Photocatalytic Degradation of Methylene Blue from Aqueous Medium onto Perlite-Based Geopolymer
title_sort photocatalytic degradation of methylene blue from aqueous medium onto perlite based geopolymer
url http://dx.doi.org/10.1155/2020/9498349
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AT salihaalehyen photocatalyticdegradationofmethylenebluefromaqueousmediumontoperlitebasedgeopolymer
AT mohammedelachouri photocatalyticdegradationofmethylenebluefromaqueousmediumontoperlitebasedgeopolymer
AT jilaliaride photocatalyticdegradationofmethylenebluefromaqueousmediumontoperlitebasedgeopolymer
AT mhamedtaibi photocatalyticdegradationofmethylenebluefromaqueousmediumontoperlitebasedgeopolymer