Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2
The synthesis and characterization of cadmium and mercury complexes of selenocyanate of the type [(L)M(SeCN)2] are described, where L is L-Histidine (His) or L-Glycine (Gly) and M is Cd2+ or Hg2+. These complexes are obtained by the reaction of 1 equivalent of respective amino acids with metal disel...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2013-01-01
|
| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2013/476874 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849690259184418816 |
|---|---|
| author | Bassem A. Al-Maythalony M. Monim-ul-Mehboob Mohammed I. M. Wazeer Anvarhusein A. Isab M. Nasiruzzaman Shaikh Saleh Altuwaijri |
| author_facet | Bassem A. Al-Maythalony M. Monim-ul-Mehboob Mohammed I. M. Wazeer Anvarhusein A. Isab M. Nasiruzzaman Shaikh Saleh Altuwaijri |
| author_sort | Bassem A. Al-Maythalony |
| collection | DOAJ |
| description | The synthesis and characterization of cadmium and mercury complexes of selenocyanate of the type [(L)M(SeCN)2] are described, where L is L-Histidine (His) or L-Glycine (Gly) and M is Cd2+ or Hg2+. These complexes are obtained by the reaction of 1 equivalent of respective amino acids with metal diselenocyanate precursor in a mixture of solvents (methanol : water = 1 : 1). These synthesized compounds are characterized by analytical and various spectroscopic techniques such as elemental analysis (EA), IR, H,1 and C13 NMR in solution and in the solid state for C13 and N15. The in vitro antibacterial activities of these complexes have been investigated with standard type cultures of Escherichia coli (MTCC 443), Klebsiella pneumoniae (MTCC 109), Pseudomonas aeruginosa (MTCC 1688), Salmonella typhi (MTCC 733), and Staphylococcus aureus (MTCC 737). |
| format | Article |
| id | doaj-art-efde629e83a1409681d54cb2d69a310c |
| institution | DOAJ |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-efde629e83a1409681d54cb2d69a310c2025-08-20T03:21:22ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2013-01-01201310.1155/2013/476874476874Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2Bassem A. Al-Maythalony0M. Monim-ul-Mehboob1Mohammed I. M. Wazeer2Anvarhusein A. Isab3M. Nasiruzzaman Shaikh4Saleh Altuwaijri5Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi ArabiaDepartment of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi ArabiaDepartment of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi ArabiaDepartment of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi ArabiaCenter of Research Excellence in Nanotechnology (CENT), King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi ArabiaClinical Research Laboratory, Saad Research & Development Center, Saad Specialist Hospital, Al-Khobar 31952, Saudi ArabiaThe synthesis and characterization of cadmium and mercury complexes of selenocyanate of the type [(L)M(SeCN)2] are described, where L is L-Histidine (His) or L-Glycine (Gly) and M is Cd2+ or Hg2+. These complexes are obtained by the reaction of 1 equivalent of respective amino acids with metal diselenocyanate precursor in a mixture of solvents (methanol : water = 1 : 1). These synthesized compounds are characterized by analytical and various spectroscopic techniques such as elemental analysis (EA), IR, H,1 and C13 NMR in solution and in the solid state for C13 and N15. The in vitro antibacterial activities of these complexes have been investigated with standard type cultures of Escherichia coli (MTCC 443), Klebsiella pneumoniae (MTCC 109), Pseudomonas aeruginosa (MTCC 1688), Salmonella typhi (MTCC 733), and Staphylococcus aureus (MTCC 737).http://dx.doi.org/10.1155/2013/476874 |
| spellingShingle | Bassem A. Al-Maythalony M. Monim-ul-Mehboob Mohammed I. M. Wazeer Anvarhusein A. Isab M. Nasiruzzaman Shaikh Saleh Altuwaijri Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2 Bioinorganic Chemistry and Applications |
| title | Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2 |
| title_full | Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2 |
| title_fullStr | Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2 |
| title_full_unstemmed | Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2 |
| title_short | Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN)2 and Hg(SeCN)2 |
| title_sort | synthesis cp mas nmr characterization and antibacterial activities of glycine and histidine complexes of cd secn 2 and hg secn 2 |
| url | http://dx.doi.org/10.1155/2013/476874 |
| work_keys_str_mv | AT bassemaalmaythalony synthesiscpmasnmrcharacterizationandantibacterialactivitiesofglycineandhistidinecomplexesofcdsecn2andhgsecn2 AT mmonimulmehboob synthesiscpmasnmrcharacterizationandantibacterialactivitiesofglycineandhistidinecomplexesofcdsecn2andhgsecn2 AT mohammedimwazeer synthesiscpmasnmrcharacterizationandantibacterialactivitiesofglycineandhistidinecomplexesofcdsecn2andhgsecn2 AT anvarhuseinaisab synthesiscpmasnmrcharacterizationandantibacterialactivitiesofglycineandhistidinecomplexesofcdsecn2andhgsecn2 AT mnasiruzzamanshaikh synthesiscpmasnmrcharacterizationandantibacterialactivitiesofglycineandhistidinecomplexesofcdsecn2andhgsecn2 AT salehaltuwaijri synthesiscpmasnmrcharacterizationandantibacterialactivitiesofglycineandhistidinecomplexesofcdsecn2andhgsecn2 |