A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy

Iron deficiency anemia (IDA) is a global health concern, particularly affecting women and children of reproductive age. Although oral iron supplements are the standard treatment for IDA, their bioavailability is often compromised by food interactions, and they are associated with significant gastroi...

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Main Authors: Ying Yao, Yuanzheng Chen, Jie Fu, Jinsong Ding, Wenhu Zhou, Xinyi Chen, Xiuping Wan
Format: Article
Language:English
Published: Elsevier 2025-04-01
Series:Materials Today Bio
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590006425001565
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author Ying Yao
Yuanzheng Chen
Jie Fu
Jinsong Ding
Wenhu Zhou
Xinyi Chen
Xiuping Wan
author_facet Ying Yao
Yuanzheng Chen
Jie Fu
Jinsong Ding
Wenhu Zhou
Xinyi Chen
Xiuping Wan
author_sort Ying Yao
collection DOAJ
description Iron deficiency anemia (IDA) is a global health concern, particularly affecting women and children of reproductive age. Although oral iron supplements are the standard treatment for IDA, their bioavailability is often compromised by food interactions, and they are associated with significant gastrointestinal side effects. To overcome these limitations, we developed a novel iron nano-supplement, TA-Fe NPs, based on metal-polyphenol networks (MPNs) formed through the coordination of tannic acid (TA) and Fe3+. These uniform nanoparticles (∼190 nm) offer enhanced chemical stability and reduced food interference compared to traditional iron supplements. The polyphenolic TA component provides antioxidant properties, effectively mitigating oxidative stress and inflammation induced by free iron ions. To further improve stability and intestinal absorption, TA-Fe NPs were encapsulated in an enteric coating (TA-Fe@L100) to protect against acidic conditions in the stomach. In a mouse model of IDA, TA-Fe@L100 demonstrated superior therapeutic efficacy compared to FeSO4, including improvements in hematological parameters, organ iron storage, and gut microbiota balance. Importantly, TA-Fe@L100 alleviated common gastrointestinal side effects associated with iron supplementation, presenting a promising alternative for IDA treatment. Our findings suggest that TA-Fe@L100 is a cost-effective and biocompatible oral iron supplement with minimal side effects, offering significant potential for broader clinical application in the management of IDA.
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spelling doaj-art-efd6b957c7054a259846a918e5686de82025-08-20T03:13:18ZengElsevierMaterials Today Bio2590-00642025-04-013110159810.1016/j.mtbio.2025.101598A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapyYing Yao0Yuanzheng Chen1Jie Fu2Jinsong Ding3Wenhu Zhou4Xinyi Chen5Xiuping Wan6Xiangya School of Pharmaceutical Sciences, Central South University, Changsha, Hunan, 410013, ChinaXiangya School of Pharmaceutical Sciences, Central South University, Changsha, Hunan, 410013, ChinaXiangya School of Pharmaceutical Sciences, Central South University, Changsha, Hunan, 410013, ChinaXiangya School of Pharmaceutical Sciences, Central South University, Changsha, Hunan, 410013, ChinaXiangya School of Pharmaceutical Sciences, Central South University, Changsha, Hunan, 410013, China; Corresponding author.Yongkang First People's Hospital of Wenzhou Medical University, Jinhua, 321300, China; Corresponding author.Department of Gastroenterology, The Quzhou Affiliated Hospital of Wenzhou Medical University, Quzhou People's Hospital, Quzhou, 324000, China; Corresponding author.Iron deficiency anemia (IDA) is a global health concern, particularly affecting women and children of reproductive age. Although oral iron supplements are the standard treatment for IDA, their bioavailability is often compromised by food interactions, and they are associated with significant gastrointestinal side effects. To overcome these limitations, we developed a novel iron nano-supplement, TA-Fe NPs, based on metal-polyphenol networks (MPNs) formed through the coordination of tannic acid (TA) and Fe3+. These uniform nanoparticles (∼190 nm) offer enhanced chemical stability and reduced food interference compared to traditional iron supplements. The polyphenolic TA component provides antioxidant properties, effectively mitigating oxidative stress and inflammation induced by free iron ions. To further improve stability and intestinal absorption, TA-Fe NPs were encapsulated in an enteric coating (TA-Fe@L100) to protect against acidic conditions in the stomach. In a mouse model of IDA, TA-Fe@L100 demonstrated superior therapeutic efficacy compared to FeSO4, including improvements in hematological parameters, organ iron storage, and gut microbiota balance. Importantly, TA-Fe@L100 alleviated common gastrointestinal side effects associated with iron supplementation, presenting a promising alternative for IDA treatment. Our findings suggest that TA-Fe@L100 is a cost-effective and biocompatible oral iron supplement with minimal side effects, offering significant potential for broader clinical application in the management of IDA.http://www.sciencedirect.com/science/article/pii/S2590006425001565Metal-organic-frameworksOral iron supplementsGut microbiota homeostasisOxidative stressEnteric coating
spellingShingle Ying Yao
Yuanzheng Chen
Jie Fu
Jinsong Ding
Wenhu Zhou
Xinyi Chen
Xiuping Wan
A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy
Materials Today Bio
Metal-organic-frameworks
Oral iron supplements
Gut microbiota homeostasis
Oxidative stress
Enteric coating
title A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy
title_full A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy
title_fullStr A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy
title_full_unstemmed A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy
title_short A metal-polyphenol network-based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy
title_sort metal polyphenol network based iron supplement with improved stability and reduced gastrointestinal toxicity for iron deficiency anemia therapy
topic Metal-organic-frameworks
Oral iron supplements
Gut microbiota homeostasis
Oxidative stress
Enteric coating
url http://www.sciencedirect.com/science/article/pii/S2590006425001565
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