Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
A novel complex of cadmium (II) picrate (pic) with V-shaped ligand bis(N-allylbenzimidazol-2-ylmethyl)benzylamine (babb), with composition [Cd(babb)2](pic)2, was synthesized and characterized by elemental...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2011-01-01
|
| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2011/705989 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832563881984131072 |
|---|---|
| author | Huilu Wu Jingkun Yuan Ying Bai Fan Kou Fei Jia Bin Liu |
| author_facet | Huilu Wu Jingkun Yuan Ying Bai Fan Kou Fei Jia Bin Liu |
| author_sort | Huilu Wu |
| collection | DOAJ |
| description | A novel complex of
cadmium (II) picrate (pic) with V-shaped ligand
bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
(babb), with composition
[Cd(babb)2](pic)2, was
synthesized and characterized by elemental
analyses and electrical conductivity, IR, and
UV/visible spectra. The crystal structure of the
complex has been determined by the
single-crystal X-ray diffraction. In the
complex, the coordination sphere around Cd (II)
is distorted octahedral, six nitrogen atoms
involved in coordination afforded by two
tridentate ligand babb. Moreover, The
DNA-binding properties of the ligand babb and Cd
(II) complex were investigated by
spectrophotometric methods and viscosity
measurements, and the results suggest that they
bind to DNA via an intercalation binding mode,
and the Cd (II) complex shows higher affinity
than the ligand. |
| format | Article |
| id | doaj-art-ef9248e41876434ba333fda04d5f487b |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-ef9248e41876434ba333fda04d5f487b2025-02-03T01:12:23ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2011-01-01201110.1155/2011/705989705989Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamineHuilu Wu0Jingkun Yuan1Ying Bai2Fan Kou3Fei Jia4Bin Liu5School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaA novel complex of cadmium (II) picrate (pic) with V-shaped ligand bis(N-allylbenzimidazol-2-ylmethyl)benzylamine (babb), with composition [Cd(babb)2](pic)2, was synthesized and characterized by elemental analyses and electrical conductivity, IR, and UV/visible spectra. The crystal structure of the complex has been determined by the single-crystal X-ray diffraction. In the complex, the coordination sphere around Cd (II) is distorted octahedral, six nitrogen atoms involved in coordination afforded by two tridentate ligand babb. Moreover, The DNA-binding properties of the ligand babb and Cd (II) complex were investigated by spectrophotometric methods and viscosity measurements, and the results suggest that they bind to DNA via an intercalation binding mode, and the Cd (II) complex shows higher affinity than the ligand.http://dx.doi.org/10.1155/2011/705989 |
| spellingShingle | Huilu Wu Jingkun Yuan Ying Bai Fan Kou Fei Jia Bin Liu Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine Bioinorganic Chemistry and Applications |
| title | Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine |
| title_full | Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine |
| title_fullStr | Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine |
| title_full_unstemmed | Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine |
| title_short | Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine |
| title_sort | synthesis crystal structure and spectra properties of the cadmium ii complex with bis n allylbenzimidazol 2 ylmethyl benzylamine |
| url | http://dx.doi.org/10.1155/2011/705989 |
| work_keys_str_mv | AT huiluwu synthesiscrystalstructureandspectrapropertiesofthecadmiumiicomplexwithbisnallylbenzimidazol2ylmethylbenzylamine AT jingkunyuan synthesiscrystalstructureandspectrapropertiesofthecadmiumiicomplexwithbisnallylbenzimidazol2ylmethylbenzylamine AT yingbai synthesiscrystalstructureandspectrapropertiesofthecadmiumiicomplexwithbisnallylbenzimidazol2ylmethylbenzylamine AT fankou synthesiscrystalstructureandspectrapropertiesofthecadmiumiicomplexwithbisnallylbenzimidazol2ylmethylbenzylamine AT feijia synthesiscrystalstructureandspectrapropertiesofthecadmiumiicomplexwithbisnallylbenzimidazol2ylmethylbenzylamine AT binliu synthesiscrystalstructureandspectrapropertiesofthecadmiumiicomplexwithbisnallylbenzimidazol2ylmethylbenzylamine |