Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate
Cleavage of benzalazine (and other azines) with periodic acid may initially involve, as a single step, the addition of IO4- (or its hydrate) across the conjugated azine system, to give an iodate I (V) complex; this view is supported from MO symmetry rules.
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
1972-02-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/8989 |
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| _version_ | 1850283873870544896 |
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| author | Alexander J. Fatiadi |
| author_facet | Alexander J. Fatiadi |
| author_sort | Alexander J. Fatiadi |
| collection | DOAJ |
| description |
Cleavage of benzalazine (and other azines) with periodic acid may initially involve, as a single step, the addition of IO4- (or its hydrate) across the conjugated azine system, to give an iodate I (V) complex; this view is supported from MO symmetry rules.
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| format | Article |
| id | doaj-art-ef914da19d27432eb7d7e656a09b31a7 |
| institution | OA Journals |
| issn | 0009-4293 2673-2424 |
| language | deu |
| publishDate | 1972-02-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj-art-ef914da19d27432eb7d7e656a09b31a72025-08-20T01:47:41ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241972-02-0126210.2533/chimia.1972.70Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction IntermediateAlexander J. Fatiadi0Analytical Chemistry Division, Institute for Materials Research, National Bureau of Standards, Washington (D. C.) 20234 (U.S.A.) Cleavage of benzalazine (and other azines) with periodic acid may initially involve, as a single step, the addition of IO4- (or its hydrate) across the conjugated azine system, to give an iodate I (V) complex; this view is supported from MO symmetry rules. https://www.chimia.ch/chimia/article/view/8989 |
| spellingShingle | Alexander J. Fatiadi Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate CHIMIA |
| title | Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate |
| title_full | Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate |
| title_fullStr | Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate |
| title_full_unstemmed | Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate |
| title_short | Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate |
| title_sort | oxidative cleavage of aromatic azines with periodic acid mo model for the reaction intermediate |
| url | https://www.chimia.ch/chimia/article/view/8989 |
| work_keys_str_mv | AT alexanderjfatiadi oxidativecleavageofaromaticazineswithperiodicacidmomodelforthereactionintermediate |