Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate
Cleavage of benzalazine (and other azines) with periodic acid may initially involve, as a single step, the addition of IO4- (or its hydrate) across the conjugated azine system, to give an iodate I (V) complex; this view is supported from MO symmetry rules.
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| Main Author: | |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1972-02-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/8989 |
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| Summary: | Cleavage of benzalazine (and other azines) with periodic acid may initially involve, as a single step, the addition of IO4- (or its hydrate) across the conjugated azine system, to give an iodate I (V) complex; this view is supported from MO symmetry rules.
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| ISSN: | 0009-4293 2673-2424 |