Molecular composition and properties of impact propylene copolymers

Impact polypropylene copolymers (IPCs) are important commercial materials, but their morphology and molecular architecture are not yet fully understood. In this study the focus was on selectively removing specific fractions from the original IPC, recombining the remaining fractions, and studying the...

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Main Authors: A. J. van Reenen, C. N. Basson
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2012-05-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0002999&mi=cd
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author A. J. van Reenen
C. N. Basson
author_facet A. J. van Reenen
C. N. Basson
author_sort A. J. van Reenen
collection DOAJ
description Impact polypropylene copolymers (IPCs) are important commercial materials, but their morphology and molecular architecture are not yet fully understood. In this study the focus was on selectively removing specific fractions from the original IPC, recombining the remaining fractions, and studying the properties and morphology of these recombined polymers. It was found that some properties of the samples changed remarkably, depending on the fraction of material that was removed before recombination. In a similar fashion, morphological changes could be observed. For example, the degree of phase separation and the crystalline morphology of the recombined materials varied noticeably. It was further established that specific copolymer fractions present in the original polymer affect not only the morphology of the final polymer, but also the hardness and impact resistance.
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institution Kabale University
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publisher Budapest University of Technology and Economics
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series eXPRESS Polymer Letters
spelling doaj-art-ef7e56f301d34d2782adf2441bcacb952025-08-20T03:57:55ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2012-05-016542743610.3144/expresspolymlett.2012.45Molecular composition and properties of impact propylene copolymersA. J. van ReenenC. N. BassonImpact polypropylene copolymers (IPCs) are important commercial materials, but their morphology and molecular architecture are not yet fully understood. In this study the focus was on selectively removing specific fractions from the original IPC, recombining the remaining fractions, and studying the properties and morphology of these recombined polymers. It was found that some properties of the samples changed remarkably, depending on the fraction of material that was removed before recombination. In a similar fashion, morphological changes could be observed. For example, the degree of phase separation and the crystalline morphology of the recombined materials varied noticeably. It was further established that specific copolymer fractions present in the original polymer affect not only the morphology of the final polymer, but also the hardness and impact resistance.http://www.expresspolymlett.com/letolt.php?file=EPL-0002999&mi=cdMechanical propertiesImpact propylene copolymersTemperature rising elution fraMolecular compositionMorphology
spellingShingle A. J. van Reenen
C. N. Basson
Molecular composition and properties of impact propylene copolymers
eXPRESS Polymer Letters
Mechanical properties
Impact propylene copolymers
Temperature rising elution fra
Molecular composition
Morphology
title Molecular composition and properties of impact propylene copolymers
title_full Molecular composition and properties of impact propylene copolymers
title_fullStr Molecular composition and properties of impact propylene copolymers
title_full_unstemmed Molecular composition and properties of impact propylene copolymers
title_short Molecular composition and properties of impact propylene copolymers
title_sort molecular composition and properties of impact propylene copolymers
topic Mechanical properties
Impact propylene copolymers
Temperature rising elution fra
Molecular composition
Morphology
url http://www.expresspolymlett.com/letolt.php?file=EPL-0002999&mi=cd
work_keys_str_mv AT ajvanreenen molecularcompositionandpropertiesofimpactpropylenecopolymers
AT cnbasson molecularcompositionandpropertiesofimpactpropylenecopolymers