Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee Powder

In this work, the possibility of using immobilized spent coffee powder (ISCP) as an adsorbent for crystal violet (CV) adsorption from an aqueous solution was analyzed. The effect of process parameters such as pH, contact time, number of ISCP films, and initial CV concentrations on the removal of CV...

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Main Authors: Jia-Jun Teoh, Siew-Teng Ong, Sie-Tiong Ha
Format: Article
Language:English
Published: Department of Chemistry, Universitas Gadjah Mada 2025-03-01
Series:Indonesian Journal of Chemistry
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Online Access:https://jurnal.ugm.ac.id/ijc/article/view/101370
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author Jia-Jun Teoh
Siew-Teng Ong
Sie-Tiong Ha
author_facet Jia-Jun Teoh
Siew-Teng Ong
Sie-Tiong Ha
author_sort Jia-Jun Teoh
collection DOAJ
description In this work, the possibility of using immobilized spent coffee powder (ISCP) as an adsorbent for crystal violet (CV) adsorption from an aqueous solution was analyzed. The effect of process parameters such as pH, contact time, number of ISCP films, and initial CV concentrations on the removal of CV was studied. The optimum pH for the adsorption of CV was found to be at pH 7. The adsorption was rapid at the initial stage, and equilibrium was achieved in 100 min. The adsorption of CV increased with the increasing number of ISCP films. Characterization of ISCP was carried out by using FESEM and ATR-FTIR. Langmuir isotherm model can be used to explain the equilibrium data, and a maximum sorption capacity of 97.09 mg/g with a high coefficient of determination (R2) of 0.9986, was obtained. The experimental data were found to be fitted well into the pseudo-second-order kinetic model. From the Plackett-Burman results, both contact time and pH were identified as significant factors. Under the optimum experimental conditions based on RSM, the percentage uptake predicted by the model was in close agreement with the experimental values.
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language English
publishDate 2025-03-01
publisher Department of Chemistry, Universitas Gadjah Mada
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series Indonesian Journal of Chemistry
spelling doaj-art-ef24a2aaf36c4ad4b1ff1cba54faca2c2025-08-20T03:08:35ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782025-03-0125254856010.22146/ijc.10137037169Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee PowderJia-Jun Teoh0Siew-Teng Ong1Sie-Tiong Ha2Faculty of Science, Universiti Tunku Abdul Rahman, Jl. Universiti, Bandar Barat, 31900 Kampar, Perak, MalaysiaFaculty of Science, Universiti Tunku Abdul Rahman, Jl. Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia; Center for Agriculture and Food Research, Universiti Tunku Abdul Rahman, Jl. Universiti, Bandar Barat, 31900 Kampar, Perak, MalaysiaFaculty of Science, Universiti Tunku Abdul Rahman, Jl. Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia; Center for Agriculture and Food Research, Universiti Tunku Abdul Rahman, Jl. Universiti, Bandar Barat, 31900 Kampar, Perak, MalaysiaIn this work, the possibility of using immobilized spent coffee powder (ISCP) as an adsorbent for crystal violet (CV) adsorption from an aqueous solution was analyzed. The effect of process parameters such as pH, contact time, number of ISCP films, and initial CV concentrations on the removal of CV was studied. The optimum pH for the adsorption of CV was found to be at pH 7. The adsorption was rapid at the initial stage, and equilibrium was achieved in 100 min. The adsorption of CV increased with the increasing number of ISCP films. Characterization of ISCP was carried out by using FESEM and ATR-FTIR. Langmuir isotherm model can be used to explain the equilibrium data, and a maximum sorption capacity of 97.09 mg/g with a high coefficient of determination (R2) of 0.9986, was obtained. The experimental data were found to be fitted well into the pseudo-second-order kinetic model. From the Plackett-Burman results, both contact time and pH were identified as significant factors. Under the optimum experimental conditions based on RSM, the percentage uptake predicted by the model was in close agreement with the experimental values.https://jurnal.ugm.ac.id/ijc/article/view/101370crystal violetcoffee powderadsorptionkineticsisotherm
spellingShingle Jia-Jun Teoh
Siew-Teng Ong
Sie-Tiong Ha
Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee Powder
Indonesian Journal of Chemistry
crystal violet
coffee powder
adsorption
kinetics
isotherm
title Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee Powder
title_full Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee Powder
title_fullStr Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee Powder
title_full_unstemmed Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee Powder
title_short Removal of Crystal Violet Dye from Aqueous Solution Using Immobilized Spent Coffee Powder
title_sort removal of crystal violet dye from aqueous solution using immobilized spent coffee powder
topic crystal violet
coffee powder
adsorption
kinetics
isotherm
url https://jurnal.ugm.ac.id/ijc/article/view/101370
work_keys_str_mv AT jiajunteoh removalofcrystalvioletdyefromaqueoussolutionusingimmobilizedspentcoffeepowder
AT siewtengong removalofcrystalvioletdyefromaqueoussolutionusingimmobilizedspentcoffeepowder
AT sietiongha removalofcrystalvioletdyefromaqueoussolutionusingimmobilizedspentcoffeepowder