Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer Cells

<b>Background/Objectives</b>:Cancer vaccine targets mostly include mutations and overexpressed proteins. However, cancer-associated post-translational modifications (PTMs) may also induce immune responses. Previously, our group established the enzyme protein arginine deiminase type-2 (PA...

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Main Authors: Ricardo A. León-Letelier, Alejandro M. Sevillano-Mantas, Yihui Chen, Soyoung Park, Jody Vykoukal, Johannes F. Fahrmann, Edwin J. Ostrin, Candace Garrett, Rongzhang Dou, Yining Cai, Fu-Chung Hsiao, Jennifer B. Dennison, Eduardo Vilar, Banu K. Arun, Samir Hanash, Hiroyuki Katayama
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Vaccines
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Online Access:https://www.mdpi.com/2076-393X/13/6/629
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author Ricardo A. León-Letelier
Alejandro M. Sevillano-Mantas
Yihui Chen
Soyoung Park
Jody Vykoukal
Johannes F. Fahrmann
Edwin J. Ostrin
Candace Garrett
Rongzhang Dou
Yining Cai
Fu-Chung Hsiao
Jennifer B. Dennison
Eduardo Vilar
Banu K. Arun
Samir Hanash
Hiroyuki Katayama
author_facet Ricardo A. León-Letelier
Alejandro M. Sevillano-Mantas
Yihui Chen
Soyoung Park
Jody Vykoukal
Johannes F. Fahrmann
Edwin J. Ostrin
Candace Garrett
Rongzhang Dou
Yining Cai
Fu-Chung Hsiao
Jennifer B. Dennison
Eduardo Vilar
Banu K. Arun
Samir Hanash
Hiroyuki Katayama
author_sort Ricardo A. León-Letelier
collection DOAJ
description <b>Background/Objectives</b>:Cancer vaccine targets mostly include mutations and overexpressed proteins. However, cancer-associated post-translational modifications (PTMs) may also induce immune responses. Previously, our group established the enzyme protein arginine deiminase type-2 (PADI2), which catalyzes citrullination modification, is highly expressed in triple-negative breast cancer (TNBC), promoting antigenicity. <b>Methods</b>: Here, we show the workflow of designing citrullinated enolase 1 (citENO1) vaccine peptides identified from breast cancer cells by mass spectrometry and demonstrate TNBC vaccine efficacy in the mouse model. Immunized mice with citENO1 peptides or the corresponding unmodified peptides, plus Poly I:C as an adjuvant, were orthotopically implanted with a TNBC murine cell line. <b>Results</b>: Vaccination with citENO1, but not unmodified ENO1 (umENO1), induced a greater percentage of activated CD8+ PD-1+ T cells and effector memory T cells in skin-draining lymph nodes (SDLNs). Remarkably, the citENO1 vaccine delayed tumor growth and prolonged overall survival, which was further enhanced by PD-1 blockade. <b>Conclusions</b>: Our data suggest that cancer-restricted post-translational modifications provide a source of vaccines that induce an anti-cancer immune response.
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spelling doaj-art-ef0b1319a8e5451ab6bfce9cbe543baa2025-08-20T02:21:58ZengMDPI AGVaccines2076-393X2025-06-0113662910.3390/vaccines13060629Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer CellsRicardo A. León-Letelier0Alejandro M. Sevillano-Mantas1Yihui Chen2Soyoung Park3Jody Vykoukal4Johannes F. Fahrmann5Edwin J. Ostrin6Candace Garrett7Rongzhang Dou8Yining Cai9Fu-Chung Hsiao10Jennifer B. Dennison11Eduardo Vilar12Banu K. Arun13Samir Hanash14Hiroyuki Katayama15Department of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of General Internal Medicine, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Breast Medical Oncology, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USADepartment of Clinical Cancer Prevention, The University of Texas MD Anderson Cancer Center, Houston, TX 77030, USA<b>Background/Objectives</b>:Cancer vaccine targets mostly include mutations and overexpressed proteins. However, cancer-associated post-translational modifications (PTMs) may also induce immune responses. Previously, our group established the enzyme protein arginine deiminase type-2 (PADI2), which catalyzes citrullination modification, is highly expressed in triple-negative breast cancer (TNBC), promoting antigenicity. <b>Methods</b>: Here, we show the workflow of designing citrullinated enolase 1 (citENO1) vaccine peptides identified from breast cancer cells by mass spectrometry and demonstrate TNBC vaccine efficacy in the mouse model. Immunized mice with citENO1 peptides or the corresponding unmodified peptides, plus Poly I:C as an adjuvant, were orthotopically implanted with a TNBC murine cell line. <b>Results</b>: Vaccination with citENO1, but not unmodified ENO1 (umENO1), induced a greater percentage of activated CD8+ PD-1+ T cells and effector memory T cells in skin-draining lymph nodes (SDLNs). Remarkably, the citENO1 vaccine delayed tumor growth and prolonged overall survival, which was further enhanced by PD-1 blockade. <b>Conclusions</b>: Our data suggest that cancer-restricted post-translational modifications provide a source of vaccines that induce an anti-cancer immune response.https://www.mdpi.com/2076-393X/13/6/629cancer vaccinepost-translational modificationimmunopeptidometriple-negative breast cancerPD-1 blockade
spellingShingle Ricardo A. León-Letelier
Alejandro M. Sevillano-Mantas
Yihui Chen
Soyoung Park
Jody Vykoukal
Johannes F. Fahrmann
Edwin J. Ostrin
Candace Garrett
Rongzhang Dou
Yining Cai
Fu-Chung Hsiao
Jennifer B. Dennison
Eduardo Vilar
Banu K. Arun
Samir Hanash
Hiroyuki Katayama
Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer Cells
Vaccines
cancer vaccine
post-translational modification
immunopeptidome
triple-negative breast cancer
PD-1 blockade
title Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer Cells
title_full Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer Cells
title_fullStr Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer Cells
title_full_unstemmed Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer Cells
title_short Citrullinated ENO1 Vaccine Enhances PD-1 Blockade in Mice Implanted with Murine Triple-Negative Breast Cancer Cells
title_sort citrullinated eno1 vaccine enhances pd 1 blockade in mice implanted with murine triple negative breast cancer cells
topic cancer vaccine
post-translational modification
immunopeptidome
triple-negative breast cancer
PD-1 blockade
url https://www.mdpi.com/2076-393X/13/6/629
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