Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound delivery

Abstract Carbon nanotubes (CNTs) have the potential to serve as delivery systems for medicinal substances and gene treatments, particularly in cancer treatment. Co-delivery of curcumin (CUR) and Methotrexate (MTX) has shown promise in cancer treatment, as it uses fewer drugs and has fewer side effec...

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Main Authors: Masoumeh Nabitabar, Maryam Shaterian, Hossein Danafar, Morteza Enhessari
Format: Article
Language:English
Published: Nature Portfolio 2024-05-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-024-59745-6
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author Masoumeh Nabitabar
Maryam Shaterian
Hossein Danafar
Morteza Enhessari
author_facet Masoumeh Nabitabar
Maryam Shaterian
Hossein Danafar
Morteza Enhessari
author_sort Masoumeh Nabitabar
collection DOAJ
description Abstract Carbon nanotubes (CNTs) have the potential to serve as delivery systems for medicinal substances and gene treatments, particularly in cancer treatment. Co-delivery of curcumin (CUR) and Methotrexate (MTX) has shown promise in cancer treatment, as it uses fewer drugs and has fewer side effects. This study used MTX-conjugated albumin (BSA)-based nanoparticles (BSA-MTX) to enhance and assess the efficiency of CUR. In-vitro cytotoxicity tests, DLS, TEM, FTIR, UV/Vis, SEM, and DSC studies assessed the formulations' physical and chemical properties. The Proteinase K enzyme was used to severe amidic linkages between MTX and BSA. The findings demonstrated the efficacy of using ƒ-MWCNT-CUR-BSA-MTX as a vehicle for efficient co-delivery of CUR and MTX in cancer treatment. The MTT colorimetric method was used to evaluate the effect of chemical and medicinal compounds. Cell division was studied using the MTT method to investigate the effect of pure MWCNT, pure CUR, MTX-BSA, and ƒ-MWCNT-CUR-MTX-BSA. Studies on cell lines have shown that the combination of curcumin and MTX with CNT can increase and improve the effectiveness of both drugs against cancer. A combination of drugs curcumin and methotrexate simultaneously had a synergistic effect on MCF-7 cells, which indicated that these drugs could potentially be used as a strategy for both prevention and treatment of breast cancer. Also, ƒ-MWCNT-CUR-MTX-BSA was found to have a significant effect on cancer treatment with minimal toxicity compared to pure curcumin, pure MTX-BSA, MTX, and ƒ-MWCNT alone. Unique properties such as a high ratio of specific surface area to volume, high chemical stability, chemical adsorption ability, high capacity of drug and biomolecules of carbon nanotubes, as well as multiple drug loading at the same time The combination of ƒ-MWCNT-CUR-BSA MTX significantly impacts cancer therapy), are desirable as an alternative option for targeted drug delivery and high therapeutic efficiency.
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spelling doaj-art-eeed1574b51543d8a741ad1aecbf08102025-08-20T02:31:51ZengNature PortfolioScientific Reports2045-23222024-05-0114111310.1038/s41598-024-59745-6Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound deliveryMasoumeh Nabitabar0Maryam Shaterian1Hossein Danafar2Morteza Enhessari3Chemistry Department, Faculty of Science, Zanjan UniversityChemistry Department, Faculty of Science, Zanjan UniversityZanjan Pharmaceutical Nanotechnology Research Center, Zanjan University of Medical SciencesFachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie—Anorganische Chemie, Freie Universität BerlinAbstract Carbon nanotubes (CNTs) have the potential to serve as delivery systems for medicinal substances and gene treatments, particularly in cancer treatment. Co-delivery of curcumin (CUR) and Methotrexate (MTX) has shown promise in cancer treatment, as it uses fewer drugs and has fewer side effects. This study used MTX-conjugated albumin (BSA)-based nanoparticles (BSA-MTX) to enhance and assess the efficiency of CUR. In-vitro cytotoxicity tests, DLS, TEM, FTIR, UV/Vis, SEM, and DSC studies assessed the formulations' physical and chemical properties. The Proteinase K enzyme was used to severe amidic linkages between MTX and BSA. The findings demonstrated the efficacy of using ƒ-MWCNT-CUR-BSA-MTX as a vehicle for efficient co-delivery of CUR and MTX in cancer treatment. The MTT colorimetric method was used to evaluate the effect of chemical and medicinal compounds. Cell division was studied using the MTT method to investigate the effect of pure MWCNT, pure CUR, MTX-BSA, and ƒ-MWCNT-CUR-MTX-BSA. Studies on cell lines have shown that the combination of curcumin and MTX with CNT can increase and improve the effectiveness of both drugs against cancer. A combination of drugs curcumin and methotrexate simultaneously had a synergistic effect on MCF-7 cells, which indicated that these drugs could potentially be used as a strategy for both prevention and treatment of breast cancer. Also, ƒ-MWCNT-CUR-MTX-BSA was found to have a significant effect on cancer treatment with minimal toxicity compared to pure curcumin, pure MTX-BSA, MTX, and ƒ-MWCNT alone. Unique properties such as a high ratio of specific surface area to volume, high chemical stability, chemical adsorption ability, high capacity of drug and biomolecules of carbon nanotubes, as well as multiple drug loading at the same time The combination of ƒ-MWCNT-CUR-BSA MTX significantly impacts cancer therapy), are desirable as an alternative option for targeted drug delivery and high therapeutic efficiency.https://doi.org/10.1038/s41598-024-59745-6Drug deliveryBreast cancerƒ-MWCNTLoad-releaseMTT assay
spellingShingle Masoumeh Nabitabar
Maryam Shaterian
Hossein Danafar
Morteza Enhessari
Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound delivery
Scientific Reports
Drug delivery
Breast cancer
ƒ-MWCNT
Load-release
MTT assay
title Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound delivery
title_full Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound delivery
title_fullStr Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound delivery
title_full_unstemmed Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound delivery
title_short Multi-wall carbon Nanotube surface-based functional nanoparticles for stimuli-responsive dual pharmaceutical compound delivery
title_sort multi wall carbon nanotube surface based functional nanoparticles for stimuli responsive dual pharmaceutical compound delivery
topic Drug delivery
Breast cancer
ƒ-MWCNT
Load-release
MTT assay
url https://doi.org/10.1038/s41598-024-59745-6
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AT hosseindanafar multiwallcarbonnanotubesurfacebasedfunctionalnanoparticlesforstimuliresponsivedualpharmaceuticalcompounddelivery
AT mortezaenhessari multiwallcarbonnanotubesurfacebasedfunctionalnanoparticlesforstimuliresponsivedualpharmaceuticalcompounddelivery