Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteus
Miscanthus x giganteus phytoremediation of soil contaminated with petroleum was assessed in this study. A method of soil sample preparation for determining the total content of petroleum products by infrared spectrophotometry has been developed. It is a one-stage extraction method with minimal use o...
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Elsevier
2024-12-01
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844024167448 |
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| author | Ruslana Huminilovych Vitalii Stadnik Martyn Sozanskyi Pavlo Shapoval Valentina Pidlisnyuk Ihor Poliuzhyn Viktoriia Kochubei Yurii Hrynchuk Bohdan Korchak |
| author_facet | Ruslana Huminilovych Vitalii Stadnik Martyn Sozanskyi Pavlo Shapoval Valentina Pidlisnyuk Ihor Poliuzhyn Viktoriia Kochubei Yurii Hrynchuk Bohdan Korchak |
| author_sort | Ruslana Huminilovych |
| collection | DOAJ |
| description | Miscanthus x giganteus phytoremediation of soil contaminated with petroleum was assessed in this study. A method of soil sample preparation for determining the total content of petroleum products by infrared spectrophotometry has been developed. It is a one-stage extraction method with minimal use of carbon tetrachloride as an extractant. This soil sample preparation method was environmentally friendly and cost-effective, as it required a significantly lower amount of extractant (15–30 ml of tetrachloromethane) compared to the commonly used threefold extraction method, which uses up to 150 ml of extractant. The extraction degree of petroleum products (PP) was determined to be from 81.78 % to 94.22 % after two days of extraction using the additive method of determining PP. It was observed that the presence of different fertilizer additives in the soil samples led to a reduction in the determined PP content in the following series: “without fertilizer” – “Biochar” additive – “Biohumus” additive. These results were compared with reference samples that did not involve the use of Miscanthus x giganteus. Furthermore, the main thermolysis stages of petroleum products sorbed by the soil matrix and the thermal behavior of an artificial soil sample spiked with PP were examined. Detailed interpretation of thermograms of laboratory soil samples was conducted at various phytoremediation stages. |
| format | Article |
| id | doaj-art-eebd9be0251f47e8a9a005358f936e46 |
| institution | OA Journals |
| issn | 2405-8440 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Heliyon |
| spelling | doaj-art-eebd9be0251f47e8a9a005358f936e462025-08-20T01:59:31ZengElsevierHeliyon2405-84402024-12-011023e4071310.1016/j.heliyon.2024.e40713Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteusRuslana Huminilovych0Vitalii Stadnik1Martyn Sozanskyi2Pavlo Shapoval3Valentina Pidlisnyuk4Ihor Poliuzhyn5Viktoriia Kochubei6Yurii Hrynchuk7Bohdan Korchak8Department of Physical, Analytical and General Chemistry, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, Ukraine; Corresponding author.Department of Physical, Analytical and General Chemistry, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, UkraineDepartment of Physical, Analytical and General Chemistry, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, UkraineDepartment of Physical, Analytical and General Chemistry, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, UkraineDepartment of Environmental Chemistry and Technology, Faculty of Environment, Jan Evangelista Purkyne University in Ústí nad Labem, 400 96, Ústí nad Labem, Czech RepublicDepartment of Physical, Analytical and General Chemistry, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, UkraineDepartment of Physical, Analytical and General Chemistry, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, UkraineDepartment of Physical, Analytical and General Chemistry, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, UkraineDepartment of Civil Safety, Lviv Polytechnic National University, 12 S. Bandery St., 79013, Lviv, UkraineMiscanthus x giganteus phytoremediation of soil contaminated with petroleum was assessed in this study. A method of soil sample preparation for determining the total content of petroleum products by infrared spectrophotometry has been developed. It is a one-stage extraction method with minimal use of carbon tetrachloride as an extractant. This soil sample preparation method was environmentally friendly and cost-effective, as it required a significantly lower amount of extractant (15–30 ml of tetrachloromethane) compared to the commonly used threefold extraction method, which uses up to 150 ml of extractant. The extraction degree of petroleum products (PP) was determined to be from 81.78 % to 94.22 % after two days of extraction using the additive method of determining PP. It was observed that the presence of different fertilizer additives in the soil samples led to a reduction in the determined PP content in the following series: “without fertilizer” – “Biochar” additive – “Biohumus” additive. These results were compared with reference samples that did not involve the use of Miscanthus x giganteus. Furthermore, the main thermolysis stages of petroleum products sorbed by the soil matrix and the thermal behavior of an artificial soil sample spiked with PP were examined. Detailed interpretation of thermograms of laboratory soil samples was conducted at various phytoremediation stages.http://www.sciencedirect.com/science/article/pii/S2405844024167448PhytoremediationPetroleum productsInfrared spectrophotometryThermal analysisExtractionMiscanthus x giganteus |
| spellingShingle | Ruslana Huminilovych Vitalii Stadnik Martyn Sozanskyi Pavlo Shapoval Valentina Pidlisnyuk Ihor Poliuzhyn Viktoriia Kochubei Yurii Hrynchuk Bohdan Korchak Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteus Heliyon Phytoremediation Petroleum products Infrared spectrophotometry Thermal analysis Extraction Miscanthus x giganteus |
| title | Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteus |
| title_full | Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteus |
| title_fullStr | Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteus |
| title_full_unstemmed | Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteus |
| title_short | Sample preparation method for IR analysis of petroleum-contaminated soil: An innovative technology for ecological remediation using Miscanthus x giganteus |
| title_sort | sample preparation method for ir analysis of petroleum contaminated soil an innovative technology for ecological remediation using miscanthus x giganteus |
| topic | Phytoremediation Petroleum products Infrared spectrophotometry Thermal analysis Extraction Miscanthus x giganteus |
| url | http://www.sciencedirect.com/science/article/pii/S2405844024167448 |
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