Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZT
Solid solutions (SS) with a quasi-binary cross-section of a four-component system of the composition [Formula: see text](Na[Formula: see text]K[Formula: see text])NbO3–xPb(Ti[Formula: see text]Zr[Formula: see text])O3, based on compositions with fundamentally different physical responses (Na, K)NbO3...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
World Scientific Publishing
2025-06-01
|
| Series: | Journal of Advanced Dielectrics |
| Subjects: | |
| Online Access: | https://www.worldscientific.com/doi/10.1142/S2010135X24500334 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850094204445786112 |
|---|---|
| author | Inna Andryushina Konstantin Andryushin Ekaterina Glazunova Sidek Khasbulatov Larisa Reznichenko |
| author_facet | Inna Andryushina Konstantin Andryushin Ekaterina Glazunova Sidek Khasbulatov Larisa Reznichenko |
| author_sort | Inna Andryushina |
| collection | DOAJ |
| description | Solid solutions (SS) with a quasi-binary cross-section of a four-component system of the composition [Formula: see text](Na[Formula: see text]K[Formula: see text])NbO3–xPb(Ti[Formula: see text]Zr[Formula: see text])O3, based on compositions with fundamentally different physical responses (Na, K)NbO3 (KNN), Pb(Ti, Zr)O3 (PZT), have been prepared by a two-stage solid-phase synthesis followed by sintering using conventional ceramic technology. The influence of thermal cycling on the dielectric properties of ceramic SS with [Formula: see text] has been studied. It has been shown that thermally induced fatigue does not have a significant effect on the Curie temperature and the diffusing of the phase transition (PT) of SS containing only extreme components. It has been found that when the concentration of PZT in the studied system is varied, the [Formula: see text]/[Formula: see text] dependencies take on a form characteristic of ferroelectrics with a diffuse PT. When the repolarisation cycles are varied, the diffusing parameter and the Curie and Burns temperatures show a wave-like behavior. The observed effects are explained by the interaction of different defect types. A conclusion is drawn on the possible practical applications of the studied SS. |
| format | Article |
| id | doaj-art-ee5d782a4f084a13851342baf89afc11 |
| institution | DOAJ |
| issn | 2010-135X 2010-1368 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | World Scientific Publishing |
| record_format | Article |
| series | Journal of Advanced Dielectrics |
| spelling | doaj-art-ee5d782a4f084a13851342baf89afc112025-08-20T02:41:42ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682025-06-01150310.1142/S2010135X24500334Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZTInna Andryushina0Konstantin Andryushin1Ekaterina Glazunova2Sidek Khasbulatov3Larisa Reznichenko4Research Institute of Physics, Southern Federal University, Stachki Str. 194, Rostov-on-Don, 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki Str. 194, Rostov-on-Don, 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki Str. 194, Rostov-on-Don, 344090, RussiaKh. Ibragimov Complex Institute of the Russian Academy of Sciences (CI RAS), V. Alieva 21a, Grozny, 364906, RussiaResearch Institute of Physics, Southern Federal University, Stachki Str. 194, Rostov-on-Don, 344090, RussiaSolid solutions (SS) with a quasi-binary cross-section of a four-component system of the composition [Formula: see text](Na[Formula: see text]K[Formula: see text])NbO3–xPb(Ti[Formula: see text]Zr[Formula: see text])O3, based on compositions with fundamentally different physical responses (Na, K)NbO3 (KNN), Pb(Ti, Zr)O3 (PZT), have been prepared by a two-stage solid-phase synthesis followed by sintering using conventional ceramic technology. The influence of thermal cycling on the dielectric properties of ceramic SS with [Formula: see text] has been studied. It has been shown that thermally induced fatigue does not have a significant effect on the Curie temperature and the diffusing of the phase transition (PT) of SS containing only extreme components. It has been found that when the concentration of PZT in the studied system is varied, the [Formula: see text]/[Formula: see text] dependencies take on a form characteristic of ferroelectrics with a diffuse PT. When the repolarisation cycles are varied, the diffusing parameter and the Curie and Burns temperatures show a wave-like behavior. The observed effects are explained by the interaction of different defect types. A conclusion is drawn on the possible practical applications of the studied SS.https://www.worldscientific.com/doi/10.1142/S2010135X24500334Solid solutionsPZTKNNthermal cyclingCurie–Weiss temperatureburns temperature |
| spellingShingle | Inna Andryushina Konstantin Andryushin Ekaterina Glazunova Sidek Khasbulatov Larisa Reznichenko Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZT Journal of Advanced Dielectrics Solid solutions PZT KNN thermal cycling Curie–Weiss temperature burns temperature |
| title | Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZT |
| title_full | Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZT |
| title_fullStr | Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZT |
| title_full_unstemmed | Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZT |
| title_short | Phase hardening during cyclic quasi-martensitic transformations in ferroroactive solid solutions of the multicomponent system (Na, K)NbO3-PZT |
| title_sort | phase hardening during cyclic quasi martensitic transformations in ferroroactive solid solutions of the multicomponent system na k nbo3 pzt |
| topic | Solid solutions PZT KNN thermal cycling Curie–Weiss temperature burns temperature |
| url | https://www.worldscientific.com/doi/10.1142/S2010135X24500334 |
| work_keys_str_mv | AT innaandryushina phasehardeningduringcyclicquasimartensitictransformationsinferroroactivesolidsolutionsofthemulticomponentsystemnaknbo3pzt AT konstantinandryushin phasehardeningduringcyclicquasimartensitictransformationsinferroroactivesolidsolutionsofthemulticomponentsystemnaknbo3pzt AT ekaterinaglazunova phasehardeningduringcyclicquasimartensitictransformationsinferroroactivesolidsolutionsofthemulticomponentsystemnaknbo3pzt AT sidekkhasbulatov phasehardeningduringcyclicquasimartensitictransformationsinferroroactivesolidsolutionsofthemulticomponentsystemnaknbo3pzt AT larisareznichenko phasehardeningduringcyclicquasimartensitictransformationsinferroroactivesolidsolutionsofthemulticomponentsystemnaknbo3pzt |