SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATION
On allowing Me4NOH as a methanolic solution or Et4NOH as an ethanolic solution to react with BO3H3 in ethanol, R4NOH∙2B2(OH)4 (R = Me, Et) are obtained and characterized by infrared. The subboric acid B2(OH)4 has been obtained in situ. An infinite chain structure has been suggested on the basis of i...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2014-05-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201304&vol=4&aid=4047 |
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| author | AMINATA DIASSE SARR LIBASSE DIOP |
| author_facet | AMINATA DIASSE SARR LIBASSE DIOP |
| author_sort | AMINATA DIASSE SARR |
| collection | DOAJ |
| description | On allowing Me4NOH as a methanolic solution or Et4NOH as an ethanolic solution to react with BO3H3 in ethanol, R4NOH∙2B2(OH)4 (R = Me, Et) are obtained and characterized by infrared. The subboric acid B2(OH)4 has been obtained in situ. An infinite chain structure has been suggested on the basis of infrared data. When OH.....O hydrogen bonds are considered, supramolecular architectures are obtained. |
| format | Article |
| id | doaj-art-ee582f8777854c50b650604bb4287c4a |
| institution | DOAJ |
| issn | 1582-540X |
| language | English |
| publishDate | 2014-05-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-ee582f8777854c50b650604bb4287c4a2025-08-20T03:09:55ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2014-05-01144263265SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATIONAMINATA DIASSE SARR0LIBASSE DIOP 1Université Cheikh Anta Diop, Faculté des Sciences et Techniques Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, SénégalUniversité Cheikh Anta Diop, Faculté des Sciences et Techniques Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, SénégalOn allowing Me4NOH as a methanolic solution or Et4NOH as an ethanolic solution to react with BO3H3 in ethanol, R4NOH∙2B2(OH)4 (R = Me, Et) are obtained and characterized by infrared. The subboric acid B2(OH)4 has been obtained in situ. An infinite chain structure has been suggested on the basis of infrared data. When OH.....O hydrogen bonds are considered, supramolecular architectures are obtained.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201304&vol=4&aid=4047OH-subboric acidtetrahedral boron |
| spellingShingle | AMINATA DIASSE SARR LIBASSE DIOP SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATION Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry OH- subboric acid tetrahedral boron |
| title | SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATION |
| title_full | SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATION |
| title_fullStr | SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATION |
| title_full_unstemmed | SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATION |
| title_short | SUBBORIC ACID ADDUCTS R4NOH*2B2(OH)4 (R= Me, Et): SYNTHESIS AND INFRARED CHARACTERIZATION |
| title_sort | subboric acid adducts r4noh 2b2 oh 4 r me et synthesis and infrared characterization |
| topic | OH- subboric acid tetrahedral boron |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201304&vol=4&aid=4047 |
| work_keys_str_mv | AT aminatadiassesarr subboricacidadductsr4noh2b2oh4rmeetsynthesisandinfraredcharacterization AT libassediop subboricacidadductsr4noh2b2oh4rmeetsynthesisandinfraredcharacterization |