Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by Polyaniline

Polyaniline was synthesized chemically, coated on sawdust via cast method in the form of emeraldine base (EB) from formic acid as solvent, and used as an adsorbent for removal of lead ion or from aqueous solution. The effects of some important chemical and physical factors in removal efficiency have...

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Main Authors: R. Ansari, F. Raofie
Format: Article
Language:English
Published: Wiley 2006-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2006/378619
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author R. Ansari
F. Raofie
author_facet R. Ansari
F. Raofie
author_sort R. Ansari
collection DOAJ
description Polyaniline was synthesized chemically, coated on sawdust via cast method in the form of emeraldine base (EB) from formic acid as solvent, and used as an adsorbent for removal of lead ion or from aqueous solution. The effects of some important chemical and physical factors in removal efficiency have also been investigated. Among the different parameters, the effect of pH was the most prominent. It was found that metal uptake is occurred under neutral or slightly alkaline conditions, while under relatively strong acidic media, the sorption of the investigated metal ions was negligible and desorption is a predominant process. It was found that undoped PANi (EB form) coated on polar substrates such as sawdust (SD) can be used as an effective adsorbent for removal of heavy metal ions in water and wastewater treatments. All the previous investigations and applications take advantage of the electrical conductivity (metallic), electrochemical (redox activity) and electrochromic properties of the polyaniline. While; in this research, we have taken advantage of the chelating properties of PANi for metal sorption.
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spelling doaj-art-ee3ebee095c848ae82b91033f7a3354d2025-02-03T05:51:23ZengWileyE-Journal of Chemistry0973-49452090-98102006-01-0131495910.1155/2006/378619Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by PolyanilineR. Ansari0F. Raofie1Chemistry Department, Guilan University, Rasht, POB: 41335-1914, IranChemistry Department, Guilan University, Rasht, POB: 41335-1914, IranPolyaniline was synthesized chemically, coated on sawdust via cast method in the form of emeraldine base (EB) from formic acid as solvent, and used as an adsorbent for removal of lead ion or from aqueous solution. The effects of some important chemical and physical factors in removal efficiency have also been investigated. Among the different parameters, the effect of pH was the most prominent. It was found that metal uptake is occurred under neutral or slightly alkaline conditions, while under relatively strong acidic media, the sorption of the investigated metal ions was negligible and desorption is a predominant process. It was found that undoped PANi (EB form) coated on polar substrates such as sawdust (SD) can be used as an effective adsorbent for removal of heavy metal ions in water and wastewater treatments. All the previous investigations and applications take advantage of the electrical conductivity (metallic), electrochemical (redox activity) and electrochromic properties of the polyaniline. While; in this research, we have taken advantage of the chelating properties of PANi for metal sorption.http://dx.doi.org/10.1155/2006/378619
spellingShingle R. Ansari
F. Raofie
Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by Polyaniline
E-Journal of Chemistry
title Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by Polyaniline
title_full Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by Polyaniline
title_fullStr Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by Polyaniline
title_full_unstemmed Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by Polyaniline
title_short Removal of Lead Ion from Aqueous Solutions Using Sawdust Coated by Polyaniline
title_sort removal of lead ion from aqueous solutions using sawdust coated by polyaniline
url http://dx.doi.org/10.1155/2006/378619
work_keys_str_mv AT ransari removalofleadionfromaqueoussolutionsusingsawdustcoatedbypolyaniline
AT fraofie removalofleadionfromaqueoussolutionsusingsawdustcoatedbypolyaniline