Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide

Coordination polymers containing a novel bis(oxine) bidentate ligand, namely 4,4'-[(8-Quinolinolyl-5-methylenoxy) diphenyl sulfide H2L have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chlorome...

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Main Authors: K. D. Patel, S. C. Panchani
Format: Article
Language:English
Published: Wiley 2004-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2004/250809
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author K. D. Patel
S. C. Panchani
author_facet K. D. Patel
S. C. Panchani
author_sort K. D. Patel
collection DOAJ
description Coordination polymers containing a novel bis(oxine) bidentate ligand, namely 4,4'-[(8-Quinolinolyl-5-methylenoxy) diphenyl sulfide H2L have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chloromethyl-8-hydroxyquinoline hydrochloride with 4,4'-dihydroxy diphenyl sulfide in the presence of a base catalyst. All of these coordination polymers and the parent ligand were characterized by elemental analyses, and IR spectral and diffuse reflectance spectral studies. The thermal stability and number-average molecular weights (Mn) of all of the coordination polymers were determined by thermogravimetric analyses and non-aqueous conductometric titrations, respectively. In addition, all of the coordination polymers have been characterized by their magnetic susceptibilities
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spelling doaj-art-ee15e2a21aff48d8a0a3699f0102a3be2025-08-20T03:20:44ZengWileyE-Journal of Chemistry0973-49452090-98102004-01-011315816310.1155/2004/250809Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl SulfideK. D. Patel0S. C. Panchani1V.P. & R.P.T.P. Vithalbhai Patel & Rajrant Pursottambhai Tulsibhai Patel Science College, Vallabh Vidyanagar – 388120, IndiaV.P. & R.P.T.P. Vithalbhai Patel & Rajrant Pursottambhai Tulsibhai Patel Science College, Vallabh Vidyanagar – 388120, IndiaCoordination polymers containing a novel bis(oxine) bidentate ligand, namely 4,4'-[(8-Quinolinolyl-5-methylenoxy) diphenyl sulfide H2L have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chloromethyl-8-hydroxyquinoline hydrochloride with 4,4'-dihydroxy diphenyl sulfide in the presence of a base catalyst. All of these coordination polymers and the parent ligand were characterized by elemental analyses, and IR spectral and diffuse reflectance spectral studies. The thermal stability and number-average molecular weights (Mn) of all of the coordination polymers were determined by thermogravimetric analyses and non-aqueous conductometric titrations, respectively. In addition, all of the coordination polymers have been characterized by their magnetic susceptibilitieshttp://dx.doi.org/10.1155/2004/250809
spellingShingle K. D. Patel
S. C. Panchani
Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide
E-Journal of Chemistry
title Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide
title_full Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide
title_fullStr Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide
title_full_unstemmed Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide
title_short Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide
title_sort coordination polymers of 4 4 8 quinolinolyl 5 methylenoxy diphenyl sulfide
url http://dx.doi.org/10.1155/2004/250809
work_keys_str_mv AT kdpatel coordinationpolymersof448quinolinolyl5methylenoxydiphenylsulfide
AT scpanchani coordinationpolymersof448quinolinolyl5methylenoxydiphenylsulfide