Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide
Coordination polymers containing a novel bis(oxine) bidentate ligand, namely 4,4'-[(8-Quinolinolyl-5-methylenoxy) diphenyl sulfide H2L have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chlorome...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2004-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2004/250809 |
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| Summary: | Coordination polymers containing a novel bis(oxine) bidentate ligand, namely 4,4'-[(8-Quinolinolyl-5-methylenoxy) diphenyl sulfide H2L have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chloromethyl-8-hydroxyquinoline hydrochloride with 4,4'-dihydroxy diphenyl sulfide in the presence of a base catalyst. All of these coordination polymers and the parent ligand were characterized by elemental analyses, and IR spectral and diffuse reflectance spectral studies. The thermal stability and number-average molecular weights (Mn) of all of the coordination polymers were determined by thermogravimetric analyses and non-aqueous conductometric titrations, respectively. In addition, all of the coordination polymers have been characterized by their magnetic susceptibilities |
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| ISSN: | 0973-4945 2090-9810 |