SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND
A novel 1D chained Na(I) coordination polymer materials has been obtained by reaction of 2-hydrazinobenzoic acid with 2-formyl-benzenesulfonic acid sodium salt in CH3CH2OH/H2O. It was characterized X-ray single crystal diffraction analysis. The crystal of the Na(I) coordination polymer belongs to tr...
Saved in:
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2015-02-01
|
| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201404&vol=4&aid=4173 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850274558932680704 |
|---|---|
| author | LI-HUA WANG |
| author_facet | LI-HUA WANG |
| author_sort | LI-HUA WANG |
| collection | DOAJ |
| description | A novel 1D chained Na(I) coordination polymer materials has been obtained by reaction of 2-hydrazinobenzoic acid with 2-formyl-benzenesulfonic acid sodium salt in CH3CH2OH/H2O. It was characterized X-ray single crystal diffraction analysis. The crystal of the Na(I) coordination polymer belongs to triclinic, space group P-1 with a = 6.0354(12) Å, b = 8.1922(16) Å, c = 18.729(4) Å, α = 93.70(3)º, β = 95.68(3)º, γ = 97.03(3)º, V = 911.8(3) Å3, Z = 2, Dc = 1.444 μg·m-3, μ= 0.245 mm-1, F(000)= 412, and final R1 = 0.0833, ωR2 = 0.2867. X-ray analysis reveals that each Na(I) center is six-coordination with a O6 distorted octahedron coordination environment. The Na(I) ions are linked through the O atoms of sodium 2-{(E)-[2-(2-carboxyphenyl) hydrazinylidene]methyl}benzenesulfonate to form 1D chain coordination polymer. |
| format | Article |
| id | doaj-art-ee02e2cc5afe406b8d898a578ef1d719 |
| institution | OA Journals |
| issn | 1582-540X 1582-540X |
| language | English |
| publishDate | 2015-02-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-ee02e2cc5afe406b8d898a578ef1d7192025-08-20T01:51:06ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2015-02-01154313319SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGANDLI-HUA WANG0College of Information and Engineering, Weifang University, Weifang 261061, P. R. China A novel 1D chained Na(I) coordination polymer materials has been obtained by reaction of 2-hydrazinobenzoic acid with 2-formyl-benzenesulfonic acid sodium salt in CH3CH2OH/H2O. It was characterized X-ray single crystal diffraction analysis. The crystal of the Na(I) coordination polymer belongs to triclinic, space group P-1 with a = 6.0354(12) Å, b = 8.1922(16) Å, c = 18.729(4) Å, α = 93.70(3)º, β = 95.68(3)º, γ = 97.03(3)º, V = 911.8(3) Å3, Z = 2, Dc = 1.444 μg·m-3, μ= 0.245 mm-1, F(000)= 412, and final R1 = 0.0833, ωR2 = 0.2867. X-ray analysis reveals that each Na(I) center is six-coordination with a O6 distorted octahedron coordination environment. The Na(I) ions are linked through the O atoms of sodium 2-{(E)-[2-(2-carboxyphenyl) hydrazinylidene]methyl}benzenesulfonate to form 1D chain coordination polymer.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201404&vol=4&aid=4173sodium 2-{(E)-[2-(2-carboxyphenyl)hydrazinylidene] methyl}benzenesulfonateNa(I) coordination polymerstructural characterizationsynthesis |
| spellingShingle | LI-HUA WANG SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry sodium 2-{(E)-[2-(2-carboxyphenyl)hydrazinylidene] methyl}benzenesulfonate Na(I) coordination polymer structural characterization synthesis |
| title | SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND |
| title_full | SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND |
| title_fullStr | SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND |
| title_full_unstemmed | SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND |
| title_short | SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND |
| title_sort | synthesis crystal structure of a novel 1d chained na i coordination polymer materials based on schiff base ligand |
| topic | sodium 2-{(E)-[2-(2-carboxyphenyl)hydrazinylidene] methyl}benzenesulfonate Na(I) coordination polymer structural characterization synthesis |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201404&vol=4&aid=4173 |
| work_keys_str_mv | AT lihuawang synthesiscrystalstructureofanovel1dchainednaicoordinationpolymermaterialsbasedonschiffbaseligand |