Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration

Inspired by the initial mineralization process with bone matrix vesicles (MVs), this study innovatively developed a delivery system to mediate mineralization during bone regeneration. The system comprises nanofibrous chitosan microspheres (NCM) and poly (allylamine hydrochloride)-stabilized amorphou...

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Main Authors: Haolin Bian, Fangfang Song, Shilei Wang, Wei Sun, Bo Hu, Xichao Liang, Hongye Yang, Cui Huang
Format: Article
Language:English
Published: Elsevier 2025-02-01
Series:Materials Today Bio
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590006425000067
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author Haolin Bian
Fangfang Song
Shilei Wang
Wei Sun
Bo Hu
Xichao Liang
Hongye Yang
Cui Huang
author_facet Haolin Bian
Fangfang Song
Shilei Wang
Wei Sun
Bo Hu
Xichao Liang
Hongye Yang
Cui Huang
author_sort Haolin Bian
collection DOAJ
description Inspired by the initial mineralization process with bone matrix vesicles (MVs), this study innovatively developed a delivery system to mediate mineralization during bone regeneration. The system comprises nanofibrous chitosan microspheres (NCM) and poly (allylamine hydrochloride)-stabilized amorphous calcium phosphate (PAH-ACP), which is thereafter referred to as NCMP. NCM is synthesized through the thermal induction of chitosan molecular chains, serving as the carrier, while PAH-ACP functions as the mineralization precursor. Additionally, the nanofibrous network of NCMP mimics the architecture of natural extracellular matrix (ECM), creating an optimal niche for the active adhesion of stem cells to its surface, exhibiting good biocompatibility, immunoregulation, and osteogenic performance. In vivo, NCMP effectively recruits cells and mineralizes collagen, modulates cell behavior and differentiation, and promotes in situ biomineralization in rat calvarial defects. These results underscore the dual efficacy of NCMP not only as an effective delivery system for mineralization precursors but also as ECM-mimicking bio-blocks, offering a promising avenue for enhancing the repair and regeneration of bone defects.
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publishDate 2025-02-01
publisher Elsevier
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spelling doaj-art-edba6bc1b5e54d7d8d80a32bba3ffe0a2025-08-20T03:01:03ZengElsevierMaterials Today Bio2590-00642025-02-013010144810.1016/j.mtbio.2025.101448Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regenerationHaolin Bian0Fangfang Song1Shilei Wang2Wei Sun3Bo Hu4Xichao Liang5Hongye Yang6Cui Huang7State Key Laboratory of Oral & Maxillofacial Reconstruction and Regeneration, Key Laboratory of Oral Biomedicine Ministry of Education, Hubei Key Laboratory of Stomatology, School & Hospital of Stomatology, Wuhan University, Wuhan, 430079, China; Department of Stomatology, The First Affiliated Hospital, College of Medicine, Zhejiang University, Hangzhou, 310003, ChinaState Key Laboratory of Oral & Maxillofacial Reconstruction and Regeneration, Key Laboratory of Oral Biomedicine Ministry of Education, Hubei Key Laboratory of Stomatology, School & Hospital of Stomatology, Wuhan University, Wuhan, 430079, ChinaKey Laboratory of Resources and Compound of Traditional Chinese Medicine, Ministry of Education, Hubei University of Traditional Chinese Medicine, Wuhan, 430065, ChinaState Key Laboratory of Oral & Maxillofacial Reconstruction and Regeneration, Key Laboratory of Oral Biomedicine Ministry of Education, Hubei Key Laboratory of Stomatology, School & Hospital of Stomatology, Wuhan University, Wuhan, 430079, ChinaResearch and Application of Regenerative Cellulose Fiber Key Laboratory of Sichuan Province, YiBin Grace Group Co., LTD, Yibin, 644000, ChinaResearch and Application of Regenerative Cellulose Fiber Key Laboratory of Sichuan Province, YiBin Grace Group Co., LTD, Yibin, 644000, ChinaState Key Laboratory of Oral & Maxillofacial Reconstruction and Regeneration, Key Laboratory of Oral Biomedicine Ministry of Education, Hubei Key Laboratory of Stomatology, School & Hospital of Stomatology, Wuhan University, Wuhan, 430079, China; Corresponding author.State Key Laboratory of Oral & Maxillofacial Reconstruction and Regeneration, Key Laboratory of Oral Biomedicine Ministry of Education, Hubei Key Laboratory of Stomatology, School & Hospital of Stomatology, Wuhan University, Wuhan, 430079, China; Corresponding author.Inspired by the initial mineralization process with bone matrix vesicles (MVs), this study innovatively developed a delivery system to mediate mineralization during bone regeneration. The system comprises nanofibrous chitosan microspheres (NCM) and poly (allylamine hydrochloride)-stabilized amorphous calcium phosphate (PAH-ACP), which is thereafter referred to as NCMP. NCM is synthesized through the thermal induction of chitosan molecular chains, serving as the carrier, while PAH-ACP functions as the mineralization precursor. Additionally, the nanofibrous network of NCMP mimics the architecture of natural extracellular matrix (ECM), creating an optimal niche for the active adhesion of stem cells to its surface, exhibiting good biocompatibility, immunoregulation, and osteogenic performance. In vivo, NCMP effectively recruits cells and mineralizes collagen, modulates cell behavior and differentiation, and promotes in situ biomineralization in rat calvarial defects. These results underscore the dual efficacy of NCMP not only as an effective delivery system for mineralization precursors but also as ECM-mimicking bio-blocks, offering a promising avenue for enhancing the repair and regeneration of bone defects.http://www.sciencedirect.com/science/article/pii/S2590006425000067Nanofibrous chitosan microsphereMatrix vesiclesAmorphous calcium phosphateCollagen mineralizationOsteogenesisTissue engineering
spellingShingle Haolin Bian
Fangfang Song
Shilei Wang
Wei Sun
Bo Hu
Xichao Liang
Hongye Yang
Cui Huang
Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration
Materials Today Bio
Nanofibrous chitosan microsphere
Matrix vesicles
Amorphous calcium phosphate
Collagen mineralization
Osteogenesis
Tissue engineering
title Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration
title_full Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration
title_fullStr Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration
title_full_unstemmed Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration
title_short Matrix vesicle-inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration
title_sort matrix vesicle inspired delivery system based on nanofibrous chitosan microspheres for enhanced bone regeneration
topic Nanofibrous chitosan microsphere
Matrix vesicles
Amorphous calcium phosphate
Collagen mineralization
Osteogenesis
Tissue engineering
url http://www.sciencedirect.com/science/article/pii/S2590006425000067
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