Procédé pour le contrôle du pH lors de la séparation des terres rares par chromatographie sur échangeurs d’ions
(NH4)3H-EDTA-solutions of relatively high concentration can be used for the separation of the rare earths by complex-elution on ion-exchangers. The available acidity of the elutriant is determined acidimetrically in the présence of zinc sulfate; calculated amounts of HCOONH4 or CH3COONH4 are added...
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1958-06-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/7908 |
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| Summary: | (NH4)3H-EDTA-solutions of relatively high concentration can be used for the separation of the rare earths by complex-elution on ion-exchangers. The available acidity of the elutriant is determined acidimetrically in the présence of zinc sulfate; calculated amounts of HCOONH4 or CH3COONH4 are added to convert the hydrogen ion liberated by the exchange reaction to the corresponding acids and to buffer the resulting solution to pH ~ 3 (for the separation of the yttrium group) or ~ 4 (for the cerium group).
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| ISSN: | 0009-4293 2673-2424 |