The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic properties
The nanocomposites based on TiO2 doped with sulfur (S/TiO2), carbon (C/TiO2), carbon and sulfur (S/C/TiO2) have been obtained. The powders were characterized by XRD, XPS, BET, SEM, EDX, TEM and UV-VIS spectroscopy. EDX and XPS spectroscopies prove that titanium dioxide powder includes only Ti and O...
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Chuiko Institute of Surface Chemistry of NAS of Ukraine
2019-11-01
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| Series: | Хімія, фізика та технологія поверхні |
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| Online Access: | https://cpts.com.ua/index.php/cpts/article/view/522 |
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| author | M. V. Shapovalova T. A. Khalyavka O. Y. Khyzhun N. D. Shcherban V. V. Permyakov S. N. Scherbakov |
| author_facet | M. V. Shapovalova T. A. Khalyavka O. Y. Khyzhun N. D. Shcherban V. V. Permyakov S. N. Scherbakov |
| author_sort | M. V. Shapovalova |
| collection | DOAJ |
| description |
The nanocomposites based on TiO2 doped with sulfur (S/TiO2), carbon (C/TiO2), carbon and sulfur (S/C/TiO2) have been obtained. The powders were characterized by XRD, XPS, BET, SEM, EDX, TEM and UV-VIS spectroscopy. EDX and XPS spectroscopies prove that titanium dioxide powder includes only Ti and O elements, composites C/TiO2 include the elements Ti, O, C, composites S/TiO2 - Ti, O, S and composites C/S/TiO2 - Ti, O, C, and S.
XRD analysis revealed phase of anatase in all composites, rutile phase appeared with increasing of sulfur amount in sulfur-containing powders. It has been found that composites consist of roundish agglomerates in the range of 5–30 mm. Sulfur additives decrease grain growth of titanium dioxide particles from 14 to 9–10 nm in S/TiO2 composites, carbon leads to increase in particle size from 14 to 19 nm, simultaneous modification of titanium dioxide by carbon and sulfur leads to the formation of particles with sizes of 7–8 nm.
Analysis of nitrogen sorption–desorption isotherms for all synthesized samples has shown the presence of a hysteresis loop which is the evidence for mesoporous structure of the powders. The isotherms correspond to type IV of IUPAC classification for mesoporous materials with H1 type for C/TiO2 and H2 type for S/TiO2, and C/S/TiO2 of hysteresis loop. The modification of TiO2 by carbon and sulfur leads to increase of specific surface area (of about 1.8 times in the case of C/TiO2, about 3.3 times for S/TiO2 and about 4.7 times for C/S/TiO2), average pore volume and decrease of radius pore volume compared with TiO2.
Absorption spectra of nanocomposites showed a bathochromic shift as compared with the absorption band of pure TiO2. It has been found that modification leads to band gap narrowing. Nanocomposite samples showed higher photocatalytic activity in the destruction of safranine T under UV and visible irradiation compared to pure TiO2. It may be related to the participation of dopants in the inhibition of electron-hole recombination, prolongation of charges lifetime, increasing efficiency of interfacial charge separation and formation of doping electronic states.
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| format | Article |
| id | doaj-art-ed674cb37b40482b95cc892d698ec185 |
| institution | Kabale University |
| issn | 2079-1704 2518-1238 |
| language | English |
| publishDate | 2019-11-01 |
| publisher | Chuiko Institute of Surface Chemistry of NAS of Ukraine |
| record_format | Article |
| series | Хімія, фізика та технологія поверхні |
| spelling | doaj-art-ed674cb37b40482b95cc892d698ec1852025-08-20T03:51:53ZengChuiko Institute of Surface Chemistry of NAS of UkraineХімія, фізика та технологія поверхні2079-17042518-12382019-11-0110410.15407/hftp10.04.377The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic propertiesM. V. Shapovalova0T. A. Khalyavka1O. Y. Khyzhun2N. D. Shcherban3V. V. Permyakov4S. N. Scherbakov5Institute for Sorption and Problems of Endoecology of National Academy of Sciences of UkraineInstitute for Sorption and Problems of Endoecology of National Academy of Sciences of UkraineFrantsevich Institute for Problems of Materials Science of National Academy of Sciences of UkraineL.V. Pisarzhevskii Institute of Physical Chemistry of National Academy of Sciences of UkraineInstitute of Geological Sciences of National Academy of Sciences of UkraineM.G. Kholodny Institute of Botany of National Academy of Sciences of Ukraine The nanocomposites based on TiO2 doped with sulfur (S/TiO2), carbon (C/TiO2), carbon and sulfur (S/C/TiO2) have been obtained. The powders were characterized by XRD, XPS, BET, SEM, EDX, TEM and UV-VIS spectroscopy. EDX and XPS spectroscopies prove that titanium dioxide powder includes only Ti and O elements, composites C/TiO2 include the elements Ti, O, C, composites S/TiO2 - Ti, O, S and composites C/S/TiO2 - Ti, O, C, and S. XRD analysis revealed phase of anatase in all composites, rutile phase appeared with increasing of sulfur amount in sulfur-containing powders. It has been found that composites consist of roundish agglomerates in the range of 5–30 mm. Sulfur additives decrease grain growth of titanium dioxide particles from 14 to 9–10 nm in S/TiO2 composites, carbon leads to increase in particle size from 14 to 19 nm, simultaneous modification of titanium dioxide by carbon and sulfur leads to the formation of particles with sizes of 7–8 nm. Analysis of nitrogen sorption–desorption isotherms for all synthesized samples has shown the presence of a hysteresis loop which is the evidence for mesoporous structure of the powders. The isotherms correspond to type IV of IUPAC classification for mesoporous materials with H1 type for C/TiO2 and H2 type for S/TiO2, and C/S/TiO2 of hysteresis loop. The modification of TiO2 by carbon and sulfur leads to increase of specific surface area (of about 1.8 times in the case of C/TiO2, about 3.3 times for S/TiO2 and about 4.7 times for C/S/TiO2), average pore volume and decrease of radius pore volume compared with TiO2. Absorption spectra of nanocomposites showed a bathochromic shift as compared with the absorption band of pure TiO2. It has been found that modification leads to band gap narrowing. Nanocomposite samples showed higher photocatalytic activity in the destruction of safranine T under UV and visible irradiation compared to pure TiO2. It may be related to the participation of dopants in the inhibition of electron-hole recombination, prolongation of charges lifetime, increasing efficiency of interfacial charge separation and formation of doping electronic states. https://cpts.com.ua/index.php/cpts/article/view/522nanocompositestitanium dioxidecarbonsulfursafranine Tphotocatalytic activity |
| spellingShingle | M. V. Shapovalova T. A. Khalyavka O. Y. Khyzhun N. D. Shcherban V. V. Permyakov S. N. Scherbakov The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic properties Хімія, фізика та технологія поверхні nanocomposites titanium dioxide carbon sulfur safranine T photocatalytic activity |
| title | The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic properties |
| title_full | The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic properties |
| title_fullStr | The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic properties |
| title_full_unstemmed | The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic properties |
| title_short | The influence of titanium dioxide modification by sulfur and carbon on physico-chemical and photocatalytic properties |
| title_sort | influence of titanium dioxide modification by sulfur and carbon on physico chemical and photocatalytic properties |
| topic | nanocomposites titanium dioxide carbon sulfur safranine T photocatalytic activity |
| url | https://cpts.com.ua/index.php/cpts/article/view/522 |
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