Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impacts

Bleached eucalyptus kraft (BEK) pulp dominates global pulp production, yet the environmental impacts of its bleaching sequences in Brazil are not fully explored. Addressing this gap, we conducted a comparative life cycle assessment (LCA) of three bleaching sequences: conventional elemental chlorine-...

Full description

Saved in:
Bibliographic Details
Main Authors: Rhonald Ortega, Naycari Forfora, Isabel Urdaneta, Ivana Azuaje, Keren A. Vivas, Ramon E. Vera, Jorge Franco, Ryen Frazier, Camilla Abbati, Daniel Saloni, Hasan Jameel, Richard Venditti, Ronalds Gonzalez
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Cleaner Environmental Systems
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666789424000722
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850054344472264704
author Rhonald Ortega
Naycari Forfora
Isabel Urdaneta
Ivana Azuaje
Keren A. Vivas
Ramon E. Vera
Jorge Franco
Ryen Frazier
Camilla Abbati
Daniel Saloni
Hasan Jameel
Richard Venditti
Ronalds Gonzalez
author_facet Rhonald Ortega
Naycari Forfora
Isabel Urdaneta
Ivana Azuaje
Keren A. Vivas
Ramon E. Vera
Jorge Franco
Ryen Frazier
Camilla Abbati
Daniel Saloni
Hasan Jameel
Richard Venditti
Ronalds Gonzalez
author_sort Rhonald Ortega
collection DOAJ
description Bleached eucalyptus kraft (BEK) pulp dominates global pulp production, yet the environmental impacts of its bleaching sequences in Brazil are not fully explored. Addressing this gap, we conducted a comparative life cycle assessment (LCA) of three bleaching sequences: conventional elemental chlorine-free (ECF), ECF with oxygen delignification, and ECF with oxygen delignification plus acid washing. We estimated the average global warming potential (GWP) for BEK delivered to the U.S. and examined how forest carbon cycle (FCC) elements, specifically biogenic GWP (GWPbio) and potential soil organic carbon (SOC) sequestration, influence GWP outcomes. Results show that the ECF sequence with oxygen delignification and acid washing reduces GWP by 11% and outperforms conventional ECF in 10 out of 11 environmental impact categories. The average GWP for Brazilian BEK delivered to the U.S. is 576 kg CO₂-eq/ton. Sensitivity analyses demonstrate that adding GWPbio increases GWP by 18%, whereas accounting for potential SOC sequestration reduces it by 39%. These findings highlight the necessity of optimizing bleaching processes and developing a standardized BEK LCA model for comparing the environmental impact of different fibers. This work sets a precedent for integrating FCC elements into LCAs and underscores the potential of SOC sequestration in mitigating climate change impacts.
format Article
id doaj-art-ed1ae2a5bcfb464a89aff6f63ed8a978
institution DOAJ
issn 2666-7894
language English
publishDate 2024-12-01
publisher Elsevier
record_format Article
series Cleaner Environmental Systems
spelling doaj-art-ed1ae2a5bcfb464a89aff6f63ed8a9782025-08-20T02:52:17ZengElsevierCleaner Environmental Systems2666-78942024-12-011510023410.1016/j.cesys.2024.100234Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impactsRhonald Ortega0Naycari Forfora1Isabel Urdaneta2Ivana Azuaje3Keren A. Vivas4Ramon E. Vera5Jorge Franco6Ryen Frazier7Camilla Abbati8Daniel Saloni9Hasan Jameel10Richard Venditti11Ronalds Gonzalez12Sustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USADepartment of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USASustainable and Alternative Fibers Initiative, Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695-8005, USA; Corresponding author.Bleached eucalyptus kraft (BEK) pulp dominates global pulp production, yet the environmental impacts of its bleaching sequences in Brazil are not fully explored. Addressing this gap, we conducted a comparative life cycle assessment (LCA) of three bleaching sequences: conventional elemental chlorine-free (ECF), ECF with oxygen delignification, and ECF with oxygen delignification plus acid washing. We estimated the average global warming potential (GWP) for BEK delivered to the U.S. and examined how forest carbon cycle (FCC) elements, specifically biogenic GWP (GWPbio) and potential soil organic carbon (SOC) sequestration, influence GWP outcomes. Results show that the ECF sequence with oxygen delignification and acid washing reduces GWP by 11% and outperforms conventional ECF in 10 out of 11 environmental impact categories. The average GWP for Brazilian BEK delivered to the U.S. is 576 kg CO₂-eq/ton. Sensitivity analyses demonstrate that adding GWPbio increases GWP by 18%, whereas accounting for potential SOC sequestration reduces it by 39%. These findings highlight the necessity of optimizing bleaching processes and developing a standardized BEK LCA model for comparing the environmental impact of different fibers. This work sets a precedent for integrating FCC elements into LCAs and underscores the potential of SOC sequestration in mitigating climate change impacts.http://www.sciencedirect.com/science/article/pii/S2666789424000722Oxygen delignificationAcid washingAquatic ecosystemForest carbon dynamicsSoil carbon sequestrationClimate change mitigation
spellingShingle Rhonald Ortega
Naycari Forfora
Isabel Urdaneta
Ivana Azuaje
Keren A. Vivas
Ramon E. Vera
Jorge Franco
Ryen Frazier
Camilla Abbati
Daniel Saloni
Hasan Jameel
Richard Venditti
Ronalds Gonzalez
Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impacts
Cleaner Environmental Systems
Oxygen delignification
Acid washing
Aquatic ecosystem
Forest carbon dynamics
Soil carbon sequestration
Climate change mitigation
title Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impacts
title_full Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impacts
title_fullStr Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impacts
title_full_unstemmed Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impacts
title_short Life cycle assessment of Brazilian bleached eucalyptus kraft pulp: Integrating bleaching processes and biogenic carbon impacts
title_sort life cycle assessment of brazilian bleached eucalyptus kraft pulp integrating bleaching processes and biogenic carbon impacts
topic Oxygen delignification
Acid washing
Aquatic ecosystem
Forest carbon dynamics
Soil carbon sequestration
Climate change mitigation
url http://www.sciencedirect.com/science/article/pii/S2666789424000722
work_keys_str_mv AT rhonaldortega lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT naycariforfora lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT isabelurdaneta lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT ivanaazuaje lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT kerenavivas lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT ramonevera lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT jorgefranco lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT ryenfrazier lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT camillaabbati lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT danielsaloni lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT hasanjameel lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT richardvenditti lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts
AT ronaldsgonzalez lifecycleassessmentofbrazilianbleachedeucalyptuskraftpulpintegratingbleachingprocessesandbiogeniccarbonimpacts