Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion Cells

Lithium-Ion batteries, so far represent the technology that best fits the needs of electric mobility, due to a number of advantages with respect to other alternative solutions, such as higher energy and power densities and longer cycle life. However, there are safety concerns that still hinder their...

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Main Authors: Carla Menale, Roberto Bubbico
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2025-06-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/15156
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author Carla Menale
Roberto Bubbico
author_facet Carla Menale
Roberto Bubbico
author_sort Carla Menale
collection DOAJ
description Lithium-Ion batteries, so far represent the technology that best fits the needs of electric mobility, due to a number of advantages with respect to other alternative solutions, such as higher energy and power densities and longer cycle life. However, there are safety concerns that still hinder their adoption in a wider range of applications: in the absence of efficient temperature control, at high operating temperatures a thermal runaway can occur, with possible destruction of the cell itself and the generation of other dangerous phenomena (fires and explosions). This problem is particularly important when a large number of cells are connected together in a whole pack, where the failure of a single cell can impact additional cells in its proximity with the possible generation of even more catastrophic consequences. In the present study, 3D simulations have been carried out to assess the cooling efficiency of an air flow, under various operating conditions, on several cylindrical Li-ion cells, characterized by different cathode compositions. Under the investigated configurations, it was found that, beyond a minimum value of the passing air velocity, it is possible to prevent a generalized thermal runaway keeping the cells within safe temperature conditions; however, the cathode material also plays a significant role, with some configurations showing a safer behaviour with respect to others, characterized by a more pronounced susceptibility to thermal instability.
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institution Kabale University
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publishDate 2025-06-01
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spelling doaj-art-ec7ec9a9f6174aeebc0d7cec69f80e2a2025-08-20T03:30:04ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162025-06-01116Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion CellsCarla MenaleRoberto BubbicoLithium-Ion batteries, so far represent the technology that best fits the needs of electric mobility, due to a number of advantages with respect to other alternative solutions, such as higher energy and power densities and longer cycle life. However, there are safety concerns that still hinder their adoption in a wider range of applications: in the absence of efficient temperature control, at high operating temperatures a thermal runaway can occur, with possible destruction of the cell itself and the generation of other dangerous phenomena (fires and explosions). This problem is particularly important when a large number of cells are connected together in a whole pack, where the failure of a single cell can impact additional cells in its proximity with the possible generation of even more catastrophic consequences. In the present study, 3D simulations have been carried out to assess the cooling efficiency of an air flow, under various operating conditions, on several cylindrical Li-ion cells, characterized by different cathode compositions. Under the investigated configurations, it was found that, beyond a minimum value of the passing air velocity, it is possible to prevent a generalized thermal runaway keeping the cells within safe temperature conditions; however, the cathode material also plays a significant role, with some configurations showing a safer behaviour with respect to others, characterized by a more pronounced susceptibility to thermal instability.https://www.cetjournal.it/index.php/cet/article/view/15156
spellingShingle Carla Menale
Roberto Bubbico
Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion Cells
Chemical Engineering Transactions
title Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion Cells
title_full Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion Cells
title_fullStr Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion Cells
title_full_unstemmed Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion Cells
title_short Influence of Cathode Composition on Air-cooling Efficiency of Lithium-ion Cells
title_sort influence of cathode composition on air cooling efficiency of lithium ion cells
url https://www.cetjournal.it/index.php/cet/article/view/15156
work_keys_str_mv AT carlamenale influenceofcathodecompositiononaircoolingefficiencyoflithiumioncells
AT robertobubbico influenceofcathodecompositiononaircoolingefficiencyoflithiumioncells