Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose
The inorganic polymers containing transition metals such as Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) were synthesized by using succinoyl carboxymethyl cellulose (SCMC) in aqueous media. The newly synthesized polymers were characterized by elemental analysis, IR spectroscopy, TG analysis, UV reflect...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2011-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/369492 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832547539560169472 |
|---|---|
| author | H. D. Juneja Manisha Joshi N. T. KhatiI |
| author_facet | H. D. Juneja Manisha Joshi N. T. KhatiI |
| author_sort | H. D. Juneja |
| collection | DOAJ |
| description | The inorganic polymers containing transition metals such as Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) were synthesized by using succinoyl carboxymethyl cellulose (SCMC) in aqueous media. The newly synthesized polymers were characterized by elemental analysis, IR spectroscopy, TG analysis, UV reflectance spectra and magnetic moment. On the basis of these studies, the composition of the polymeric unit was found to be [M(II)L]n, [Mʼ(II)L.2H2 O]n, {[Mˮ(II)L.2H2O]n H2O}, where M= Zn(II), Mʼ = Mn(II), Ni(II) and Cu(II) and Mˮ = Co(II), L = SCMC ligand. On the basis of instrumental techniques, it has been found that the [Zn(II)(SCMC)]n inorganic polymer has tetrahedral geometry, whereas {[Cu(II)(SCMC)].2H2O}n has square planar geometry and [Mn(II)(SCMC).2H2O]n, {[Co(II)(SCMC).2H2O)].H2O}n and [Ni(II) (SCMC).2H2O]n have octahedral geometry. The decomposition temperatures of the inorganic polymers have been determined by TGA. The TGA reveal that the Mn(II) polymer of SCMC is highly thermally stable than rest of the polymers and these polymers can be used as thermal resisting materials. |
| format | Article |
| id | doaj-art-ec152fd87dae4ca7a6b0fb9291b69ec7 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-ec152fd87dae4ca7a6b0fb9291b69ec72025-02-03T06:44:30ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01841993199910.1155/2011/369492Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl CelluloseH. D. Juneja0Manisha Joshi1N. T. KhatiI2Department of Chemistry, R T M Nagpur University, Nagpur-440033, IndiaDepartment of Chemistry, Priyadarshini College of Engineering, Nagpur-440019, IndiaDepartment of Chemistry, Priyadarshini College of Engineering, Nagpur-440019, IndiaThe inorganic polymers containing transition metals such as Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) were synthesized by using succinoyl carboxymethyl cellulose (SCMC) in aqueous media. The newly synthesized polymers were characterized by elemental analysis, IR spectroscopy, TG analysis, UV reflectance spectra and magnetic moment. On the basis of these studies, the composition of the polymeric unit was found to be [M(II)L]n, [Mʼ(II)L.2H2 O]n, {[Mˮ(II)L.2H2O]n H2O}, where M= Zn(II), Mʼ = Mn(II), Ni(II) and Cu(II) and Mˮ = Co(II), L = SCMC ligand. On the basis of instrumental techniques, it has been found that the [Zn(II)(SCMC)]n inorganic polymer has tetrahedral geometry, whereas {[Cu(II)(SCMC)].2H2O}n has square planar geometry and [Mn(II)(SCMC).2H2O]n, {[Co(II)(SCMC).2H2O)].H2O}n and [Ni(II) (SCMC).2H2O]n have octahedral geometry. The decomposition temperatures of the inorganic polymers have been determined by TGA. The TGA reveal that the Mn(II) polymer of SCMC is highly thermally stable than rest of the polymers and these polymers can be used as thermal resisting materials.http://dx.doi.org/10.1155/2011/369492 |
| spellingShingle | H. D. Juneja Manisha Joshi N. T. KhatiI Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose E-Journal of Chemistry |
| title | Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose |
| title_full | Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose |
| title_fullStr | Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose |
| title_full_unstemmed | Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose |
| title_short | Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose |
| title_sort | synthesis and structural studies of some inorganic polymers of succinoyl carboxymethyl cellulose |
| url | http://dx.doi.org/10.1155/2011/369492 |
| work_keys_str_mv | AT hdjuneja synthesisandstructuralstudiesofsomeinorganicpolymersofsuccinoylcarboxymethylcellulose AT manishajoshi synthesisandstructuralstudiesofsomeinorganicpolymersofsuccinoylcarboxymethylcellulose AT ntkhatii synthesisandstructuralstudiesofsomeinorganicpolymersofsuccinoylcarboxymethylcellulose |